• Resources Recycling
• /
• v.20 no.6
• /
• pp.56-62
• /
• 2011

Zirconium is used in nuclear reactors as a structural material due to its excellent corrosion resistance and to low neutron crosssection. Variation in the distribution and solubility of Zr(IV) with solution pH was obtained. Distribution of Zr(IV) containing species in HCl and $HNO_3$ solution was analyzed by considering the complex formation of Zr(IV) species with the anion of the inorganic acid. Bromley interaction parameter between $ZrO^{2+}$ and nitrate ion was estimated by using the reported data on the solvent extraction of Zr(IV) by Cyanex272 from $HNO_3$ solution. This Bromley parameter can be utilized in calculating extraction isotherm of Zr(IV) and in predicting the separation factor between Zr(IV) and Hf(IV).

• The Pure and Applied Mathematics
• /
• v.9 no.1
• /
• pp.19-30
• /
• 2002

We consider one class of bursting oscillation models, that is square-wave burster. One of the interesting features of these models is that periodic bursting solution need not to be unique or stable for arbitrarily small values of a singular perturbation parameter $\epsilon$. Recent results show that the bursting solution is uniquely determined and stable for most of the ranges of the small parameter $\epsilon$. In this paper, we present a condition of uniqueness and stability of periodic bursting solutions for all sufficiently small values of $\epsilon$ > 0.

• Honam Mathematical Journal
• /
• v.32 no.2
• /
• pp.193-202
• /
• 2010

We investigate the estimation of the moisture transfer coefficients in porous media by optimization technique which minimizes the functional defined by the squares error of the numerical solution of an inverse diffusion problem from their experimental values of the moisture content at the some time-steps. In this paper, we solve a diffusion equation numerically by the control volume finite element methods.

• Bulletin of the Korean Chemical Society
• /
• v.8 no.1
• /
• pp.19-26
• /
• 1987

A statistical thermodynamical treatment for polymer adsorption from solution is presented. The canonical partition function for the polymer solution in the presence of a surface or an impermeable interface is formulated on the basis of usual quasi-crystalline lattice model, Bragg-Williams approximation of random mixing, and Pak's simple treatment of liquid. The present theory gives the surface excess ${\Gamma}_{exc}$ and the surface coverage ${\phi}^s_2$ of the polymer as a function of the chain length x, the Flory-Huggins parameter x, the adsorption energy parameter $x_s$, and polymer concentration $v_2$. Present theory is also applicable to the calculation of interfacial tension of polymer solution against water. For the idealized flexible polymer, interfacial tensions according to our theory fit good to the experimental data to the agreeable degrees.

• Journal of the Korean Institute of Telematics and Electronics
• /
• v.26 no.8
• /
• pp.1187-1196
• /
• 1989

In this paper, a method for computing the capacitance parameter for a multi-interconnection line in a multilayered dielectric region is presented. The number of interconnection lines and the number of dielectric layers are arbitrary, and the interconnection lines are finite cross section or infinite cross section. The surface of lines and dielectric interface are divided into subsection. The surface charge density of each subsection is a constant step-pulse function for each subsection. After the solution of surface charge density is effected by the method of moments, capacitance parameter is calculated.

• Advances in concrete construction
• /
• v.15 no.5
• /
• pp.313-319
• /
• 2023

In this paper, the analytic solution has been found by using truncation approach. With the help of suitable substitution, different physical parameters are yielded in their non-dimensional form. The governing boundary layer partial differential equations are reduced to a set of ordinary ones by using appropriate similarity transformations. The velocity profile across the domain have also been taken into account. The effect normal velocity profiles buoyancy parameter, slip parameter, shrinking parameter, Casson fluid parameter on the heat profile. It is found that the normal velocity profiles rise with the buoyancy parameter and for the slip parameter. It is observed that the normal velocity profile decreases with the increase of shrinking parameter. The reverse behiour is found for the Casson fluid parameter. The results are numerically computed, analyzed and discussed. For the efficiency of present model, the results are compared with earlier investigations.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.5 no.4
• /
• pp.27-38
• /
• 2001

A mechanical lumped parameter model is proposed for the dynamic modeling of a semi-infinite reservoir. A semi-analytic transmitting boundary is derived for a semi-infinite 2-D reservoir of constant depth. The characteristics of the solution are examined in both frequency and time domains. Mass, damping and spring coefficients of the mechanical model are obtained to preserve the major features of the solution such as eigenfrequencies and the shapes of Bessel functions that appear as kernels in the convolution integrals. The lumped parameter model in its final form consists of two masses, a spring and two dampers for each eigenfrequency. Application examples demonstrated that the new lumped parameter model could be used for the time domain analysis of dam-reservoir systems.

• Journal of Industrial Technology
• /
• v.22 no.B
• /
• pp.35-44
• /
• 2002

To find the optimal solution as rapidly and exactly as possible with Nelder-Mead simplex algorithm, the present values of the reflection, expansion, contraction and/or shrink parameters of this algorithm are needed to be changed at appropriate time during the search process. The reflection parameter is selected in this study in order to be changed because reflection, expansion and contraction process can be simultaneously effected by only this parameter. Two independent indices for determining whether the present value of the reflection parameter of this algorithm should be changed or not during the search process are suggested in this study. Those indices were made of the equations of Nelder-Mead simplex algorithm's convergence criterion and Dennis-Wood's convergence criterion, respectively. It is appeared that the optimal solution can be find with smaller numbers of objective function evaluation than the original Nelder-Mead's one with fixed parameter when the those indices are used during the search process. and the more remarkable reduction effect of the number of an objective function evaluation can be obtained when the latter index is used.

• Bulletin of the Korean Chemical Society
• /
• v.16 no.11
• /
• pp.1084-1088
• /
• 1995

A complete solid solution (SrLaAl1-xNixO4) between insulating SrLaAlO4 and metallic SrLaNi(Ⅲ)O4 oxides were prepared under high oxygen pressure (1.5 kbar, 800 ℃). They have tetragonal K2NiF4-type structure in all the solid solution range. Compared with lattice parameters of the same solid solution prepared under normal condition (1 bar, 1200 ℃), large decrease in the c-parameter was induced by high pressure treatment while no noticeable variation of the a-parameter was observed. Although marked changes of structural parameters, magnetic susceptibilities, and electron paramagnetic resonance spectra were consistently occurred before and after x=0.5, overall behaviors were essentially the same with those of solid solution prepared under normal condition. Such a phenomenon is explained by assuming the formation of partially filled narrow σ*x2-y2 band for x>0.5. Lattice contraction along the c-axis by high pressure treatment seems not to broaden this band. Particularly, the continuous absorption characteristic of a high free carrier concentration for x>0.5 and the absence of Ni-O in-plane stretching mode in the infrared absorption spectra supports this picture. However, the conductivities increasing with temperature for all solid solution suggest that some localization character, of probably Anderson type, remains for x>0.5.

• 한국전산유체공학회:학술대회논문집
• /
• 2008.03b
• /
• pp.506-509
• /
• 2008

Mathematical models have been developed to calculate hydrodynamic characteristics of perforated-wall structures. Most of the models separate the fluid regions into front and back of the wall, assume the solution in each region, and calculate the solution by using the matching condition at the wall. The matching condition involves the permeability parameter, which can be calculated by the methods proposed by Mei et al. or Sollitt and Cross. In this study, we compare these two methods. The former is advantageous because all the related variables are known, but it gives wrong result in the limit of long waves, i.e. zero transmission and perfect reflection of very long waves. In deep water, the latter predicts smaller transmission and larger reflection than the former, and vice versa in shallow water. In the latter method, the friction coefficient decreases as the wall thickness or the porosity of the wall increases.