• Title/Summary/Keyword: Solidification Interface

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A Study of Heat Storage System with Phase Change Material - Inward Melting and Solidification in a Horizontal Cylinder - (상변화물질을 이용한 잠열축열조에 관한 기초 연구 - 수평원관내에서의 내향용융 및 응고열전달 실험 -)

  • Kim, I.G.;Cho, N.C.;Kim, J.G.;Lee, C.M.;Yim, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.1 no.4
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    • pp.319-329
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    • 1989
  • Heat transfer phenomena during inward melting and solidification process of the phase change material were studied expertimentally. The phase change medium was 99% pure n-docosane paraffin ($C_{22}H_{46}$). The solid-liquid interface motion during phase change was recorded photographically. Measurements were made on the temperature, the solid-liquid interface, the melted or frozen mass and the various energy components stored or extracted from the cylinder wall. For melting, the experimental results reaffirmed the dominant role played by the conduction at an early stage, by the natural convection at longer time. For solidification, natural convection effects in the superheated liquid were modest and were confined to short freezing time. Although the latent energy is the largest contributor to the total stored or extracted energy, the aggregate sensible energies can make a significant contribution, especially at large cylinder wall superheating or subcooling, large initial phase change material subcooling or superheating.

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Characteristics and Stability of Compositional Convection in Binary Solidification with a Constant Solidification Velocity (일정한 응고속도를 갖는 2성분 응고에서 조성 대류의 특성 및 안정성)

  • Hwang, In Gook
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.199-204
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    • 2014
  • In binary solidification compositional convection in a porous mushy layer influences the quality of the final products. We consider the mushy layer solidifying from below with a constant solidification velocity. The disturbance equations for the mushy layer are derived using linear stability theory. The basic-state temperature fields and the distribution of the porosity in the mushy layer are investigated numerically. When the superheat is large, the thickness of the mushy layer is relatively small compared to the thickness of the thermal boundary layer. With decreasing the superheat the critical Rayleigh number based on the thickness of the mushy layer increases and the mushy layer becomes stable to the compositional convection. The critical Rayleigh number obtained from the continuity conditions of temperature and heat flux at the mush-liquid interface is smaller than that from the isothermal condition at the upper boundary of the mushy layer.

Solidification Process of an Al-Cu Alloy in a Vertical Annular Mold and Effects of Cooling Rate on Macrosegregation (수직환상주형내 Al-Cu합금의 응고과정 및 냉각속도의 조대편석에 대한 영향)

  • 유호선
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.7
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    • pp.1818-1832
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    • 1994
  • Transport process during solidification of an AI-CU alloy in a vertical annular mold of which inner wall is cooled is numerically simulated. A model which can take account of local density dependence on the solute concentration is established and incorperated in the analysis. Results show that thermally and solutally induced convections are developed in sequence, so that there is little interaction between them. Thermal convection effectively removes the initial superheat from the melt and vanishes as solidification proceeds from the cooling wall. On the other hand, solutal convection which is developed later over the meshy and the pure liquid regions leads to large-scale redistribution of the consituents. The degree of the initial superheating hardly affects overall solidification behavior except the early stage of the process, when the cooling rate is kept constant. Macrosegregation is reduced remarkably with increasing cooling rate, because not only the liquidus interface advances so quickly that time available for the solute transport is not enough, but also the interdendritic flow is strongly damped by rapid crystal growth within the mushy region.

Effect of Scrap Addition Ratio on Tensile and Solidification Cracking Properties of AC4A Aluminum Casting Alloy (AC4A 알루미늄 합금의 인장 및 응고균열 특성에 미치는 스크랩 첨가 비율의 영향)

  • Oh, Seung-Hwan;Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.40 no.3
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    • pp.85-96
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    • 2020
  • The effect of an aluminum scrap addition ratio on the tensile and solidification cracking properties of the AC4A aluminum alloy in the as-cast state and heat-treated state were investigated in this study. Generally, the expected problem of using scrap in aluminum casting is an increase of hydrogen and Fe element inside the aluminum melt. Another issue is an oxide film which has a weak interface with the molten aluminum and acts as potent nucleation sites for internal porosity and crack initiation. Solidification cracking is one of the critical defects that must be resolved to produce high quality castings. A conventional evaluation method for solidification cracking is a relative and qualitative analysis method which does not provide quantitative data on the thermal stress in the solidification process. Therefore, a newly designed solidification cracking test apparatus was used in this study, and the device can provide quantitative data. As a result, after conducting experiments with different scrap addition ratios (0%, 20%, 35%, 50%), the tensile strengths and elongations in the as-cast state were 214, 187.7, 182.1 and 170.4MPa and 4.6%, 3.4%, 3.1% and 2.3%, respectively. In the case of the T6 heat-treated state, the tensile strengths and elongations were 314.9, 294.6, 293.1 and 271.1MPa and 5.4%, 4.6%, 3.8% and 3.1%, respectively. The strength of the solidification cracking was 3.1, 2.4, 2.2and 1.6MPa as the scrap addition ratio increases.

Heat Transfer and Solidification of Liquid Silicon in von-Kármán Swirling Flow (Von-Kármán 회전 유동 하에서의 액체 실리콘의 응고와 열전달)

  • Yoo, Joo-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.185-197
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    • 1999
  • Heat transfer and solidification of liquid silicon in von-$K{\acute{a}}rm{\acute{a}}n$ swirling flow is investigated. The moving boundary is fixed for all times by a coordinate transformation, and finite difference method Is used to obtain the instantaneous location of the solid-liquid Interface and the heat transfer from the surfaces of solid and liquid. For small Stefan number or low wall temperature, the transient heat transfer from the surface of solid(QS(t)) is much larger than that from the liquid side of solid-liquid interface(QL(t)) and QL(t) reaches its quasi-steady-state value much faster than QS(t).

A study on the phase change in the cylindrical mold by the enthalpy method (엔탈피법을 이용한 원통형 몰드내에서의 상변화과정에 관한 연구)

  • 여문수;최상경;김문철
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.6
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    • pp.891-897
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    • 1999
  • The heat transfer characteristics at the interface between the mold and the casting is one of the major factors for the solidification speed which determines the casting structures. The thermal resistance exists due to air gap formation at the mold/casting interface during the freezing process. In this study one dimensional Stefan problem with the air-gap resistance in the cylindrical mold is considered and the heat transfer characteristics is numerically examined by using the enthalpy method which is convenient in solving the Stefan problem with mushy zone. The present results agreed very well with those of previous papers. The effects of major parameters such as thermal conductivity, heat transfer coefficient of mold, on the thermal characteristics are investigated.

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In Situ Observation of Solidification Behavior in Undercooled $Pd_{40}Cu_{30}Ni_{10}P_{20}$ Alloy Melts during Linear Cooling (연속냉각 중 과냉 된 $Pd_{40}Cu_{30}Ni_{10}P_{20}$ 합금 용탕의 실시간 응고거동 관찰)

  • Kim, Ji-Hun
    • Journal of Korea Foundry Society
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    • v.23 no.5
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    • pp.276-285
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    • 2003
  • In the undercooled melt of $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy, the solidification behavior including nucleation and growth of crystals at the micrometer level has been observed in-situ by use of a confocal scanning laser microscope combined with an infrared image furnace. The $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy specimens were cooled from the liquid state to glass transition temperature. 575 K, at various cooling late under a helium gas flow. According to the cooling rate, the morphologies of the solidification front are changed among various types, irregular jog like front, columnar dendritic front, cellular grain, star like shape jog and fine grain, etc. The velocities of the solid-liquid interface are measured to be $10^{-5}{\sim}10^{-8}$ m/s which are at least two orders higher than the theoretical crystal growth rates. Combining the morphologies observed in terms of cooling rates and their solidification behaviors, we conclude that phase separation takes place in the undercooled molten $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy. The continuous cooling transformation (CCT) diagram was constructed from solidification onset time at various linear cooling conditions with different rate. The CCT diagram suggests that the critical cooling rate for glassy solidification is about 1.5 K/s, which is in agreement with the previous calorimetric findings.

Finite Element Analysis of Solidification Processes of Axisymmetric Castings Considering Phase Change and Contact (상변화와 접촉을 고려한 축대칭 주조 응고공정의 유한요소 해석)

  • Ghoo, B.Y.;Keum, Y.T.;Lee, J.K.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.1
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    • pp.126-141
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    • 1997
  • The purpose of this research is to develope a FEM program for analyzing solidification processes of axisymmetric casting, considering phase changes and the contact between the metal and mold. Tempera- ture recovery method is employed fro considering the phase changes releasing the latent heat and the coin- cident node method is used for calculating the amount of heat transfer between the metal and mold. Tan- gent modulus algorithm is adopted for calculating flow stress and a gap element is employed for modeling the interface between the mold and metal in finding deformed shapes. In order to verify the developed program, axisymmetric aluminum and steel casting processes are simulated. Temperature distribution, phase front position, and shrinkage and porosity creation are compared with measurements, FIDAP results, and good agreements are examined.

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Modeling of Microstructural Evolution in Squeeze Casting of an Al-4.5wt%Cu Alloy (용탕단조시 Al-4.5%Cu합금의 조직예측)

  • Cho, In-Sung;Hong, Chun-Pyo;Lee, Ho-In
    • Journal of Korea Foundry Society
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    • v.16 no.6
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    • pp.550-555
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    • 1996
  • A stochastic model, based on the coupling of the finite volume(FV) method for macroscopic heat flow calculation and a two-dimensional cellular automaton(CA) model for treating microstructural evolution was applied-for the prediction of microstructural evolution in squeeze casting. The interfacial heat transfer coefficient at the casting/die interface was evaluated as a function of time using an inverse problem method in order to provide a quantitative simulation of solidification sequences under high pressure. The effects of casting process variables on the formation of solidification grain structures and on the columnar to equiaxed transition of an Al-4.5wt%Cu alloy in squeeze casting were investigated. The calculated solidification grain structures were in good agreement with those obtained experimentally.

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