• Title/Summary/Keyword: Solution-Process

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Development of On-Site Process for Refractory 2,4-Dichlorophenol Treatment (난분해성 2,4-Dichlorophenol 처리를 위한 원위치 처리 프로세스 개발 연구)

  • Park, Kyeong-Deok;Kim, Il-Kyu
    • Journal of Power System Engineering
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    • v.20 no.1
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    • pp.42-49
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    • 2016
  • This study showed that on-site ferrate(VI) solution was synthesized by wet oxidation method and applied aqueous 2,4-dichlorophenol(DCP) solution to evaluate the degradation efficiency. On-site ferrate(VI) solution was synthesized by putting $FeCl_3{\cdot}6H_2O$ in the strong alkali solution with NaClO and NaOH and applied DCP solution directly. DCP solution was extracted by the liquid-liquid method and analyzed by GC-ECD. The factors such as pH, DCP initial concentration, injected ferrate(VI) dosage, temperature were investigated. The optimum pH and temperature conditions of DCP degradation were obtained in neutral condition and $35^{\circ}C$. And the experimental results showed that DCP removal efficiency also increased with the decrease of DCP initial condition and the injected ferrate(VI) dosage.

Development of the EAI Solution Selection Criteria : Focused on the case of KRA(Korea Racing Association) (EAI(Enterprise Application Integration) 솔루션 도입을 위한 평가기준 개발 및 적용사례 연구 : KRA적용사례 중심으로)

  • Jeon Seong-Hyeon;Park Chan-Uk
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2004.10a
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    • pp.158-169
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    • 2004
  • Recently companies are aggressively pushing ahead with integrating the systematical applications of internal and external information systems such as Data level, Application level, Process level in the company, Process level between companies. The EAI solution is generally considered as the necessary tool to integrate companies, but the appraisal standard for the EAI solution has not yet settled in Korea, so the companies have difficulty in deciding whether to adopt the EAI solution or not. Through this report, we first introduce the KRA Project as the best practice in making an application of the settled standard to evaluate and adopt the EAI solution, and then suggest that it can be adapted to companies considering applying to the EAI solution.

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Development of Curdlan Separation Process with Density Gradient Centrfugation (Density Gradient를 이용한 식품소재를 커들란의 분리공정개발)

  • 김봉영;이중헌
    • KSBB Journal
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    • v.16 no.5
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    • pp.523-525
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    • 2001
  • Curdlan is one biopolymer composed of ${\beta}$1,3-glucan and dissolved in a alkali solution but formed salt under neutral or acid condition. It was produced by Agrobactrium species and the separation process is necessary to make pure curdlan from the culture broth. The pH swing separation method was as feasible separation process using solubility changes with the pH difference. however, this method requires a lot of acid and alkali solution also produces a lot of waste. Therefore, an efficient process which could save energy and minimize toxic waste was developed. A density gradient separation process was developed in this research. High density sucrose solution was used as a separation agent. Curdlan was separated from the culture broth when the density of the sucrose solution was 1.15 g/L. Since the curdlan was produced on the surface of cell wall. the pre-treatment of culture broth was necessary. Curdlan recovery yield was increased up to 83% with the homogenization of the culture broth and further increased up to 87% with the treatment of alkai-acid solution.

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Effects of coagulation-UF pretreatment on pressure retarded osmosis membrane process (응집-UF 전처리 공정이 압력지연삼투 공정에 미치는 영향)

  • Goh, Gilhyun;Kim, Suhyun;Kim, Jungsun;Kang, Limseok
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.4
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    • pp.285-292
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    • 2021
  • Osmotic power is to produce electric power by using the chemical potential of two flows with the difference of salinity. Water permeates through a semipermeable membrane from a low concentration feed solution to a high concentration draw solution due to osmotic pressure. In a pressure retarded osmosis (PRO) process, river water and wastewater are commonly used as low salinity feed solution, whereas seawater and brine from the SWRO plant are employed as draw solution. During the PRO process using wastewater effluent as feed solution, PRO membrane fouling is usually caused by the convective or diffusive transport of PRO which is the most critical step of PRO membrane in order to prevent membrane fouling. The main objective of this study is to assess the PRO membrane fouling reduction by pretreatment to remove organic matter using coagulation-UF membrane process. The experimental results obtained from the pretreatment test showed that the optimum ferric chloride and PAC dosage for removal of organic matter applied for the coagulation and adsorption process was 50 mg/L as FeCl3 (optimum pH 5.5). Coagulation-UF pretreatment process was higher removal efficiency of organic matter, as also resulting in the substantial improvement of water flux of PRO membrane.

Recovery of Heavy-Metallic Components from a Waste Electro-polishing Solution of 316L Steel by the Solar Cell Electricity (태양전지 전력을 이용한 316L강의 전해연마 폐액 중 중금속 성분의 회수)

  • Kim, Ki-Ho;Jang, Jung-Mok
    • Journal of Surface Science and Engineering
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    • v.42 no.1
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    • pp.53-57
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    • 2009
  • Recovery of heavy-metallic component from a waste solution of factory was undertaken by the solar cell electricity. The solution was obtained from an electrolytic etching process of 316L stainless steel. The electrolysis of the solution for recovery of heavy metallic components was made with platinum plated titanium mesh anode and copper plate cathode. Analysis for the solution and electro-winned materials were made by EDS, XRD and SEM. Iron, chromium, and sulfur components were recovered on the cathode from the solution. Result of EDS analysis for the electro-winned materials revealed that some metal oxide were contained in the recovered material. The recovered materials were expected to have metallic form only by the electrolysis, but metal compounds were contained because of weak solar cell power. Nickel and manganese component in the solution doesn't recovered by this electrolysis process, but they made a sludge with phosphoric acid in the solution.

The Influence of Silicon Doping on Electrical Characteristics of Solution Processed Silicon Zinc Tin Oxide Thin Film Transistor

  • Lee, Sang Yeol;Choi, Jun Young
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.2
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    • pp.103-105
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    • 2015
  • Effect of silicon doping into ZnSnO systems was investigated using solution process. Addition of silicon was used to suppress oxygen vacancy generation. The transfer characteristics of the device showed threshold voltage shift toward the positive direction with increasing Si content due to the high binding energy of silicon atoms with oxygen. As a result, the carrier concentration was decreased with increasing Si content.

Morphology Development of HAp Crystallites in GEL Matrix

  • Chang, Myung-Chul
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.133-136
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    • 2007
  • The crystal morphology of hydroxyapatite [HAp] phase in gelatin [GEL] matrices was investigated with the condition of a GEL precursor treatment in an aqueous solution of $H_{3}PO_{4}$ at $37-80^{\circ}C$. Needle-shaped nanocomposite particles were prepared through a dynamic reaction during a coprecipitation process using a phosphoric GEL solution. Various types of mineralized morphology appeared with a phosphorylated condition of the GEL solution. HAp/GEL nanocomposite slurries showed the existence of an octacalcium phosphate [OCP] phase during the process.

Development of a Unit Module for the Process of Large Scale Dialysis for Silk fibroin (실크 피브로인의 대규모 투석 공정의 단위 모듈의 개발)

  • Kim, Dong-Woo;Ha, Sung-Jin;Lim, Gun-Bin;Hur, Won
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.27-30
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    • 2001
  • For the development of a large-scale dialysis process for silk fibroin solution, a batch and continuous dialysis chamber was designed and built, which are to be used as a unit module for the process. A series of dialysis experiments were carried out to estimate the kinetic parameters for dialysis using the solutions of salt-solubilized silk fibroin. The solution was dialyzed by distilled water either batch-wise or continuously. Dialysis kinetics was monitored by measuring refractometery at high salt concentration and conductivity at lower salt concentration. The apparent dialysis coefficients were $5.4g/m^2-hr$ and $1.8g/m^2-hr$, for well mixed batch and continuous dialysis, respectively. The alteration of molecular weight distribution of dialyzed silk fibroin solution was monitored.

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Effect of Polymer Content on Synthesis Process and Microstructure of Alumina-Zirconia Composite (알루미나-지르코니아 복합체의 제조공정 및 미세구조에 미치는 폴리머 첨가의 영향)

  • 이상진;권명도;이충효;조경식
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.310-317
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    • 2003
  • Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

Discrete Sizing Design of Truss Structure Using an Approximate Model and Post-Processing (근사모델과 후처리를 이용한 트러스 구조물의 이산 치수설계)

  • Lee, Kwon-Hee
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.5
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    • pp.27-37
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    • 2020
  • Structural optimization problems with discrete design variables require more function calculations (or finite element analyses) than those in the continuous design space. In this study, a method to find an optimal solution in the discrete design of the truss structure is presented, reducing the number of function calculations. Because a continuous optimal solution is the Karush-Kuhn-Tucker point that satisfies the optimality condition, it is assumed that the discrete optimal solution is around the continuous optimum. Then, response values such as weight, displacement, and stress are predicted using approximate models-referred to as hybrid metamodels-within specified design ranges. The discrete design method using the hybrid metamodels is used as a post-process of the continuous optimization process. Standard truss design problems of 10-bar, 25-bar, 15-bar, and 52-bar are solved to show the usefulness of this method. The results are compared with those of existing methods.