• 해양환경안전학회지
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• 제22권1호
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• pp.138-144
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• 2016

티타늄은 표면에 형성되는 보호성 부동태 피막 때문에 일반부식과 해수에서 내식성이 강하지만 염산, 황산, 인산 등의 산에서는 보호성 산화물 피막이 파괴된다고 알려져 있다. 본 연구에서는 Ti에 Al 및 V등을 첨가한 ${\alpha}+{\beta}$계에 대하여 $1066^{\circ}C$와 $966^{\circ}C$에서 5시간 용체화 열처리를 실시하고, 이 시편을 $550^{\circ}C$, $600^{\circ}C$, 및 $650^{\circ}C$에서 각각 1시간, 4시간, 8시간 및 16시간 시효열처리한 후 마이크로비커스 경도를 측정하고, 이 시편을 1N $H_2SO_4$ 용액에서 전기화학적 분극법으로 부식을 계측하였으며, 분극을 마친 시편의 표면을 현미경 조직사진으로 부식상태를 검토하였다. 시험 결과 용체화열처리한 시편이 모재와 시효열처리한 시편보다 높은 내식성을 나타내며. 용체화 온도가 높고 시간이 길어질수록 내식성은 증가하였다.

• 동력기계공학회지
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• 제20권5호
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• pp.29-36
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• 2016

Aluminum alloys have been widely used in engine materials, cold & hot-water storage vessels and piping etc., Furthermore, the aluminum alloy of AC8A have been widely used in mold casting material of engine piston for various vehicles because of its properties of temperature, wear and corrosion resistance. Therefore, it is considered that evaluation of corrosion resistance as well as wear resistance of AC8A material is also important to improve its property and to prolong its lifetime. In previous paper, the effect of solution($510^{\circ}C$:4hrs) and tempering($190^{\circ}C$: 16, 24, and 36 hrs)heat treatments to corrosion resistance and hardness were investigated using electrochemical method. In this study, in order to examine completely the effect of the tempering hours to hardness variation and corrosion resistance, the results of solution($510^{\circ}C$:4hrs) and tempering($190^{\circ}C$: 2, 4, 8 and 12hrs)heat treatments to hardness and corrosion resistance were investigated using electrochemical method. The hardness decreased with solution heat treatment compared to mold casting condition, but its value increased with tempering heat treatment. Furthermore, the corrosion resistance increased with decreasing of the hardness, and decreased with increasing of the hardness reversely. And the tempering heat treatment temperature at $190^{\circ}C$ for 8 hrs exhibited the highest value of the hardness and also indicated the highest corrosion current density. However, the values of hardness and corrosion current density was again increasingly decreased with increasing of tempering hours than 8 hrs, Consequently, it is suggested that decision of the optimum. tempering hours is very important to improve the corrosion or wear resistance.

• 열처리공학회지
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• 제11권1호
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• pp.1-9
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• 1998

The objective of this study is to investigate the effect of solution-treatment temperature on the microstructure and damping capacity of a martensitic Fe-7%Ni-0.4%C alloy. The size of lath increased from $0.3{\mu}m$ to $0.55{\mu}m$ with increasing the solution-treatment temperature from 700 to $1100^{\circ}C$. In addition, the size of block, packet, and austenite grain had tendency to increase with increasing solution-treatment temperature. The damping capacity of the Fe-7%Ni-0.4%C martensitic alloy decreased with increasing the solution treatment temperature. The reason is not attributed to the increase in the size of lath, block, packet, and austenite grain, but to the increase in vacancy concentration which hinders dislocation motion.

• 열처리공학회지
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• 제28권1호
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• pp.17-23
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• 2015

Hydroxyapatite coatings were fabricated by a room temperature spray method on zirconia substrates and the influence of heat-treatment on their microstructure was also investigated. Phase composition of coated hydroxyapatite films was similar to the starting powder, but the grain size of hydroxyapatite particles was reduced to the size of nano-scale about 100 nm. Grain size, particle compactness, and adhesiveness to zirconia of hydroxyapatite coatings were increased with heat-treatment temperature, but some of cracks by heat-treatment above $1100^{\circ}C$ were initiated between hydroxyapatite coatings and zirconia substrate. Heat-treated hydroxyapatite layers show the dissolution in SBF solution for 5 days. Hydroxyapatite-coated specimen heat-treated at $1100^{\circ}C$ for 1 h has a good biocompatibility, which specimen induced the nanocrystalline hydroxyapatite precipitates on the coating surface by the immersion in SBF solution for 5 days.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2006년도 춘계 학술대회 개요집
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• pp.137-139
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• 2006

In order to establish the optimum hot forming temperature and solution heat treatment temperature for 25% chromium super duplex stainless steel weld, a commercial 25%Cr-10%Ni-4%Mo weld metal for super duplex stainless steel(UNS S32750) with different solution heat treatment conditions at $1100^{\circ}C,\;1050^{\circ}C,\;1025^{\circ}C\;and\;1000^{\circ}C$ for 1.5 hours has been investigated by means of optical metallography, and estimated mechanical properties. It is found that exposure to elevated temperatures at $1050^{\circ}C,\;1025^{\circ}C\;and\;1000^{\circ}C$ except $1100^{\circ}C$ brings partial decomposition of ferrite to austenite and sigma phase, which deteriorates their properties and heat treatment at $1100^{\circ}C$ shows acceptable mechanical properties.

• Journal of Periodontal and Implant Science
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• 제30권1호
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• pp.187-203
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• 2000

The precipitation of calcium phosphate on implant surface has been known to accelerate osseointegration and to enhance osseous adaptation. The present study was performed to examine whether the precipitation of calcium phosphate on Ti-6Al-4V alloy could be affected by the immersion in NaOH solution and heat treatment. Ti-6Al-4V alloy plates of $15{\times}3.5{\times}1mm$ in dimension were polished sequentially from #240 to #2,000 emery paper and one surface of each specimen was additionally polished with $0.1{\mu}m$ alumina paste. Polished specimens were soaked in various concentrations of NaOH solution(0.1, 1.0, 3.0, 5.0, 7.0, 10.0 M) at $60^{\circ}C$ for 24 hours for alkali treatment, and 5.0 M NaOH treated specimens were heated for 1 hour at each temperature of 400, 500, 600, 700, $800^{\circ}C$. After the alkali and heat treatments, specimens were soaked in the Hank's solution with pH 7.4 at $36.5^{\circ}C$ for 30days.The surface ingredient change of Ti-6Al-4V alloy was evaluated by thin-film X-ray diffractometer(TF-XRD) and the surface microstructure was observed by scanning electron microscope(SEM), and the elements of surface were analyzed by X-ray photoelectron spectroscopy(XPS). The results were obtained as follows ; 1. The precipitation of calcium phosphate on Ti-6Al-4V alloy was accelerated by the immersion in NaOH solution and heat treatment. 2. In Alkali treatment for the precipitation of calcium phosphate on Ti-6Al-4V alloy, the optimal concentration of NaOH solution was 5.0 M. 3. In heat treatment after alkali treatment in 5.0 M NaOH solution, the crystal formation on alloy surface was enhanced by increasing temperature. In heat treated alloys at $600^{\circ}C$, latticed structure and prominences of calcium phosphate layer were most dense. On heat treated alloy surface at the higher temperature(${\geq}700^{\circ}C$), main crystal form was titanium oxide rather than apatite. The above results suggested that the precipitation of calcium phosphate on the surface of Ti-6Al-4V alloy could be induced by alkali treatment in 5.0 M-NaOH solution and by heat treatment at $600^{\circ}C$.

• 한국주조공학회지
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• 제38권2호
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• pp.32-40
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• 2018

Changes in the microstructures and mechanical properties of an AC2B alloy through solution heat treatment were investigated using recycled AC2B cutting chips as raw material. The as-cast microstructure of the AC2B alloy comprised ${\alpha}$-Al, $Al_2Cu$, and coarse needle-shaped phases considered to be eutectic Si and an Al-Fe-Si based intermetallic compound. After solution heat treatments at $505^{\circ}C$ for 1 h and 6 h, the samples showed complete dissolution of $Al_2Cu$ and relatively fine distribution of intermetallic compounds. Hardness test results showed that the hardness rapidly increased after the solution heat treatment for 1 h by solid solution hardening, and the increase of hardness exhibited a plateau from 1 h to 6 h. The results of the hardness and tensile tests showed that there was no visible difference in the effect of 1 h and 6 h solid solution treatment.

• 열처리공학회지
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• 제33권5호
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• pp.226-231
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• 2020

The Cu-Co-Si alloy shows high strength by forming precipitates by aging precipitation heat treatment of supersaturated solid solution treated with solution treatment such as Cu-Ni-Si alloy, and the Co₂Si precipitated phase is dispersed in the copper matrix. The effect of aging treatment on the microstructure, mechanical and electrical properties of Cu-Co-Si alloys for electronic devices was investigated. As a results of SEM/EDS analysis, it was found that Co₂Si precipitates of 30~300 nm size were distributed in grains. By performing the double aging treatment, it was possible to improve the strength and electrical conductivity by dispersing the fine precipitate evenly.

• 열처리공학회지
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• 제8권1호
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• pp.75-83
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• 1995

The purpose of this study is to investigate the effect of heat treatments on the martensite transformation and tensile deformation behavior in Ti-Ni-B alloys with various boron concentration. Three types of heat treatment are given to the specimens; i) solution treatment ii) aging iii) thermo-mechanical treatment. In solution treated specimens. R-phase transition which is related to abnormal increase of electrical resistance prior to martensitic transformation has been formed at a boron content of 0.2at % and the $M_s$ temperature has been decreased with the increasing of boron content. However. It has not been affected by aging, while that of thermo-mechanically treated specimens has been remarkably increased in the vicinity of recrystallization temperature. The thermo-mechanically treated specimen has showed a good thermal fatigue characteristics, shape memory effect and superelasticity in comparison with the solution treated specimen.

• 열처리공학회지
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• 제24권3호
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• pp.144-148
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• 2011

Change in damping capacity with strain amplitude was studied in Mg-Al-Si alloy in as-cast, solution-treated and aged states, respectively. The as-cast microstructure of the alloy is characterized by eutectic ${\beta}$($Mg_{17}Al_{12}$) phase and Chinese script type $Mg_2Si$ particles. The solution treatment dissolved the ${\beta}$ phase into the matrix, while the aging treatment resulted in the distribution of continuous and discontinuous type ${\beta}$ precipitates. The solution-treated microstructure showed better damping capacity than as-cast and aged microstructures both in strain-dependent and strain-independent damping regions. The decrease in second-phase particles which weakens the strong pinning points on dislocations and distribution of solute atoms in the matrix, would be responsible for the enhanced damping capacity after solution treatment.