• Bulletin of the Korean Chemical Society
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• v.30 no.3
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• pp.556-560
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• 2009

Aggregation behavior of three kinds of benzindocarbocyanine dyes in aqueous methanol solution was studied by UV-Vis absorption spectrum. The results indicated that the three dyes all existed monomer-dimer equilibrium in aqueous methanol solution (concentration range $10^{−5}\;to\;10^{−6}$ M) at 25.0$\sim$41.0 ${^{\circ}C}$ for Dye 1, 28.0$\sim$49.0 ${^{\circ}C}$ for Dye 2 and 26.0$\sim$47.0 ${^{\circ}C}$ for Dye 3. The fundamental property of the three dyes as the dimeric association constant KD, the dimeric free energy ${\Delta$}G_D, the dimeric entropy ${\Delta$}S_D, and the dimeric enthalpy ${\Delta$}H_D were determined. The ${\Delta$}H_D of three dyes: Dye 1, Dye 2 and Dye 3 was -42.5, -15.1 and -18.9 kJ/mol, respectively. The experimental observations were the subject of a theoretical study including the ground-state geometries which were fully optimized using DFT at B3LYP/6-31G level. The effect of dye molecule structure on ${\Delta$}H_D was discussed by theoretical calculations.

• Journal of Magnetics
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• v.14 no.4
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• pp.161-164
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• 2009

Iron-doped $Sn_{1-x}Fe_xO_2$ (x = 0.0, 0.05, 0.1, 0.2, 0.33) thin films on Si(100) substrates and powders were prepared by a chemical solution process. The x-ray diffraction (XRD) patterns of the $Sn_{1-x}Fe_xO_2$ thin films and powders showed a polycrystalline rutile tetragonal structure. Thermo gravimetric (TG) - differential thermal analysis (DTA) showed the final weight loss above $430{^{\circ}C}$ for all powder samples. According to XRD Rietveld refinement of the powders, the lattice parameters and unit cell volume decreased with increasing Fe content. The magnetic properties were characterized using a vibrating sample magnetometer (VSM) and M$\ddot{o}$ssbauer spectroscopy. The thin film samples with x = 0.1 and 0.2 showed paramagnetic properties but thin films with x = 0.33 exhibited ferromagnetic properties at room temperature. Mossbauer studies revealed the $Fe^{3+}$ valence state in the samples. The ferromagnetism in the samples can be interpreted in terms of the direct ferromagnetic coupling of ferric ions via an electron trapped in a bridging oxygen deficiency, which can be explained using the F-center exchange model.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.14 no.9
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• pp.3745-3761
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• 2020

Low-rank representation methods already achieve many applications in the image reconstruction. However, for high-gradient image patches with rich texture details and strong edge information, it is difficult to find sufficient similar patches. Existing low-rank representation methods usually destroy image critical details and fail to preserve edge structure. In order to promote the performance, a new representation-based image super-resolution reconstruction method is proposed, which combines gradient domain guided image filter with the structure-constrained low-rank representation so as to enhance image details as well as reveal the intrinsic structure of an input image. Firstly, we extract the gradient domain guided filter of each atom in high resolution dictionary in order to acquire high-frequency prior information. Secondly, this prior information is taken as a structure constraint and introduced into the low-rank representation framework to develop a new model so as to maintain the edges of reconstructed image. Thirdly, the approximate optimal solution of the model is solved through alternating direction method of multipliers. After that, experiments are performed and results show that the proposed algorithm has higher performances than conventional state-of-the-art algorithms in both quantitative and qualitative aspects.

• Structural Engineering and Mechanics
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• v.71 no.1
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• pp.45-56
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• 2019

A modified mechanical model of pre-pressed spring self-centering energy dissipation (PS-SCED) brace is proposed, and the hysteresis band is distinguished by the indication of relevant state variables. The MDOF frame system equipped with the braces is formulated in an incremental form of linear acceleration method. A multi-objective genetic algorithm (GA) based brace parameter optimization method is developed to obtain an optimal solution from the primary design scheme. Parameter sensitivities derived by the direct differentiation method are used to modify the change rate of parameters in the GA operator. A case study is conducted on a steel braced frame to illustrate the effect of brace parameters on node displacements, and validate the feasibility of the modified mechanical model. The optimization results and computational process information are compared among three cases of different strategies of parameter change as well. The accuracy is also verified by the calculation results of finite element model. This work can help the applications of PS-SCED brace optimization related to parameter sensitivity, and fulfill the systematic design procedure of PS-SCED brace-structure system with completed and prospective consequences.

• ETRI Journal
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• v.30 no.6
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• pp.807-817
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• 2008

We present a low-density parity-check (LDPC)-based, threaded layered space-time-frequency system with emphasis on the iterative receiver design. First, the unbiased minimum mean-squared-error iterative-tree-search (U-MMSE-ITS) detector, which is known to be one of the most efficient multi-input multi-output (MIMO) detectors available, is improved by augmentation of the partial-length paths and by the addition of one-bit complement sequences. Compared with the U-MMSE-ITS detector, the improved detector provides better detection performance with lower complexity. Furthermore, the improved detector is robust to arbitrary MIMO channels and to any antenna configurations. Second, based on the structure of the iterative receiver, we present a low-complexity belief-propagation (BP) decoding algorithm for LDPC-codes. This BP decoder not only has low computing complexity but also converges very fast (5 iterations is sufficient). With the efficient receiver employing the improved detector and the low-complexity BP decoder, the proposed system is a promising solution to high-data-rate transmission over selective-fading channels.

• Structural Monitoring and Maintenance
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• v.3 no.2
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• pp.115-127
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• 2016

It is a challenging problem of assessing the location and extent of structural damages with vibration measurements. In this paper, an improved Extended Kalman filter (EKF) with Tikhonov regularization is proposed to identify structural damages. The state vector of EKF consists of the initial values of modal coordinates and damage parameters of structural elements, therefore the recursive formulas of EKF are simplified and modal truncation technique can be used to reduce the dimension of the state vector. Then Tikhonov regularization is introduced into EKF to restrain the effect of the measurement noise for improving the solution of ill-posed inverse problems. Numerical simulations of a seven-story shear-beam structure and a simply-supported beam show that the proposed method has good robustness and can identify the single or multiple damages accurately with the unknown initial structural state.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.107-110
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• 1999

The ultrasonic spray method was employed to make (Y,Gd)BO$_3$:Eu Phosphor, and its optical properties under 147nm VUV and 254 nm UV excitations were characterized and then compared with that produced by the solid-state reaction. The mixed solution of acetate hydrates of Y, Gd, Eu and boric acid diluted in water or methanol was used as the precursor fur the spray. It was found that (Y,Gd)BO$_3$:Eu phosphor made by this ultrasonic spray had a spherical shape and fine particle size of 1${\mu}{\textrm}{m}$. The crystalline structure for the as-sprayed phosphor was amorphous, but it converted into the same polycrystalline phase of solid state reaction after post heat treatment at 110$0^{\circ}C$ for 2hr. The emitting intensity under VUV and UV excitations for the spray-formed (Y,Gd)BO$_3$:Eu phosphor, however, was inferior to the later one. The excitation spectra were also studied and compared under VUV and UV excitations to explain the change of emitting intensity with Gd substitution in (Y$_{1-x}$ Gd$_{x}$)BO$_3$:Eu Phosphors made by spray and solid state reaction.on.

• Macromolecular Research
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• v.10 no.6
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• pp.311-317
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• 2002

The quantitative analysis of polymer micelles consisting of amphiphilic block copolymers was carried out by small-angle neutron scattering (SANS). The block copolymers, made of poly(2-ethoxyethyl vinyl ether-b-2-hydroxyethyl vinyl ether)(poly(EOVE-b-HOVE)), exhibited a sharp morphological transition from a homogeneous solution to a micelle structure with increasing temperature. This transition is accompanied by a formation of spherical domains of poly(EOVE) with a radius around 200 $\AA$. The variations of the size and its distribution of the domains were investigated as a function of polymer concentration and temperature. The validity of SANS analysis, including the wavelength- and incident-beam-smearing effects of the SANS instrument, was examined with a pre-calibrated polystyrene latex.

• Journal of Power Electronics
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• v.17 no.4
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• pp.1058-1070
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• 2017

This paper proposes a novel active damping scheme to suppress LCL-filter resonance with only grid-current feedback control in grid-connected voltage-source converters. The idea comes from the concept of the model reference adaptive control (MRAC). A detailed theoretical derivation is given, and the effectiveness of this method is explained based on its physical nature. According to the control structure of this method, the active damping compensator, which is essentially a second order resonant integrator (SORI) filter, provides an effective solution to damp LCL resonance and to eliminate the need for additional sensors. Compared with extra feedback methods, the cost and complexity are reduced. A straightforward tuning procedure for the active damping method has been presented. A stability analysis is illustrated in the discrete domain while considering a one-step delay. Finally, experimental results are presented to validate the analysis and to demonstrate the good performance of the proposed method.

• Advances in nano research
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• v.14 no.2
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• pp.127-139
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• 2023

This paper studies the free vibration behavior of bi-dimensional functionally graded (BFG) nanobeams subjected to arbitrary boundary conditions. According to Eringen's nonlocal theory and Hamilton's principle, the underlying equations of motion have been obtained for BFG nanobeams. Moreover, the variable substitution method is utilized to establish the structure's state-space differential equations, followed by forming the dynamic stiffness matrix based on state-space differential equations. In order to compute the natural frequencies, the current study utilizes the Wittrick-Williams algorithm as a solution technique. Moreover, the nonlinear vibration frequencies calculated by employing the proposed method are compared to the frequencies obtained in previous studies to evaluate the proposed method's performance. Some illustrative numerical examples are also given in order to study the impacts of the nonlocal parameters, material property gradient indices, nanobeam length, and boundary conditions on the BFG nanobeam's frequency. It is found that reducing the nonlocal parameter will usually result in increased vibration frequencies.