Journal of Power System Engineering (동력기계공학회지)

The Korean Society for Power System Engineering (한국동력기계공학회)
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Development of On-Site Process for Refractory 2,4-Dichlorophenol Treatment

난분해성 2,4-Dichlorophenol 처리를 위한 원위치 처리 프로세스 개발 연구

  • Park, Kyeong-Deok (Department of Environmental Engineering, Pukyong National University) ;
  • Kim, Il-Kyu (Department of Environmental Engineering, Pukyong National University)
  • Received : 2015.10.20
  • Accepted : 2016.02.11
  • Published : 2016.02.28
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Abstract

This study showed that on-site ferrate(VI) solution was synthesized by wet oxidation method and applied aqueous 2,4-dichlorophenol(DCP) solution to evaluate the degradation efficiency. On-site ferrate(VI) solution was synthesized by putting $FeCl_3{\cdot}6H_2O$ in the strong alkali solution with NaClO and NaOH and applied DCP solution directly. DCP solution was extracted by the liquid-liquid method and analyzed by GC-ECD. The factors such as pH, DCP initial concentration, injected ferrate(VI) dosage, temperature were investigated. The optimum pH and temperature conditions of DCP degradation were obtained in neutral condition and $35^{\circ}C$. And the experimental results showed that DCP removal efficiency also increased with the decrease of DCP initial condition and the injected ferrate(VI) dosage.

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References

  1. A. Karci, I. Arslan-Alaton, T. Olmez-Hanci and M. Bekbolet, 2012, "Transformation of 2,4-Dichlorophenol by $H_2O_2$-UV-C, Fenton and Photo-Fenton Processes: Oxidation Products and Toxicity Evolution", Journal of Photochemistry and Photobiology A: Chemistry. Vol. 230, pp. 65-73. https://doi.org/10.1016/j.jphotochem.2012.01.003
  2. D. Petroutsos, P. Katapodis, M. Samiotaki, G. Panayotou and D. Kekos, 2008, "Detoxification of 2,4-Dichlorophenol by the Marine Microalga Tetraselmis Marina", Phytochemistry, Vol. 69, No. 3, pp. 707-714. https://doi.org/10.1016/j.phytochem.2007.09.002
  3. O. E. Igbinosa, E. E. Odjadjare, V. N. Chigor, I. H. Igbinosa, A. O. Emoghene, F. O. Ekhaise, N. O. Igiehon and O. G. Idemudia, 2013, "Toxicological Profile of Chlorophenols and Their Derivatives in the Environment The Public Health Perspective", The Scientific World Journal, Vol. 2013, pp. 1-11.
  4. W. Z. Tang and C. P. Huang, 1996, "2,4-Dichlorophenol Oxidation Kinetics by Fenton's Reagent", Environmental Technology, Vol. 17, pp. 1371-1378. https://doi.org/10.1080/09593330.1996.9618465
  5. L. F. Kenneth and O. Hutzinger, 1996, "Polychlorinated Benzene, Phenol, Dibenzo-PDioxin, and Dibenzofuran in Heterogeneous Combustion Reactions of Acetylene", Environ. Sci. Technol., Vol. 30, No. 3, pp. 998-1008. https://doi.org/10.1021/es9504808
  6. I. Kim, 2014, "Degradation of 2,3-dichlorophenol by a Photo-Fenton Process with Continuous Pump-Feeding of Hydrogen Peroxide", Journal of the Korean Society for Power System Engineering Vol. 18, No. 6, pp. 84-90.
  7. S. Hager, R. Bauer and G. Kudielka, 2000, "Photocatalytic Oxidation of Gaseous Chlorinated Organics over Titanium Dioxide", Chemosphere, Vol. 41, No. 8, pp. 1219-1225. https://doi.org/10.1016/S0045-6535(99)00558-5
  8. Y. H. Lee, M. Cho, J. Y. Kim and J. Y. Yoon, 2004, "Chemistry of Ferrate (Fe(VI)) in Aqueous Solution and Its Applications as a Green Chemical", J. Ind. Eng. Chem., Vol. 10, No. 1, pp. 161-171.
  9. V. K. Sharma, 2002, "Potassium ferrate(VI); an Environmentally Friendly Oxidant", Advances in Environmental Research, Vol. 6, pp. 143-156. https://doi.org/10.1016/S1093-0191(01)00119-8
  10. S. Licht and X. Yu, 2005, "Electrochemical Alkaline Fe(VI) Water Purification and Remediation," Environ. Sci. Technol., Vol. 39, No. 20, pp. 8071-8076. https://doi.org/10.1021/es051084k
  11. Y. H. Lee, I. H. Um and J. Y. Yoon, 2003, "Arsenic(III) Oxidation by Iron(VI) (Ferrate) and Subsequent Removal of Arsenic(V) by Iron(III) Coagulation", Environ. Sci. Technol., Vol. 37, No. 24, pp. 5750-5756. https://doi.org/10.1021/es034203+
  12. J. H. Nam, I. K. Kim, J. H. Kwon and Y. D. Kim, 2015, "Applications of Electrochemical ferrate(VI) for Degradation of Trichloroethylene in the Aqueous Phase", Desalination and Water Treatment, pp. 1-8.
  13. Q. Han, H. Wang, W. Dong, T. Liu, Y. Yin and H. Fan, 2015, "Degradation of Bisphenol A by ferrate(VI) Oxidation; Kinetics, Products and Toxicity Assessment", Chemical Engineering Journal, Vol. 262, pp. 34-40. https://doi.org/10.1016/j.cej.2014.09.071
  14. P. Zhang, G. Zhang, J. Dong, M. Fan and G. Zeng, 2012, "Bisphenol A Oxidative Removal by Ferrate (Fe(VI)) under a Weak Acidic Condition", Separation and Purification Technology, Vol. 84, No. 9, pp. 46-51. https://doi.org/10.1016/j.seppur.2011.06.022
  15. B. Yang, G. G. Ying, Z. F. Chen, J. L. Zhao, F. Q. Peng and X. W. Chen, 2014, "Ferrate(VI) Oxidation of Tetrabromobisphenol A in Comparison with Bisphenol A", Water Research, Vol. 62, No. 1, pp. 211-219. https://doi.org/10.1016/j.watres.2014.05.056
  16. B. Yang, G. G. Ying, L. J. Zhang, L. J. Zhou, S. Liu and Y. X. Fang, 2011, "Kinetics Modeling and Reaction Mechanism of ferrate(VI) Oxidation of Benzotriazoles", water research, Vol. 45, pp. 2261-2269. https://doi.org/10.1016/j.watres.2011.01.022
  17. V. K. Sharma, J. O. Smith and F. J. Millero, 1997, "Ferrate(VI) Oxidation of Hydrogen Sulfide", Environ. Sci. Technol., Vol. 31, No. 9, pp. 2486-2491. https://doi.org/10.1021/es960755z
  18. V. K. Sharma, W. Rivera, J. O. Smith and B. O'Brien, 1998, "Ferrate(VI) Oxidation of Aqueous Cyanide", Environ. Sci. Technol., Vol. 32, No. 17, pp. 2608-2613. https://doi.org/10.1021/es970820k
  19. Y. Wang, H. Liu, G. Liu, Y. Xie and S. Gao, 2015, "Oxidation of Diclofenac by Potassium Ferrate (VI): Reaction Kinetics and Toxicity Evaluation", Science of the Total Environment, Vol. 506-507, pp. 252-258. https://doi.org/10.1016/j.scitotenv.2014.10.114
  20. M. H. Lim and M. J. Kim, 2009, "Removal of Natural Organic Matter from River Water Using Potassium Ferrate(VI)", Water Air Soil Pollut, Vol. 200, pp. 181-189. https://doi.org/10.1007/s11270-008-9902-x
  21. G. R. Xu, Y. P. Zhang and G. B. Li, 2009, "Degradation of Azo Dye Active Brilliant Red X-3B by Composite Ferrate Solution", Journal of Hazardous Materials, Vol. 161, No. 2-3, pp. 1299-1305. https://doi.org/10.1016/j.jhazmat.2008.04.090
  22. R. Prucek, J. Tucek, J. Kolarik, I. Huskova, J. Filip, R. S. Varma, V. K. Sharma and R. Zboril, 2015, "Ferrate(VI)-Prompted Removal of Metals in Aqueous Media: Mechanistic Delineation of Enhanced Efficiency via Metal Entrenchment in Magnetic Oxides", Environ. Sci. Technol., Vol. 49, pp. 2319-2327. https://doi.org/10.1021/es5048683
  23. X. Tang, H. Zheng, H. Teng, Y. Sun, J. Guo, W. Xie, Q. Yang and W. Chen, 2014, "Chemical Coagulation Process for the Removal of Heavy Metals from Water: a Review", Desalination and Water Treatment, pp. 1-16.
  24. S. Sailo, L. Pachuau, J. K. Yang, S. M. Lee,and D. Tiwari, 2015, "Efficient Use of ferrate(VI) for the Remediation of Wastewater Contaminated with Metal Complexes", Environ. Eng. Res., Vol. 20, No. 1, pp. 89-97. https://doi.org/10.4491/eer.2014.079
  25. J. Ma and W. Liu, 2002, "Effectiveness and Mechanism of Potassium ferrate(VI) Preoxidation for Algae Removal by Coagulation", Water Research, Vol. 36, pp. 871-878. https://doi.org/10.1016/S0043-1354(01)00282-2
  26. R. Gandhi, 2013, "Treatment of Combined Sewer Overflows Using Ferrate (VI)", The University of Western Ontario.
  27. V. K. Sharma, R. A. Rendon, F. J. Millero and F. G. Vazquez, 2000, "Oxidation of Thioacetamide by ferrate(VI)", Marine Chemistry, Vol. 70, No. 1-3, pp. 235-242. https://doi.org/10.1016/S0304-4203(00)00029-3
  28. D. Tiwari, H. U. Kim, B. J. Choi, S. M. Lee, O. H. Kwon, K. M. Choi and J. K. Yang, 2007, "Ferrate(VI); A Green Chemical for the Oxidation of Cyanide in Aqueous-Waste Solutions", Journal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering, Vol. 42, No. 6, pp. 803-810. https://doi.org/10.1080/10934520701304674
  29. N. Graham, C. C. Jiang, X. Z. Li, J. Q. Jiang and J. Ma, 2004, "The Influence of pH on the Degradation of Phenol and Chlorophenols by Potassium Ferrate", Chemosphere, Vol. 56, pp. 949-956. https://doi.org/10.1016/j.chemosphere.2004.04.060
  30. F. J. Benitez, J. Beltran-Heredia, J. L. Acero and F. J. Rubio, 2000, "Rate Constants for the Reactions of Ozone with Chlorophenols in Aqueous Solutions", Journal of Hazardous Materials, Vol. 79, No. 3, pp. 271-285. https://doi.org/10.1016/S0304-3894(00)00269-7
  31. Z. Macova, K. Bouzek, J. Hives, V. K. Sharma, R. J. Terryn and J. C. Baum, 2009, "Research Progress in the Electrochemical Synthesis of ferrate(VI)", Electrochimica Acta, Vol. 54, No. 10, pp. 2673-2683. https://doi.org/10.1016/j.electacta.2008.11.034
  32. W. F. Wagner, J. R. Gurip and E. N. Hart, 1952, "Factors Affecting Stability of Aqueous Potassium Ferrate(VI) Solutions", Anal. Chem., Vol. 24, No. 9, pp. 1497-1498. https://doi.org/10.1021/ac60069a037

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