• Title/Summary/Keyword: Solution state structure

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Effect of centrifugation on the structure and properties of silk sericin

  • Park, Chun Jin;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.33 no.2
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    • pp.144-148
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    • 2016
  • Recently, silk sericin has been studied extensively for biomedical and cosmetic applications because of its unique properties, including UV resistance and wound healing ability. For use in applications, sericin is fabricated in various forms including films and gels. However, the mechanical properties of sericin are too weak. In this basic study on improving the mechanical properties of sericin, a silk sericin aqueous solution was separated into two layers by centrifugation. The solution viscosity, molecular conformation, and mechanical properties of each separation layer of the sericin were examined. Sericin from the lower layer had a higher solution viscosity and film mechanical properties (strength and strain) than that from the upper layer, implying that sericin from the lower layer had a higher molecular weight than that from the upper layer. The molecular conformation of the sericin films varied depending on the casting solvent. In aqueous solution, the sericin film from the lower layer showed a ${\beta}$-sheet conformation, whereas that from the upper layer displayed a random coil conformation. All the sericin films showed a highly ${\beta}$-sheet-crystallized state when cast in formic acid, regardless of the separation layer.

Swelling and Fibrillation of Lyocell Fibers in Water and NaOH Solution (Lyocell 섬유소재의 알칼리 팽윤과 피브릴화 거동)

  • Min, Byung-Ghyl;Jeong, Young-Jin;Kim, Chang-Whan;Oh, Young-Sae
    • Fashion & Textile Research Journal
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    • v.1 no.1
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    • pp.56-61
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    • 1999
  • Swelling and fibrillation of two kinds of lyocell, $Tencel^{(R)}$ and $Lyocell^{(R)}$, were investigated using polarizing and scanning electron microscope (SEM). $Tencel^{(R)}$ of a representative lyocell showed that loop tenacity which is related to wrinkle and resilience of fiber does not show significant reduction in wet state. Two kinds of lyocell exhibited surprising degree of swelling in aqueous NaOH solution under free tension. Diameters of $Tencel^{(R)}$ and $Lyocell^{(R)}$ swelled up to 670% and 830%, respectively in the range of around 10% NaOH concentration. Molecular orientation estimated by birefringence also reduced remarkably in alkaline solution. Moreover, diameter and birefringence which changed in alkaline solution did not recovered to original level even after washing and drying. Fibrillation of $Lyocell^{(R)}$ fiber observed by SEM seems to be easier than that of $Tencel^{(R)}$. In order to understand the difference between $Tencel^{(R)}$ and $LyoceJl^{(R)}$, further study on the structure of the two fibers will be followed.

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Mechanical properties of new stainless steel-aluminum alloy composite joint in tower structures

  • Yingying Zhang;Qiu Yu;Wei Song;Junhao Xu;Yushuai Zhao;Baorui Sun
    • Steel and Composite Structures
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    • v.49 no.5
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    • pp.517-532
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    • 2023
  • Tower structures have been widely used in communication and transmission engineering. The failure of joints is the leading cause of structure failure, which make it play a crucial role in tower structure engineering. In this study, the aluminum alloy three tube tower structure is taken as the prototype, and the middle joint of the tower was selected as the research object. Three different stainless steel-aluminum alloy composite joints (SACJs), denoted by TA, TB and TC, were designed. Finite element (FE) modeling analysis was used to compare and determine the TC joint as the best solution. Detail requirements of fasteners in the TC stainless steel-aluminum alloy composite joint (TC-SACJ) were designed and verified. In order to systematically and comprehensively study the mechanical properties of TC-SACJ under multi-directional loading conditions, the full-scale experiments and FE simulation models were all performed for mechanical response analysis. The failure modes, load-carrying capacities, and axial load versus displacement/stain testing curves of all full-scale specimens under tension/compression loading conditions were obtained. The results show that the maximum vertical displacement of aluminum alloy tube is 26.9mm, and the maximum lateral displacement of TC-SACJs is 1.0 mm. In general, the TC-SACJs are in an elastic state under the design load, which meet the design requirements and has a good safety reserve. This work can provide references for the design and engineering application of aluminum alloy tower structures.

Effect of geometry of underground structure and electrode on electrical resistance measurement: A numerical study

  • Tae-Young Kim;Hee-Hwan Ryu;Meiyan Kang;Suyoung Choi;Song-Hun Chong
    • Geomechanics and Engineering
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    • v.39 no.1
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    • pp.105-113
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    • 2024
  • Recently, electrical resistivity surveys have been used to obtain information related to underground structures including burial structure type and depth. However, various field conditions hinder understanding measured electrical resistance, and thus there is a need to understand how various geometries affect electrical resistance. This study explores the effect of geometric parameters of a structure and electrodes on electrical resistance in the framework of the finite element method. First, an electrical resistance module is developed using the generalized mesh modeling technique, and the accuracy of the module is verified by comparing the results with the analytical solution for a cylindrical electrode with conical tip. Then, 387 cases of numerical analysis including geometric parameters of a buried structure and electrodes are conducted to quantitatively estimate the detection depth under a steady-state current condition. The results show that electrical resistance is increased as (1) shallower burial depth of structure, (2) closer distance between ground electrode and structure, (3) longer horizontal electrode distance. In addition, the maximum detection depth corresponding to converged electrical resistance is deeper as (4) closer distance between ground electrode and structure, (5) shorter horizontal electrode distance. The distribution of the electric potential around the electrodes and underground structure is analyzed to provide a better understanding of the measured electrical resistance. As engineering purpose, the empirical equation is proposed to calculate maximum detection depth as first approximation.

Structural Studies of Membrane Protein by Solid-state NMR Spectroscopy (고체상 핵자기공명 분광법을 이용한 막단백질의 구조연구)

  • Kim, Yongae
    • Analytical Science and Technology
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    • v.17 no.5
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    • pp.388-392
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    • 2004
  • Structural studies of membrane proteins, importantly involving interpretation of genomics information, many signaling pathway and major drug target for drug discovery, are having difficulty in characterizing the function using conventional solution nmr spectroscopy and x-ray crystallography because phospholipid bilayers hindered fast tumbling and crystallization. Here, we studied the structure of the pf1 coat protein in oriented phospholipid bilayers by home-built solid-state NMR probe. Bacteriophage pf1 was purified from Paeudomonas Aeruginosa and coat protein of bacteriophage pf1 was isolated from DNA and other proteins.

Submodule Level Distributed Maximum Power Point Tracking PV Optimizer with an Integrated Architecture

  • Wang, Feng;Zhu, Tianhua;Zhuo, Fang;Yi, Hao;Shi, Shuhuai
    • Journal of Power Electronics
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    • v.17 no.5
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    • pp.1308-1316
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    • 2017
  • The distributed maximum power point tracking (DMPPT) concept is widely adopted in photovoltaic systems to avoid mismatch loss. However, the high cost and complexity of DMPPT hinder its further promotion in practice. Based on the concept of DMPPT, this paper presents an integrated submodule level half-bridge stack structure along with an optimal current point tracking (OCPT) control algorithm. In this full power processing integrated solution, the number of power switches and passive components is greatly reduced. On the other hand, only one current sensor and its related AD unit are needed to perform the ideal maximum power generation for all of the PV submodules in any irradiance case. The proposal can totally eliminate different small-scaled mismatch effects in real-word condition and the true maximum power point of each PV submodule can be achieved. As a result, the ideal maximum power output of the whole PV system can be achieved. Compared with current solutions, the proposal further develops the integration level of submodule DMPPT solutions with a lower cost and a smaller size. Moreover, the individual MPPT tracking for all of the submodules are guaranteed.

Swelling and Shrinking Behavior of Lyocell Fibers

  • Donkai, Nobuo;Sasaki, Hiroari;Kasahara, Katsuji
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.17-18
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    • 2003
  • Swelling behaviors of Lyocell and Polynosic fibers are investigated by measuring fiber sizes in ferric sodium tartrate complex (FeTNa) and NaOH solution. They showed an anisotropic swelling behavior, i.e., a large expansion in a radius and small shrinking in a longitudinal direction. Birefringent structure was maintained in Lyocell fibers in the swollen state but not in Polynosic fibers for both solvent systems.

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The Oxygen Potential of Urania Nuclear Fuel During Irradiation

  • Park, Kwang-Heon
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.72-77
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    • 1998
  • A defect model for UO$_2$ fuel containing soluble fission products was devised based on the defect structure of pure and doped uranias. Using the equilibrium between fuel solid-solution and fission-products and the material balance within the fuel, a tracing method to get the stoichiometry change of urania fuel with burnup was made. This tracing method was applied to high burnup urania fuel and DUPIC fuel. The oxygen potential of urania fuel turned out to increase slightly with burnup. The stoichiometry change was calculated to be negligible due to the buffering role f Mo. The oxygen potential of DUPIC fuel out to be sensitive to the initial chemical state of Mo in the fuel.

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Synthesis of New Bicyclic Aziridines Containing Chalcone Analogs and Investigation of Their Photochromic Properties

  • Besharati-Seidani, Tayebeh;Mahmoodi, Nosrat O.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.875-883
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    • 2013
  • Ten new derivatives of 1,3-diazabicyclo[3.1.0]hex-3-enes linked via ether linkage to chalcones were synthesized and characterized by UV, FT-IR, $^1H$ NMR and $^{13}C$ NMR spectral techniques. The spectra of all synthesized compounds, confirmed structure-photochromic behavior relationships (SPBR) both in solution or in solid state by irradiation under UV light at 254 nm. In other efforts for first time photochromic behavior of ketoaziridines has been investigated.

Structure Study of Inclusion Complex of ${\beta}-Cyclodextrin$ and Aspirin (${\beta}$-시클로덱스트린과 아스피린의 포접화합물의 구조에 관한 연구)

  • Choi, Hee-Sook
    • Journal of Pharmaceutical Investigation
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    • v.21 no.4
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    • pp.223-230
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    • 1991
  • The structural specificity and the chemical dynamics between ${\beta}-cyclodextrin$ and aspirin were studied by FT-IR UN, $^1H$ NMR. $^{13}C NMR$. and FAB-MS spectroscopy in solution and solid state, A stable solid inclusion complex was prepared by the recrystallization method, From the spectral changes of the host and guest molecules, orientational preference for binding in the cyclodextrin cavity was determined.

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