• Title/Summary/Keyword: Solubilization rate

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Effect of Microbubble Ozonation Process on Performance of Biological Reactor System for Excess Sludge Solubilisation (마이크로버블오존을 이용한 잉여슬러지 가용화 처리가 생물반응조의 성능에 미치는 영향)

  • Lee, Shun-Hwa;Jung, Kye-Ju;Kwon, Jin-Ha;Lee, Se-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.2
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    • pp.113-119
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    • 2011
  • The study purpose was to examine an effect of zero emission of excess sludge on biological reactor and treated water quality within the biological reactor in the process of biological treatment combined with excess sludge reduction system with ozone. Under an ozone injection rate 0.03 g $O_3/g$ SS, Sludge Disintegration Number (SDN) 3 and less than pH 4 as pre-treatment process, it was possible to maintain a stable biological treatment process without sludge disintegration. In the test of $OUR_{max}$, of sludge, its value was hardly under the condition of ozone injection rate 0.03 g $O_3/g$ SS. There were almost no changes of MLVSS/MLSS within biological reactor followed by a solubilization of excess sludge. Accumulation of microorganism within biological reactor was also not observed. After solubilization of excess sludge, an increase for organic matter and SS concentrations of an effluent was not observed and T-N concentration was reduced by increasing nitrification and denitrification rate within biological reactor. Most of T-P was not removed by zero emission of excess sludge and was leaked by being included in effluents.

A Study on the Solubilization and Physical Properties of Sanjoinine-A (산조인 알카로이드의 가용화 및 물성에 관한 연구)

  • Sheu, Kwang-Gyou;Lee, Chi-Ho
    • Journal of Pharmaceutical Investigation
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    • v.26 no.4
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    • pp.257-261
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    • 1996
  • The seeds of Zizyphus Jujuba have been used as an antianxiety agent for the treatment of insomnia from the earliest times. Sanjoinine-A, isolated from the seeds of Zizyphus Jujuba, have been found to have a minor tranquilizer activity. However this drug is poorly soluble in water. In order to increase the dissolution rate of sanjoinine-A, solid dispersions with PVP-MC and inclusion complex with ${\beta}-cyclodextrin$ were prepared and evaluated. All of these systems increased the dissolution rate of sanjoinine A comparing with sanjoinine-A free base. From pH-rate profile of sanjoinine-A at $60^{\circ}C$, it was found that sanjoinine A was relatively stable in acidic solution, but unstable in basic solution.

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An Experimental Study on the Pond Sediment and Water Quality Purification using Oxygen Solubilization Device(OSD) System (산소용해수를 이용한 호소 저질 및 수질개선에 관한 실험적 연구)

  • Kim, Young-Taek;Bae, Yoon-Sun;Roh, Eun-Kyung;Park, Chul-Hwi;Lee, Yeon-Ku
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.94-103
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    • 2006
  • The pollution in closing water can be caused by not only artificial factor like sewage but also natural factor like elution from sediment. In this study we analyzed Sediment Oxygen Demand (SOD) for verification of sediment purification effect and sediment elution experiment as well as general items like COD, TN, TP, SS to complement and assess the effect of sediment and water quality. The experiment result showed that the release rate of OSD system were 4 times and 3 times as large as control for P and Fe respectively. SOD for operated OSD system and control were $12.18gO_2{\cdot}m^{-2}{\cdot}d^{-1}$ and $47.95gO_2{\cdot}m^{-2}{\cdot}d^{-1}$. From water qualities analyzed by COD, TN, TP, SS, chlorophyll-a, the removal efficiency increase of TN, TP, chlorophyll-a and COD were about 10~20%, 40~50% and 10% respectively. In conclusion, OSD can contribute to improvement of both the waterbody and the sediment environment effectively.

Ruminal Solubility of Trace Elements from Selected Philippine Forages

  • Serra, S.D.;Serra, A.B.;Ichinohe, T.;Fujihara, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.4
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    • pp.378-384
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    • 1997
  • The ruminal solubility of copper (Cu), manganese (Mn), molybdenum (Mo), and zinc (Zn) in eight Philippine forages was studied. These forages were: 1) grasses: paragrass (Brachiaria mutica (Forsk.) Stapf), stargrass (Cynodon plectostachyum Pilger), and napiergrass (Pennisetum purpureum Schumach.); 2) creeping legumes: calopogonium or calopo (Calopogonium muconoides Desv.) and centrocema (Centrocema pubescens Benth.); 3) tree lequmes: gliricidia or kakawate (Gliricidia sepium (Jacq.) Walp.), leucaena or ipil-ipil (Leucaena leucocephala (Lam.) de Wit.), and sesbania or katuray (Sesbania grandiflora (L.) Poir). Nylon bags with samples were incubated for 0, 3, 6, 12, 24, 48 and 72h in three rumen cannulated sheep fed with timothy hay (Phleum pratense L.) at 2% body weight/d. The 0-h bags were washed with deionized water. There were species differences (p < 0.05) on the different solubilities of trace elements. At O-h incubation, the trend of solubility was Mo (54%) > Zn (43%) > Cu (38.7%) > Mn (29.5%). At 3-h incubation, all the elements except Mn had an average solubility above 50%. Combining particulate passage rate (1.9%/h) and various trace elements disappearance rates, the effective ruminal solubilization (ERS) of trace elements were computed. The ERS across species ranged from 44.6 to 89.9% for Cu, 29.9 to 84% for Mn, 66 to 95.1% for Mo, and 30.1 to 82.3% for Zn resulting to a trend of Mo > Zn > Cu > Mn.

Characteristics of Biological Hydrogen Production from Sewage Sludge treated by Optimal Solubilization Technology (최적 가용화 기술로 처리된 하수슬러지의 생물학적 수소 생산 특성)

  • Choi, Kwang-Keun;Kim, Sun-Jip;Lee, Tae-Joon;Park, Dae-Won;Lee, Won-Kwon
    • KSBB Journal
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    • v.21 no.5
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    • pp.353-359
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    • 2006
  • The purpose of this study is to search the optimal solubilization technology which could be applied to sewage sludge, and is to find the characteristics of biological hydrogen production when the sludge treated by optimal method was used as a sole substrate. As a result of the test, treatment technology mixed with alkali and ultrasonic treatment was very powerful tool for treating sewage sludge with high solubilization, and its ratio and elution rate of organic material was 0.9 and 0.076 $min^{-1}$, respectively. When the sludge treated by above optimal technology was used, 4.4 ml $H_2/g$ VSS of hydrogen was produced. Finally, When the sludge treated by above optimal technology was used, 13.4 ml $H_2/g$ VSS of hydrogen was produced under optimum pH.

Dynamic Behavior Study in Systems Containing Nonpolar Hydrocarbon Oil and C12E5 Nonionic Surfactant (C12E5 비이온 계면활성제 수용액과 비극성 탄화수소 오일 사이의 동적 거동 관찰)

  • Bae, Min Jung;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.46-53
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    • 2009
  • Phase equilibrium and dynamic behavior studies were performed in systems containing $C_{12}E_5$ nonionic surfactant solution and nonpolar hydrocarbon oil. The phase behavior result showed an oil-in-water(O/W) microemulsion(${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water-in-oil(W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a 3 phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop with time were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous surfactant solution were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time were found to increase with an increase in the chain length of a hydrocarbon oil.

Dynamic Behavior Study Using Videomicroscopy in Systems Containing Nonpolar Hydrocarbon Oil and C10E5 Nonionic Surfactant Solution (Videomicroscopy를 이용한 C10E5 비이온 계면활성제 수용액과 비극성 탄화수소 오일 사이의 동적 거동에 관한 연구)

  • Bae, Min-Jung;Lim, Jong-Choo
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.473-478
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    • 2009
  • Phase equilibrium and dynamic behavior studies were performed on systems containing $C_{10}E_5$ nonionic surfactant solutions and nonpolar hydrocarbon oils. The phase behavior showed an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water in oil (W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a three-phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time increased with an increase in the chain length of a hydrocarbon oil.

Solubilization of Dairy Sludge using Ultrasonic Pretreatment (초음파를 이용한 유가공 슬러지의 가용화)

  • Moon, Sang Jae;Jeon, Byeong Cheol;Choi, Jin Taek;Nam, Se Yong
    • Journal of Dairy Science and Biotechnology
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    • v.35 no.4
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    • pp.244-248
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    • 2017
  • The effects of ultrasonic (1.2~1.7 kJ/g TS) pretreatment on the solubilization of dairy and livestock sludge were separately evaluated to investigate the possibility of recycling dairy sludge as a potential source of organic carbon. Compared to other industrial wastewater and sewage sludge, dairy sludge has higher organic matter content and no toxic materials. The solubilization rates of dairy and livestock sludge, at a specific energy input of 1.7 kJ/g TS, were 14.5% and 10.6%, respectively. After the 90-minute ultrasonic treatment, the soluble COD (chemical oxygen demand) increased about 7.1 times that of the initial SCOD, at an increase rate of $0.022m^{-1}$. In comparison, the increase in soluble nitrogen, which was ~3.4 times that of the initial soluble nitrogen concentration, was much smaller than the increase in SCOD; thus, the C/N ratio increased from 4.0 to 8.7.

Effect of Wet Milling on Scum Generation and Solubilization in Batch Ozone Reaction Using Digested Sludge (소화슬러지를 이용한 회분식 오존반응 시 습식분쇄가 스컴 생성과 가용화에 미치는 영향)

  • Hong, Seong-Min;Lee, Dong-Hoon;Kim, Choong-Gon;Shin, Hyun-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.2
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    • pp.13-18
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    • 2019
  • Sewage sludge treatment is increasing every year due to improvement of living and urbanization. However, interest in anaerobic digestion which is one of the recycling technology. There is anaerobic digestion of increasing due to limitations of ocean dumping and final disposal. But, the limit of anaerobic digestion efficiency due to the advanced treatment of sewage has been limited, and studies for solubilization technology have been actively conducted. Therefore, in this study, we aimed to investigate the variation of generation of scum and the solubilization efficiency in the application of pre-treatment of ozone reaction and the change of properties of digested sludge with wet milling. There are results of VS/TS increased by 4.4% and $SCOD_{cr}/TCOD_{cr}$ increased by 9.4% by wet milling alone. In addition, the increase of the specific surface area due to which the reduction of the particle size of the solid content of the sludge in the ozone reaction caused by wet milling decreased the generation rate of scum at 14.3% and increased VS/TS at 2.1%, compared with the ozone reaction alone. From these results, it is expected that the application of wet milling can be increased the contact efficiency with solids in the sludge during ozone reaction with suppress scum and increase the efficiency of the subsequent process in anaerobic digestion.

Analysis of Extruded Pectin Extraction from Apple Pomace by Response Surface Methodology

  • Shin, Hae-Hun;Kim, Chong-Tai;Cho, Yong-Jin;Hwang, Jae-Kwan
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.28-31
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    • 2005
  • To extract apple pectins, apple pomace (AP) was extruded under 14 different conditions of screw speed (250-350 rpm), feed rate of 30-40 kg/hr, and 20-30% moisture content using twin-screw extrusion. Response surface methodology (RSM), based on three variables by three-level factorial design, was employed to investigate effects of screw speed, feed rate, and moisture on dependent variables of extrudates, soluble dietary fiber (SDF), yield of anhydrogalacturonic acid ($Y_{AGA}$) representing pectin, and intrinsic viscosity ([${\eta}$]). Second order models were used to generate three-dimensional response surface for dependent variables, and their coefficients of determination ($R^2$) ranged from 0.96 to 0.99. Moisture content showed highest effect on solubilization of AP.