• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.11 no.1
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• pp.71-83
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• 2007

The double diffusive convection of cold water in the vicinity of its density maximum in a rectangular partitioned enclosure of aspect ratio 5 with isothermal side walls and insulated top and bottom is studied numerically. A thin partition is attached to the hot wall. The species diffusivity of the fluid is assumed to vary linearly with concentration. The governing equations are solved by finite difference scheme. The effects of position and height of the partition, variable species diffusivity and enclosure width are analyzed for various hot wall temperatures. It has been found that adding partition on the hot wall reduces the heat transfer. The density inversion of the water has a great influence on the natural convection. When increasing species diffusivity parameter heat and mass transfer rate is decreased.

• Journal of the Korean Wood Science and Technology
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• v.37 no.2
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• pp.141-147
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• 2009

The fluctuation of physical properties in wood or wood composites is an important subject when the materials in building and construction. Sorption and desorption occur in wood when exposed to the open air, and the temperature distribution in wood can fluctuate as a result of changes in environmental temperature, solar radiation, humidity, and wind velocity. In this study, the temperature difference and fluctuation caused by outdoor environment among different wood species were analyzed using a numerical method. The effect on the process of heat transfer in wood caused by environmental factors was investigated using 1-dimensional partial differential equation with real boundary and initial conditions. The experimental data have been used to check the accuracy of programming code. Through analysis, it was found out that density and moisture content have a negative effect on thermal diffusivity of wood.

• Journal of the Korean Electrochemical Society
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• v.12 no.1
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• pp.1-10
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• 2009

This article reviewed transport behaviours of electroactive species in ionic compounds, focusing on chemical diffusion of Li through the transition metal oxide in a current flowing condition. For this purpose, a distinction has been first briefly made between migration and diffusion with respect to current, driving force and charge of electroactive species considered. Then, the equations for chemical diffusion are derived theoretically in open-circuit and current flowing conditions. Finally, the experimental methods such as ac impedance spectroscopy and current (potential) transient techniques are described in details for characterising chemical diffusion. In addition, the role of the thermodynamic enhancement factor in chemical diffusion is discussed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.12
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• pp.1009-1016
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• 2007

Numerical study on preferential diffusion effects in flame structure in $CH_4-H_2$ diffusion flames is conducted with detailed chemistry. Comparison of flame structures with mixture-averaged species diffusion and suppression of the diffusivities of $H_2$ and H was made. Discernible differences in flame structures are displayed with three species diffusion models. The behaviors of maximum flame temperatures with those species diffusion models are not explained by scalar dissipation rate but by the nature of chemical kinetics. It is seen that the modifcation of flame structure is mainly due to the preferential diffusion of H2 and thereby the nature of chemical kinetics. It is also found that the behaviors of major species with the three species diffusion models are addressed to the nature of chemical kinetics, and this is evident by examining importantly contributing reaction steps to the production and destruction of those chemical species.

• Analytical Science and Technology
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• v.8 no.2
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• pp.205-213
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• 1995

Counter-diffusion of coronene desorbed from alumina with addition of tetra-phenylporphine was studied by spectrophotometry. The counter-diffusion processes of adsorbing and desorbing materials in liquid phase were simulated by counter-diffusion model based on Fritz's binary component isotherm under an assumption of equimass diffusion. The counter-diffusivities of desorbed coronene with addition of tetra-phenylporphine were as ${\sim}10^{-15}m^2/sec$ and that of adsorbed tetra-phenylporphine as ${\sim}10^{-11}m^2/sec$. The counter-diffusivity of coronene determined from desorption process was smaller by ${\sim}10^5$ times than the diffusivity determined from adsorption process of a single species. The reduction of the determined counter-diffusivity of coronene in desorption process was explained by the cross of diffusion fluxes and build-up of high gradient of coronene in pore.

• Computers and Concrete
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• v.7 no.5
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• pp.421-435
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• 2010

This paper utilizes the modified Davis model and the mode coupling theory, as parts of the electrolyte solution theory, to investigate the diffusivity of the ion in concrete. Firstly, a computational model of the ion diffusion coefficient, which is associated with ion species, pore solution concentration, concrete mix parameters including water-cement ratio and cement volume fraction, and microstructure parameters such as the porosity and tortuosity, is proposed in the saturated concrete. Secondly, the experiments, on which the chloride diffusion coefficient is measured by the rapid chloride penetration test, have been carried out to investigate the validity of the proposed model. The results indicate that the chloride diffusion coefficient obtained by the proposed model is in agreement with the experimental result. Finally, numerical simulation has been completed to investigate the effects of the porosity, tortuosity, water-cement ratio, cement volume fraction and ion concentration in the pore solution on the ion diffusion coefficients. The results show that the ion diffusion coefficient in concrete increases with the porosity, water-cement ratio and cement volume fraction, while we see a decrease with the increasing of tortuosity. Meanwhile, the ion concentration produces more obvious effects on the diffusivity itself, but has almost no effects on the other ions.

• Nuclear Engineering and Technology
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• v.41 no.1
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• pp.39-52
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• 2009

Theory-based models and high performance simulations are briefly reviewed starting with atomistic methods, such as Electronic Structure calculations, Molecular Dynamics, and Monte Carlo, continuing with meso-scale methods, such as Dislocation Dynamics and Phase Field, and ending with continuum methods that include Finite Element and Finite Volume. Special attention is paid to relating thermo-mechanical and chemical properties of the fuel to reactor parameters. By inserting atomistic models of point defects into continuum thermo-chemical calculations, a model of oxygen diffusivity in $UO_{2+x}$ is developed and used to predict point defect concentrations, oxygen diffusivity, and fuel stoichiometry at various temperatures and oxygen pressures. The simulations of coupled heat transfer and species diffusion demonstrate that including the dependence of thermal conductivity and density on composition can lead to changes in the calculated centerline temperature and thermal expansion displacements that exceed 5%. A review of advanced nuclear fuel performance codes reveals that the many codes are too dedicated to specific fuel forms and make excessive use of empirical correlations in describing properties of materials. The paper ends with a review of international collaborations and a list of lessons learned that includes the importance of education in creating a large pool of experts to cover all necessary theoretical, experimental, and computational tasks.

• Journal of Radiation Protection and Research
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• v.20 no.4
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• pp.265-274
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• 1995

Diffusivity of ions of radioactive species is an important factor for designing radwaste repositories. Clay minerals are used as a backfill material. In this study, diffusion of Co-60 ions through the bentonite having various densities has been studied, using a diffusion cell. The measured diffusivities of Co-60 ions decreased as the density of bentonite increased. The diffusivity of Co-60 ion decreased from $8.79{\times}10^{11}m^2/s$ to $6.82{\times}10-13m^2/s$ as the clay dry bulk density increased from 0.41 to 2.03g/cm3. The diffusivity of Co ion was larger than that of Sr ion at low density, but the diffusivity of Co ion decreased rapidly as the density of clay increased and became smaller than that of Cs ion at high density. This phenomenon is thought to be caused by the rapid decrease of the fraction of mobile cation since the chemical combination of Co ions with oxygen or oxide on clay surface and the entrance of Co ions into the crystal structure of clay increase as the clay density increases. This change should be considered especially in designing the clay back fill for low and intermediate radwaste disposal facilities.

• Journal of the Korean Wood Science and Technology
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• v.36 no.4
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• pp.1-10
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• 2008

A series of the studies on the applied physical properties of domestic species have been conducted last three years. Pinus koraiensis and Larix kaempferi were two of the three species examined for the first year. Because the same apparatus and experimental procedures were used for all species, their results can be easily comparable. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMCs and sorption isotherms at various RH conditions. The thermal conductivity and diffusivity, and electric resistance and volumetric electric resistivity were measured with a thermal-wire device and a high electric resistance meter. The differences in the thermal and electric properties between quarter- and flat-sawn specimens were observed, which were partially attributed to their anatomical differences. An acoustic measurement system was used to evaluate dynamic MOE and internal friction. This paper provides the useful fundamental data for designing a wood structure, correcting a portable resistance-type moisture meter, and acoustic properties of wood.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.70-84
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• 2008

A series of the studies on the applied physical properties of domestic species have been conducted last three years. Pinus densiflora was one of the three species examined for the first year. Because the same apparatus and experimental procedures were used for all species, their results can be easily comparable. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMC's and sorption isotherms at various heating conditions. The thermal conductivity and diffusivity, and electric resistance and volumetric electric resistivity were measured with a thermal-wire device and a high electric resistance meter. The differences of the thermal and electric properties between quarter- and flat-sawn specimens were observed, which was partially attributed to their anatomical differences. An acoustic measurement system was used to evaluate dynamic MOE and internal friction. This paper provides the useful fundamental data for designing a wood structure, correcting a portable resistance-type moisture meter, and nondestructive testing wood.