• Title/Summary/Keyword: Specific Heat Capacity

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Adsorption of Cd on Carbonaceous Adsorbent Developed from Automotive Waste Tire (자동차 폐타이어로부터 발달된 탄소질 흡착제에 의한 Cd의 흡착)

  • Kim, Younjung;Uh, Eun Jeong;Choi, Jong Ha;Hong, Yong Pyo;Kim, Daeik;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.61 no.6
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    • pp.339-345
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    • 2017
  • Carbonaceous adsorbent (CA-WTP) was prepared by heat treatment at $400^{\circ}C$ for 2 h in N2 atmosphere using waste tire powder (WTP). WTP and CA-WTP were first characterized by thermo-gravimetric analysis (TGA), energy dispersive X-ray spectrometer (EDS), scanning electron microscopy (SEM), specific surface area analysis (BET) and FT-IR spectroscopy. Then, they were tested as adsorbents for removal of Cd in water. CA-WTP exhibited much higher specific surface area and total pore volume than WTP itself and showed higher adsorption capacity for Cd. Equilibrium data of adsorption were analyzed using Freundlich and Langmuir isotherm models. It was seen that both Freundlich and Langmuir isotherms have correlation coefficient $R^2$ value larger than 0.95. The results of studies indicate that CA-WTP developed from WTP by heat treatment could be used as efficient adsorbent for the removal Cd from water.

An Economic Analysis on Slush Hydrogen Containing Liquid and Solid Phase for Long-Term and Large-Scale Storage (장주기/대용량 수소저장을 위한 액체/고체기반 Slush 수소의 저장 비용 분석)

  • PARK, SUNGHO;LEE, CHANGHYEONG;RYU, JUYEOL;HWANG, SEONGHYEON
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.3
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    • pp.247-254
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    • 2022
  • Slush hydrogen containing liquid and solid hydrogen is expected to achieve zero boil-off by suppressing boil-off gas because heat of fusion for solid absorbe the heat ingress from atmosphere. In this paper, quantitative analysis on storage cost considering specific energy consumption between 1,000 m3 class liquid hydrogen storage system with re-liquefaction and slush hydrogen storage system during equivalent zero boil off period. Even though approximately 50% of total storage capacity should be converted into solid phase during the initial cargo bunkering, total energy consumption to convert into slush hydrogen is relatively 25% less than re-liquefaction energy for boil off hydrogen during zero boil off period. That's because energy consumption of slush phase change take up only 1.8% of liquefaction energy. moreover, annual revenue requirement including CAPEX, OPEX and electric cost for slush hydrogen storage could be more reduced approximately 32.5% than those of liquid hydrogen storage and specific energy storage cost ($/kg-H2) could also be lowered by about 41.7% compared with liquid hydrogen storage.

Sequential Catalytic Combustion System (순차식 촉매연소 시스템)

  • Yu, Sang-Phil;Song, Kwang-Sup;Ryu, In-Soo;Jeong, Nam-Jo
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.153-158
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    • 2003
  • Catalytic Combustion used to be applied to specific conditions because of the characteristics different from flame combustion. However, many researches are focused on widening the applicant range of catalytic combustion with the competences of catalytic combustion. The development of many catalytic combustion appliances is one of the trials to overcome the restrictions of reaction and maximize the merits. In this research, past developments of appliances are depicted and new conceptual system will be introduced - sequential system. Sequential catalytic combustion system is composed of units - existing catalytic heat exchangers. This system is performed with parallel in composition and serially in operation. First, the burden of the preheating can be dramatically reduced. Second, stable operation control is expected. Lastly, Capacity expansion is flexible.

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Structural stability of fire-resistant steel (FR490) H-section columns at elevated temperatures

  • Kwon, In-Kyu;Kwon, Young-Bong
    • Steel and Composite Structures
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    • v.17 no.1
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    • pp.105-121
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    • 2014
  • A fundamental limitation of steel structures is the decrease in their load-bearing capacity at high temperatures in fire situations such that structural members may require some additional treatment for fire resistance. In this regard, this paper evaluates the structural stability of fire-resistant steel, introduced in the late 1999s, through tensile coupon tests and proposes some experimental equations for the yield stress, the elastic modulus, and specific heat. The surface temperature, deflection, and maximum stress of fire-resistant steel H-section columns were calculated using their own mechanical and thermal properties. According to a comparison of mechanical properties between fire-resistant steel and Eurocode 3, the former outperformed the latter, and based on a comparison of structural performance between fire-resistant steel and ordinary structural steel of equivalent mechanical properties at room temperature, the former had greater structural stability than the latter through $900^{\circ}C$.

Performance Analysis of SOFC/MGT Hybrid System

  • Kim, Jae-Hwan;Suzuki, Kenjiro
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.703-707
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    • 2001
  • A performance analysis of a SOFC/MGT hybrid system has been carried out for concept design. Thermo-dynamic models for each component being able to describe electrochemical characteristics and heat and mate-rial balance are proposed. Estimated is the power capacity of a SOFC suitable for the hybrid operation with a 5kW class MGT. Effects of current density and operating pressure are also investigated. Electric efficiency showed weak dependence on operating pressure and current density. It is desirable that the SOFC operates at high current density in manufacturing cost's point of view though operating with high current density slightly decreases the electric efficiency find specific power.

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Geothermal properties for Database (지열자료 정보 D/B 구축 요소)

  • Kim, Hyoung-Chan;Park, Jeong-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.28-31
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    • 2006
  • It is require to construct geothermal database to develop geothermal energy as renewable energy policy. It must be consist of geologic data, borehole data and geophysical data for geothermal database. In aspect of geology, there are included the distribution of geology, structural geology, geological time, rock name, density of rock, porosity, thermal diffusivity, specific capacity and thermal conductivity In order to calculate the heat general ion, it is needed to analysis the radioactivity elements as U, Th and K of rock. In aspect of borehole data, there are included temperature of depth, surface temperature and geothermal gradient And also there is geotherrnornetry using chemical components of groundwater as Na Ca, K and $SiO_2$. In aspect of geophysical data, there are some thematic map as booger gravity anomaly data and magnetic survey data and etc. In addition, it is important to descript the distribution of hot spring and water temperature.

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Optimal Design of a 3 Watt GM-JT Refrigeratior at 4 K (4 K, 3 Watt급 GM-JT냉동기의 최적설계)

  • Chang, H.M.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.1
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    • pp.11-19
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    • 1994
  • An optimal design for Gifford-McMahon/Joule-Thomson(GM-JT) refrigerators was performed by a numerical method. The design goal was to meet the cooling requirement for MRI systems, which was 3 Watt at 4 K. A general cycle analysis program was written to calculate the cooling capacity of the GM-JT refrigerators for the givenstage GM refrigerator. The program was executed for a specific refrigerator with various design parameters. The optimal values for the maximum cooling were found for the sizes of the heat exchangers, the mass flow rate of helium, and the compression pressure.

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Finite Element Analysis of Thermal Behaviours of a Disk Brake in High-Speed Trains (고속 전철에서 디스크 브레이크의 열거동에 관한 유한요소해석)

  • 김청균;조승현
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.10a
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    • pp.200-210
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    • 1997
  • This paper presents the thermal behaviours of a solid type disk brake for a high-speed train. The thermal behaviours of a brake disk with 50mm thickness shows good performance compared with 45mm thickness of a disk because of a high specific heat capacity and thermal expansion ratio. The FEM results show that the thickness of the d!sk with a same weight of the brake disk should be increased for a good flexibility of the contact thermal problems. Therefore, the ratio between the pad and disk in diameter may be reduced and the thickness of a disk increased.

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Evaporation characteristics of materials from resistive heating sources(I) (저항가열원에 의한 물질의 증발특성(I))

  • 정재인;임병문;문종호;홍재화;강정수;이영백
    • Journal of the Korean institute of surface engineering
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    • v.24 no.1
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    • pp.25-30
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    • 1991
  • The evaporation characteristics of Ag, Al, Au, Cr. Cu, In, Mg, Mn, Pb, Pd, Si, SiO, Sn, Ti and Zn with the various resistive heating sources have been studied. The employed sources are refractory metal (Mo, Ta and W) boats, W-wire, ceramic (usually Al2O3)-coated and -barriered refractory metal boats, and special boats such as baffled boats and intermetallic boats (nitride compound and graphite). We investigated the melting mode, evaporation rate at a specific power, and lifetime of the sources. A special boat holder is also discussed which is needed to cool the sources at a large heat capacity.

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Estimation of Cooldown Time in Cryocooled Superconducting Magnet System

  • Choi, Yeon-Suk;Kim, Dong-Lak;Shin, Dong-Won
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.2
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    • pp.25-28
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    • 2010
  • A cooldown time is one of the major factors in many cryocooler applications, especially for the design of conduction-cooled superconducting apparatus. The estimation of cooldown seeks the elapsed time to cool thermal object by a cryocooler during initial cooldown process. This procedure includes the dimension of cold mass, heat transfer analysis for cryogenic load and available refrigerating capacity of a cryocooler. This method is applied to the specific cooling system for a 3 Tesla superconducting magnet cooled by a two-stage GM cryocooler. The result is compared with that of experiment, showing that the results of proposed method have a good agreement with experiments during initial cooling of superconducting magnet.