• Title/Summary/Keyword: Solute

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Influence of light Regime on Nitrate Reductase Activity and Organic and norganic Solute Composition of Four Sedges (Carex spp.)

  • Choo, Yeon-Sik;Roland-Albert;Song, Seung-Dal
    • Animal cells and systems
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    • v.2 no.4
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    • pp.455-462
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    • 1998
  • A survey was conducted on the inorganic and organic solute patterns of plants in connection with nitrate metabolism according to different light regimes (1.9, 16.0, 91.5 $Wm^{-2}$). Besides measuring in vivo NRA, we also quantitatively analyzed ater-soluble inorganic ions, organic acids, low molecular weight carbohydrates, amino aciss and total N (% DW). Among 4 Carex species, C. pilosa is known as shade-adapted species and the others as half (C. gracilis) to full (C. rostrata & C. distans) light-adapted species. Compared to species adapted to high light intensity, shade-adapted C. pilosa showed reduced productivity under the highest light intensity. In general, nitrate and amino acid levels decreased at higher light intensity, while sugar and organic acid concentrations increased. In C. pilosa osmolality tended to rise with increasing light intensity, while in the other species it tended to fall. Under low light intensity, the drop in soluble carbohydrate contents is osmotically compensated for by an enhanced nitrate concentration. It is concluded that competition between nitrate and $CO_2$reduction for reductants and ATP from photosynthesis may have important ecological consequences for the adaptation of plants to low or high light conditions. Additionally, the patterns of ionic changes due to increased light intensities were essentially the same in all selected species, indicating similar characteristics of heir mineral ion and organic acid metabolism as well as in field-grown Carex species.

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Fabrication of Nono-Size Crystalline $TiO_2$ Powders for Photocatalyst Using (초임계 유체를 이용한 광촉매용 나노크기의 결정질 $TiO_2$ 분말 제조)

  • Lim, Dae-Young;Kim, Jong-Ock;Kim, Taik-Nam;Lee, Chae-Hyun;Park, Won-Kyu
    • The Journal of Engineering Research
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    • v.3 no.1
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    • pp.207-213
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    • 1998
  • In order to fabricate ideal powders, new processing is necessary in which the solute atoms in solution rapidly move to mix each other to the degree of molecular level, the viscosity of solution should be low not to effect the moving of solute atoms, and the powders could be directly obtained as crystalline. Supercritical fluid is defined as condensed gas state up to its critical pressure and temperature. In this paper, supercritical fluid methods were studied as a new ceramic processing of powder preparation. The crystalline anatase powders of $TiO_2$ which are useful for photocatalyst materials were fabricated by hydrolysis of titanium(IV) ethoxide using water which was ethanol as a supercritical fluid.

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Optimization of Bioreactor Operation by Mass Transfer Coefficient (물질전달계수를 이용한 생물 반응기 운전 최적화)

  • Kim, Hyung-Soon
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.3
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    • pp.243-251
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    • 2001
  • The effects of various operating parameters(agitation speed, impeller type, antiform agents, impeller spacing etc.) on air-liquid mass transfer was characterized by volumetric mass transfer coefficient($k_La$). Also, the dual-impeller agitated systems are compared with single-impeller agitated systems with a special focus on its applications for bioreactors, $k_La$ was take over a range of 200~450 rpm of agitation speed, and 0.5~2.5 vvm of air flow rates, for four single impeller and impeller combinations consisting of four impeller types, namely rushton, pitched blade, scaba, intermig were tested. The rushton impeller showed the best $k_La$ as compared with other single impellers. The dual impeller system are found to be superior as compared to single impeller in all aspects, The best combination of the dual impeller was a intermig of axial flow type as an upper impeller and a rushton of radial flow type as a lower part. Also, the control of the DO level with the variation of agitation speed was more efficient than that with an increase in air flow rate. The addition of antiform dropped the $k_La$ very large up to 1g/L regardless the type. PPG was less effect on $k_La$ than other antiforms. The impeller spacing and presence of solute are found very effective on $k_La$. When the $NaNO_3$is presented as solute, the $k_La$ increased approximately 50% then control.

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Water and Sodium Balance of Body Fluid (체액의 수분 및 나트륨 균형)

  • Kim, Ji-Hong
    • Childhood Kidney Diseases
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    • v.14 no.2
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    • pp.111-119
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    • 2010
  • The maintenance of the osmolality of body fluids within a very narrow physiologic range is possible by water balance mechanisms that control the intake and excretion of water. Main factors of this process are the thirst and antidiuretic hormon arginine vasopressin (AVP), secretion regulated by osmoreceptors in the hypothalamus. Body water is the primary determinant of the osmolality of the extracellular fluid (ECF), disorders of body water homeostasis can be divided into hypo-osmolar disorders, in which there is an excess of body water relative to body solute, and hyperosmolar disorders, in which there is a deficiency of body water relative to body solute. The sodium is the predominant cation in ECF and the volume of ECF is directly proportional to the content of sodium in the body. Disorders of sodium balance, therefore, may be viewed as disorders of ECF volume. This reviews addresses the regulatory mechanisms underlying water and sodium metabolism, the two major determinants of body fluid homeostasis for a good understanding of the pathophysiology and proper management of disorders with disruption of water and sodium balance.

Sensitivity Test of the Parameterization Methods of Cloud Droplet Activation Process in Model Simulation of Cloud Formation (구름방울 활성화 과정 모수화 방법에 따른 구름 형성의 민감도 실험)

  • Kim, Ah-Hyun;Yum, Seong Soo;Chang, Dong Yeong
    • Atmosphere
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    • v.28 no.2
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    • pp.211-222
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    • 2018
  • Cloud droplet activation process is well described by $K{\ddot{o}}hler$ theory and several parameterizations based on $K{\ddot{o}}hler$ theory are used in a wide range of models to represent this process. Here, we test the two different method of calculating the solute effect in the $K{\ddot{o}}hler$ equation, i.e., osmotic coefficient method (OSM) and ${\kappa}-K{\ddot{o}}hler$ method (KK). To do that, each method is implemented in the cloud droplet activation parameterization module of WRF-CHEM (Weather Research and Forecasting model coupled with Chemistry) model. It is assumed that aerosols are composed of five major components (i.e., sulfate, organic matter, black carbon, mineral dust, and sea salt). Both methods calculate similar representative hygroscopicity parameter values of 0.2~0.3 over the land, and 0.6~0.7 over the ocean, which are close to estimated values in previous studies. Simulated precipitation, and meteorological variables (i.e., specific heat and temperature) show good agreement with reanalysis. Spatial patterns of precipitation and liquid water path from model results and satellite data show similarity in general, but on regional scale spatial patterns and intensity show some discrepancy. However, meteorological variables, precipitation, and liquid water path do not show significant differences between OSM and KK simulations. So we suggest that the relatively simple KK method can be a good alternative to the OSM method that requires various information of density, molecular weight and dissociation number of each individual species in calculating the solute effect.

Effects on n-Alcohols on the Amino-Proton Chemical Shifts and on the Hindered Rotation about the N-C(O) Bond of Acetamide (아세트아미드의 아미노 양성자의 화학적 이동과 N-C(O) 결합주위의 부자유회전에 미치는 n-알코올 용매 효과)

  • Gwon, Sun Gi;Choe, Jong Ho;Choe, Yeong Sang;Yun, Chang Ju;Gwon, Dae Geun
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.509-516
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    • 1990
  • 1H-nmr chemical shifts and lineshapes of amino-protons of acetamide (AA) in n-alcohols were determined. The chemical shifts are discussed by the Reichardt's solvent polarity parameter, E$_{T}$(30). The following relationship between $\delta$obs and E$_{T}$(30) was obtained. ${\delta}_{obs}$ = ${\delta}_{o}$ + aE$_{T}$ (30) + b[E$_{T}$(30)]$^2$ where ${\delta}_{o}$ is the chemical shift of the solute in gaseous state or at $E_{T}$(30) = 0, a is a characteristic constant for the protons of AA in n-alcohol solutions and b is a constant for the solute (AA)-solvent (n-alcohols) interaction. The barrier of the hindered rotation about the N-C(O) bond in AA was obtained by analysis of the lineshapes of the amino-protons in AA. The behavior of the internal rotation as well as chemical shifts of the amino-protons in AA has been found to be closely related to the $E_{T}$(30) of n-alcohols.

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Concentration of Sodium Chloride, Sodium Acetate and Sodium Citrate Solutions by using Polyamide Reverse Osmosis Membrane (폴리아미드 역삼투막을 이용한 염화나트륨, 아세트산나트륨, 구연산나트륨 용액의 농축)

  • Lee, Heungil;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.679-686
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    • 2018
  • Reverse osmosis (RO) concentration of sodium chloride, sodium acetate, and sodium citrate solutions has been performed by polyamide RO membrane. Concentration polarization phenomena was also studied by changing pressure, solute kinds, and initial solution concentration. Pressure effect on permeation flux was that the increase of flux was accompanied by the increase of pressure. Flux increase was observed by the decrease of initial solution concentration. Surface concentration on the RO membrane increases and so flux declines due to the concentration polarization. In the later phase of concentration, concentration polarization effect was decreased by the back diffusion of solute from the polariztion layer. In case of sodium citrate, its large ion size and charge density resulted in the discrepancy between theory and experimental data of concentration polarization. It may be due to electric repulsion on the membrane surface.

The Effect of Sodium Lactate and Sodium Chloride on Water Activity of Water-Sorbitol System (Water-Sorbitol System의 수분활성도에 미치는 Sodium Lactate 및 Sodium Chloride의 영향)

  • Park, Jang-Woo;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.330-335
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    • 1991
  • The values of water activity in the different concentrations of NaCl and sodium lactate were measured by hygrometer in the water-sorbitol systems. Interaction of NaCl and sodium lactate was evaluated by Raoult's law. The discrepancy between experimental and theoretical value by the Raoult's law was defined as interaction between water-sorbitol and added solutes in the systems. The changes of interacted water and solutes were observed in whole range of water activity. The value of interacted water (water: sorbitol=1 : 1.1241) obtained by added sodium lactate was found to be higher than sodium chloride. The amount of interacted solute reached maximum about Aw 0.87, while the interactions between added solute and sorbitol showed an increasing tendency below Aw 0.87.

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Separation and Purification of 2,6-Dimethylnaphthalene Present in the Fraction of Light Cycle Oil by Crystallization Operation (결정화조작에 의한 접촉분해경유 유분에 함유된 2,6-디메틸나프탈렌의 분리·정제)

  • Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.799-804
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    • 2018
  • The separation and purification of 2,6-dimethylnaphthalene (2,6-DMN) present in the light cycle oil (LCO) fraction was investigated by a crystallization operation. Solute crystallization (SC) was performed using LCO fraction and iso-propyl alcohol as a raw material and a SC solvent, respectively. Increasing the operation temperature and volume ratio of the solvent to the raw material (S/F) resulted in improving the purity of 2,6-DMN, whereas the yield decreased. As a result of the crystallization operation in three steps containing the SC using LCO fraction (13.9% 2,6-DMN) and isopropyl alcohol, the re-crystallization 1 (RC 1) using the crystals recovered by SC and methyl acetate, and RC 2 using the crystals recovered by RC 1 and methyl acetate, the crystal with 99.9% 2,6-DMN was recovered with 19.5% yield. Furthermore, the separation and purification process of 2,6-DMN present in the LCO fraction was reevaluated by using the experimental results obtained through each operations of SC, RC 1, and RC 2.

Characteristics of Precipitation Hardened Extra Low Carbon Steels (석출강화형 극저탄소강의 특성에 대한 고찰)

  • Yoon, Jeong-Bong;Kim, Sung-il;Kim, In-Bae
    • Korean Journal of Metals and Materials
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    • v.46 no.10
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    • pp.609-616
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    • 2008
  • Conventional bake-hardenable(BH) steels should be annealed at higher temperatures because of the addition of Ti or/and Nb which forms carbides and raises recrystallization start temperature. In this study, the development of new BH steels without Ti or Nb addition has been reviewed. The new BH steels have nearly same mechanical properties as the conventional BH steels even though it is annealed at lower temperature. The steels also show smaller deviation of the mechanical properties than that of the conventional BH steels because of the conarol of solute carbon content during steel making processes. The deviation of mechanical properties in conventional BH steels is directly dependent on the deviation of solute carbon which is greatly influenced by the amount of the carbide formers in conventional BH steels. Less alloy addition in the newly developed BH steels gives economical benefits. By taking the advantage of sulfur and/or nitrogen which scarenge in Interstitial-Free or conventional BH steels, fine manganese sulfides or nano size copper sulfides were designed to precipitate, and result in refined ferrite grains. Aluminum nitrides used as a precipitation hardening element in the developed steels were also and resull in fine and well dispersed. As a result, the developed steels with less production cost and reduced deviation of mechanical properties are under commercial production. Note that the developed BH steels are registered as a brand name of MAFE(R) and/or MAF-E(R).