• Title/Summary/Keyword: Soot Oxidation

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Experimental Study on Estimation of Oxidation Rate of PM inside of Diesel Particulate Filter (DPF내 포집된 입자상 물질의 산화율 산출을 위한 실험적 연구)

  • Shim, Beomjoo;Park, Kyoungsuk;Jo, Kyuhee;Lee, Hyeongjun;Min, Byeongdu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.2
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    • pp.98-103
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    • 2013
  • Conventional method to estimate mass of particulate matter accumulated in diesel particulate filter is to use pressure difference between upstream and downstream of the filter. Then measured pressure difference should be compared that of clean condition which is no particulate matter accumulated in DPF. During regeneration soot oxidation is also estimated by same method. This methodology, however, has demerit on accuracy because of pressure difference deviation of clean DPFs and pressure difference caused by non-carbon based PM which is different from that of caused by carbon based PM. This study suggests new methodology to estimate accumulated soot oxidation rate through exhaust gas characteristics during regeneration. Results, more high accuracy of soot oxidation was obtained by analysis of relationship between fuel mass and concentration of carbon dioxide and oxygen.

Predictions on the Flame Structure and Soot Distribution in the Coflowing Laminar Diffusion Flames (동층류 축대칭 확산화염내의 화염구조 및 매연입자 분포의 예측)

  • 이정기;김상수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.8
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    • pp.1583-1594
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    • 1992
  • A numerical calculation on the flame structure and soot particle distribution in a coannular laminar diffusion flame was performed. Flame analysis model utilized basically flame sheet concepts, Shvab-Zel'dovich assumption, and one step overall irreversible reaction. It was also considered the variation of thermodynamics and transport properties, and the stagnation enthalpy was used for solving temperature field. Radiation was taken into account, since it has been found to be important in determining the flame temperature in sooty flames. For soot particle analysis, we adopted the coagulation, suface condensation, and the oxidation model in addition to tesner's two-step formation model. Equations for primary soot particle excluding the agglomeration process were solved. Based on the results, the regions of soot generation, growth, and oxidation in the flame have been observed and radiation strongly influenced flame temperature and soot distribution.

Combined Application of Burner and Oxidation Catalyst for Diesel Particulate Filter Regeneration (DPF 재생을 위한 버너-산화촉매 복합 적용)

  • Shim, Sung-Hoon;Jeong, Sang-Hyun
    • Journal of the Korean Society of Combustion
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    • v.15 no.3
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    • pp.25-31
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    • 2010
  • Combined technique of burner and DOC has been used for regeneration of Diesel Particulate Filter. Experiments has been performed to increase the temperature of engine exhaust gas to burn the collected soot in DPF at all conditions of operation of 3 liter diesel engine. Ignition temperature of soot can be successfully obtained by heats of burner flame and residual fuel oxidation at diesel oxidation catalyst even in the condition of oxygen deficiency. It is found that the load of air compressor and heat loss can be reduced to the level of practical application. It is also found that CO and THC emissions are not increase by additional combustion of regeneration burner.

Numerical Modeling of Soot Formation in $C_2H_4$/Air Turbulent Non-premixed Flames ($C_2H_4$/Air 비예혼합 난류화염의 매연생성 모델링)

  • Kim, Tae-Hoon;Woo, Min-O;Kim, Yong-Mo
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.22-28
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    • 2010
  • The Direct Quadrature Method of Moments (DQMOM) has been presented for the solution of population balance equation in the wide range of the multi-phase flows. This method has the inherently interesting features which can be easily applied to the multi-inner variable equation. In addition, DQMOM is capable of easily coupling the gas phase with the discrete phases while it requires the relatively low computational cost. Soot inception, subsequent aggregation, surface growth and oxidation are described through a population balance model solved with the DQMOM for soot formation. This approach is also able to represent the evolution of the soot particle size distribution. The turbulence-chemistry interaction is represented by the laminar flamelet model together with the presumed PDF approach and the spherical harmonic P-1 approximation is adopted to account for the radiative heat transfer.

Soot Formation and Oxidation of an Ethylene Laminar Diffusion Flame with Different Radiation Boundary Conditions (에틸렌 층류 확산화염의 복사경계조건에 따른 매연생성 및 산화특성)

  • Lee, Chun-Beom;Nam, Youn-Woo;Lee, Won-Nam;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.11-18
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    • 2003
  • The soot formation and oxidation characteristics with different radiation boundary conditions have been studied experimentally in a co-flow ethylene/air laminar diffusion flame. The boundary conditions are two cases, one is a fully refractive radiation boundary condition by a polished aluminum cylinder(AL) and the other is a fully absorbing radiation boundary condition by a black body cylinder(BB). The AL case compared with BB condition show the lower inception point, denser soot volume fraction, wider and longer annular soot area owing to the reabsorption of radiating energy.

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Nano-Soot Particle Formation in Inverse Diffusion Flames (인버스 확산화염에서의 나노 수트 입자 생성)

  • Lee, Eui-Ju;Shin, Hyun-Joon;Oh, Kwang-Chul;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.19-26
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    • 2003
  • Experimental measurements of flame structure and soot characteristics were performed for ethene inverse diffusion flames (IDF). IDF has been considered as the excellent flow field to study the incipient soot because soot particle do not experience the oxidation process. In this study, LIF image clarified the reaction zone of IDF with OH signal and PAH distribution. laser light scattering technique also identified the being of soot particle. To address the degree of soot maturing, C/H ratio and morphology of soot sample were investigated. From these measurements, the effect of flow residence time and temperature on soot inception could be suggested, and more details on soot characteristic in the IDF was determined according to fuel dilution and flame condition. The fuel dilution results in a decrease of temperature and enhancement of residence time, but the critical dilution mole fraction is existed for temperature not to effect on soot growth. Also, the soot inception evolved on the specific temperature and its morphology are independent of the fuel dilution ratio of fuel.

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Numerical Analysis for the Detailed Structure and the Soot Formation Mechanism in Counterflow Ethylene-Air Nonpremixed Flame (대향류 에틸렌/공기 비예혼합 화염의 구조 및 Soot 생성 메커니즘 해석)

  • 임효준;김후중;김용모
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.5
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    • pp.40-54
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    • 1999
  • The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

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Temperature Distribution in Ethylene Diffusion Flames Based on Measurement Techniques;Comparison of Thermocouple and Tow-Color Pyrometry (측정방법에 따른 에틸렌 확산화염의 온도분포;열전대 및 이색법 측정 결과 비교)

  • Lee, Won-Nam;Na, Yong-Dae;Lee, Bum-Ky;Park, Seong-Nam
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.175-182
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    • 2000
  • Flame temperatures were measured and compared using a rapid insertion technique and a two-color pyrometry with Abel inversion process in co-flow ethylene diffusion flames. The measured line-of-sight temperature showed very limited usefulness in understanding the detailed soot formation/oxidation process in a co-flow diffusion flame. The flame temperatures could be measured with reasonable accuracy for the soot laden regions in ethylene diffusion flames using two-color pyrometry with an Abel inversion technique. Two-color-pyrometry with Abel inversion was demonstrated as a useful temperature measurement technique for co-flow diffusion flames, expecially under pressure conditions, where a thermocouple is not applicable. The soot volume fraction could be also obtained using tow-color pyrometry with Abel inversion, which provides important information for understanding the soot formation/oxidation mechanism in diffusion flames.

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Reduction of Soot Emitted from a $C_2$$H_4$ Normal Diffusion Flame with Application of DC Corona Discharge (DC 코로나 방전이 적용된 에틸렌 정상 확산 화염의 Soot 배출 저감)

  • Lee, Jae-Bok;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.496-506
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    • 2001
  • The effect of corona discharge on soot emission was experimentally investigated. Size and number concentrations of soot aggregates were measured and compared for various voltages. Regardless of the polarity of the applied voltage, the flame length decreased and the tip of flame spreaded with increasing voltage. For the experimental conditions selected, the flame was blown off toward the ground electrode by corona ionic wind. When the negative applied voltage was greater than 3kV(for electrode spacing = 3.5cm), soot particles in inception or growth region were affected by the corona discharge, resulting in the reduction of number concentration. The results show that the ionic wind favored soot oxidation and increased flame temperature. Number concentration and primary particle size greatly increased, when the corona electrodes were located the region of soot nucleation or growth(close to burner mouth).

Simultaneous Application of Platinum-Supported Alumina Catalyst and Ozone Oxidant for Low-temperature Oxidation of Soot (백금담지 알루미나 촉매와 오존 산화제 동시 적용에 의한 탄소 입자상 물질의 저온 산화반응)

  • Lee, Jin Soo;Lee, Dae-Won
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.752-760
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    • 2018
  • The lowering of temperature for combustion of diesel particulate matters (or diesel soot) is one of the important tasks in automotive industry that is searching for a way to meet up "high-fuel efficiency, low-emission" standard. In this study, it was discussed how the use of ozone over platinum-based catalyst promotes a low-temperature soot oxidation occurred at $150^{\circ}C$. The use of platinum catalyst did not increase oxidation rate largely but was very effective in improving the selectivity of carbon dioxide. The pre-oxidation of NO into $NO_2$ using ozone was rather crucial in improving the oxidation rate of soot at $150^{\circ}C$.