• 한국전기전자재료학회논문지
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• 제13권5호
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• pp.451-457
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• 2000

Experimental investigations on the effect of two kinds of additives ; aqueous NaOH solution and ammonia(NH$_3$) for removal of NOx and SO$_2$ simultaneously by corona discharge were carried out. The simulated combustion flue gas was[NO(0.02[%])-SO$_2$(0.08[%])-$CO_2$-Air-$N_2$] Volume percentage of aqueous NaOH solution used was 20[%] and $N_2$flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution Ammonia gas(14.81[%]) balanced by argon was diluted by air. NH$_3$ molecular ratios(MR) based on [NH$_3$] and [NO+SO$_2$] were 1, 1.5 and 2.5 The vapour of aqueous NaOH solution and NH$_3$was introduced to the main simulated combustion flue gas duct through injection systems which were located at downstream of corona discharge reactor. NOx(NO+NO$_2$) removal rate by injecting the vapour of aqueous NaOH solution was much better than that by injecting NH$_3$however SO$_2$removal rate by injecting NH$_3$was much better than that by injecting the vapour of aqueous NaOH SO$_2$removal rate slightly increased with increasing applied voltage. When the vapour of aqueous NaOH solution and NH$_3$were simultaneously injection NOx and SO$_2$ removal rate were significantly increased.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.102-108
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• 2006

On the refutation demanded for a control of various toxic substances. PCBs(poly chlorinated biphenyl) has a fatal poisonous matter in the ecosystem and the environmental pollution as it Is a kind of stable chemical substance. Especially, the gross Product of PCBs is estimated at about one million tonnage all over the world. However it is kept on storing in untreated state, then has a deterioration by the Prolonged storage and a risk of overflowing. Therefore, this research examined the fundamental characteristics of combustion and emission for the target of using the IPA (iso-propyl alcohol) solution as a part of PCBs control. IPA was filled to three kinds of Vessel, i.e. Vessel I, II, and III, and then was investigated as follows combustion shape, flame temperature. mass burning velocity, and PM(Particulate matter). A radial thermometer and a C-A thermocouple measured the flame temperature, and the optical extinction method by using He-Ne laser and the filter weight method used in the PM measurement. As a result, with an increasing of L/S ratio, the flame length become shorter and the burning velocity is more rapid, but the particulate matters is higher. It is supposed that the air flow rate is high on Vessel. and then the combustion is Promoted in the surface area of the upstream zone. The future works plan to investigate the characteristics with an using of the mixing of IPA and PCBs

• 대한기계학회논문집B
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• 제27권11호
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• pp.1579-1586
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• 2003

A gun-type burne. fur a LPG(Liquified Petroleum Gas) boiler was utilized for hydrogen combustion. The study was performed to obtain fundamental data prior to the design of a very low NO$\_$x/, hydrogen-fueled burner. First, numerical simulations were performed to predict mixing characteristics between air and fuel flows, and temperature distributions, etc. Experimental study was then performed to find out flame lengths, temperature distributions, and NO$\_$x/ concentrations. The results showed that a gun-type burner for a LPG boiler can be successfully used for hydrogen combustion without any major retrofitting. The hydrogen flame was very stable and 75 ppm of NO$\_$x/ in average was observed for the conditions considered in this study. Hydrogen combustion could be therefore a solution to avoid the problem of green-house gas(CO$_2$) if hydrogen becomes cost-effective.

• 대한기계학회논문집B
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• 제33권7호
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• pp.552-558
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• 2009

An experimental study using the combustor with branch tube was conducted in order to model the industry combustor with FGR (flue gas recirculation) system and to study a thermo-acoustic instability generated by a branch tube. The branch tube is a structure used to modify a system geometry and then to change its pressure field, and the thermo-acoustic instability, usually occurs in a confined geometry, can result in serious problems on industrial combustors. Thus understanding of the instability created by modifying geometry of combustor is necessary to design and operate combustor with FGR system. Pressure fluctuation in the combustion chamber was observed according to diameter and length of branch and it was compared with the solution of 1-D wave equation. It was found that branch tube affects the pressure field in the combustion chamber, and the pressure fluctuation in the combustion chamber was reduced to almost zero when phase difference between an incipient wave in the combustion chamber and a reflected wave in the branch tube is $\pi$ at the branch point. Also, the reduction of pressure fluctuation is irrespective of the installed height of branch tube if it is below $h^*=0.9$ in the close-open tube and open-open tube.

• 한국추진공학회지
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• 제6권2호
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• pp.75-84
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• 2002

고체 추진 로켓 내부 연소실의 비정상 유동을 수치적으로 해석하였다. 완전 보존식을 이용하여 2 차원 축-대칭 연소실 안의 연소 불안정을 해석하기 위한 수치 기법을 구성하였는데 비정상 유동을 해석하기 위한 수정된 $\kappa$-$\varepsilon$ 난류 모델이 사용되었다. 이산화한 지배 방정식은 연관된 경계 조건을 포함하여 dual time-stepping 방법으로 시적분 하였다. 정상 상태의 계산을 기반으로 연소실 내의 천이 압력파의 비정상 상태를 수치적으로 모사하기 위하여 압력 펄스 및 압력 변동을 연소실 상단에 부과하였다. 로켓 모터 연소실 내의 다양한 정상 상태 및 비정상 상태의 특성을 계산 및 해석하였다.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2000년도 춘계총회,특별강연,심포지움,연구발표회
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• pp.145.2-145.2
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• 2000

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 추계총회 및 연구발표회 초록집
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• pp.198.2-198
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• 2003

• 한국재료학회지
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• 제8권7호
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• pp.616-620
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• 1998

착체증합법 및 연소합성법에 의해 Zn_{0.994}Mn_{0.006}Ga_2O_4$녹색형광체 분말을 합성하였으며, 이들의 분말 및 발광특성을 XRD, SEM, BET, PL 등을 사용하여 조사하였고, 이를 고상반응법에 의하여 합성한 시료와 비교하였다. 착체중합법과 연소합성법에 의해 합성한 시료는 각각 $500^{\circ}C$와 $400^{\circ}C$에서 단일 스피텔 상이 생성되었으며, 이들의 입자크기는 고상반응에 의해 합성된 분말에 비하여 작았다. 한편, 착체중합법에 의하여 합성한 분말의 발광강도는 열처리 온도가 $900^{\circ}C$일 때, 연소합성법에서는 반응온도가 $400^{\circ}C$일 때 각각 최대값을 나타내었다.

• 한국재료학회지
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• 제17권7호
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• pp.382-385
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• 2007

[ $LaFeO_3$ ] powders were prepared as the oxidation catalyst materials to reduce the emission of particulate matters from diesel engine and their catalytic effects on the oxidation of carbon were investigated. Solution combustion method was employed for the powder synthesis, which uses highly exothermic and selfsustaining reactions. In this study $LaFeO_3$ powders were synthesized at $400^{\circ}C$ as varying the ratio ($\Phi$) of fuel (citric acid) and oxidizer (metal nitrate), and their phase and carbon ignition property were examined. As $\Phi$ decreases, the crystallinity of synthesized $LaFeO_3$ powders enhanced. By calcining at $700^{\circ}C$, all the powders synthesized at various $\Phi$ fully crystallized. The calcined $LaFeO_3$ powders showed carbon ignition temperature as low as $501{\sim}530^{\circ}C$, which implied the decrease of the ignition temperature by $120{\sim}150^{\circ}C$.

• Nuclear Engineering and Technology
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• 제54권3호
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• pp.1062-1070
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• 2022

In the present communication, pure and stable α-Bismuth Oxide (Bi₂O₃) nanoparticles (NPs) were synthesized by low temperature solution combustion method using urea as a fuel and calcined at 500℃. The synthesized sample was characterized by using powder X-ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Energy dispersive X-ray analysis (EDAX), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR) and UV-Visible absorption spectroscopy. The PXRD pattern confirms the formation of mono-clinic, stable and low temperature phase α-Bi₂O₃. The direct optical energy band gap was estimated by using Wood and Tauc's relation which was found to be 2.81 eV. The characterized sample was studied for X-ray/gamma ray shielding properties in the energy range 0.081-1.332 MeV using NaI (Tl) detector and multi channel analyzer (MCA). The measured shielding parameters agrees well with the theory, whereas, slight deviation up to 20% is observed below 356 keV. This deviation is mainly due to the influence of atomic size of the target medium. Furthermore an accurate theory is necessary to explain the interaction of X-ray/gamma ray with the NPs.The present work opens new window to use this facile, economical, efficient, low temperature method to synthesize nanomaterials for X-ray/gamma ray shielding purpose.