• Title/Summary/Keyword: Solid-phase

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VARIATIONS OF CONTAMINANT RETARDATION FACTOR IN THE PRESENCE OF TWO MOBILE COLLOIDS

  • Kim, Song-Bae;Kim, Dong-Ju
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.115-119
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    • 2001
  • Contaminant retardation factor is derived from the colloidal and contaminant transport equations for a four-phase porous medium: an aqueous phase, two mobile colloidal phases, and a solid matrix. It is assumed that the contaminant sorption to solid matrix and colloidal particles and the colloidal deposition on solid matrix follow the linear isotherms. The behavior of the contaminant retardation factor in response to the change of model parameters is examined employing the experimental data of Magee et al. (1991) and Jenkins and Lion (1993). In the four-phase system, the contaminant retardation factor is determined by both the contaminant association with solid matrix and colloidal particles and the colloidal deposition on solid matrix. The contaminant mobility is enhanced when the affinity of contaminants to mobile colloids increases. In addition, as the affinity of colloids to solid matrix decreases, the contaminant mobility increases.

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Transient Simulation of Solid/Liquid Two-Phase Flow in a Stirred Tank (교반기 내부의 고체/액체 다상 유동의 비정상상태 해석)

  • Kim, Chi-Gyeom;Yong, Suk-Jin;Won, Chan-Shik;Hur, Nahm-Keon
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.236-239
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    • 2008
  • In the present study, a transient glass particle distribution in a stirred solid/liquid mixer was investigated using computational fluid dynamics(CFD). The flow patterns and solid concentaration distriburion in a solid/liquid mixer formed by pitched paddle and baffles were predicted. The numerical results were compared to experimental data from the available literature. Eulerian multi-phase model was used to investigate the influence of the density of solid particle on the same impeller speed. A good agreement was obtained between the experimental data and simulation results.

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Numerical Analysis on Semi-Solid Forging and Casting Process of Aluminum Alloys (알루미늄합금의 반용융 단조 및 주조공정에 관한 수치해석)

  • 강충길;임미동
    • Transactions of Materials Processing
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    • v.6 no.3
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    • pp.239-249
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    • 1997
  • The behaviour of alloys in the semi-solid state strongly depends on the imposed stress state and on the morphology of the phase which can vary from dendritic to globular. To optimal net shape forging of semi-solid materials, it is important to investigate for filling phenomena in forging process of arbitrarily shaped dies. To produce a automotive part which has good mechanical property, the filling pattern according to die velocity and solid fraction distribution has to be estimated for arbitrarily shaped dies. Therefore, the estimation of filling characteristic in the forging simulation with arbitrarily shaped dies of semi-solid materials are calculated by finite element method with proposed algorithm. The proposed theoretical model and a various boundary conditions for arbitrarily shaped dies is investigated with the coupling calculation between the liquid phase flow and the solid phase deformation. The simulation process with arbitrarily shaped dies is performed to the isothermal conditions of two dimensional problems. To analysis of forging process by using semi-solid materials, a new stress-strain relationship is described, and forging analysis is performed by viscoelastic model for the solid phase and the Darcy's law for the liquid flow. The calculated results for forging force and filling limitations will be compared to experimental data. The filling simulation of simple products performed with the uniform billet temperature(584$^{\circ}C$) from the induction heating by the commercial package MAGMAsoft. The initial step of computation is the touching of semi-solid material with the end of die gate and the initial concept of proposed system just fit with the capability of MAGMAsoft.

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Scale-up of Covalently Immobilized Urokinase Column and Repeated Use of It by Solid-Phase Refolding (공유결합으로 고정화된 urokinase 칼럼의 스케일업과 solid-phase refolding에 의한 반복 사용)

  • 서창우;최강선;이은규
    • KSBB Journal
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    • v.16 no.5
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    • pp.500-504
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    • 2001
  • We scaled up a covalent immobilization system of urokinase to the activated Sepharose and used it repeatedly to cleava a fusion protein consisting of human growth hormone and GST fragment. After scale up from 6 ml to 250 ml. the column system still demonstrated basically the same performance in terms of urokinase immobilization and fusion protein cleavage. When the column was washed with 6 M guanidine HCI after the cleavage reaction, the immobilized urokinase showed no activity probably becasue it was fully unfoled. However, as the denaturant was gradually removed from the column the immobilized urokinase fully regained its bioactivity, which indicated it was properly refolded into is natie conformation as covalently attached to the solid matrix. After 20 cycles of this solid-phase unfolding/refolding. the immobilized urokinase maintained approx. 80% of the initial bioactivity. This method provides and efficient protocol to apply the solid-phase refolding technique to improve the longevity of immobilized enzyme columns.

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Characterization of Drawn Polyethylene by Solid State $^{13}C$ Magic Angle Spinning NMR

  • Han, Oc-Hee
    • Journal of the Korean Magnetic Resonance Society
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    • v.2 no.1
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    • pp.24-32
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    • 1998
  • Drawn polyethylene was studied by 13C cross polarization magic angle spinning techniques. Solid-solid phase transition from orthorhombic to monoclinic crystalline phase by drawing was observed. In addition, using a synchronized magic angle spinning 2 dimension technique, we confirmed that macroscopic ordering of the polyethylene was produced by drawing.

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Microstructural Changes of $SiO_2-Si$ During Liquid-Phase Sintering (액상소결단계에서 $SiO_2-Si$의 미세조직 변화)

  • 강대갑;정충환
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.443-447
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    • 1994
  • Compacts of mixed SiO2-Si powder were liquid phase sintered at 145$0^{\circ}C$ for up to 60 min in a hydrogen atmosphere. In contrast to the conventional microstructures of liquid phase sintered materials, the specimens showed that the solid phase of SiO2 formed a matrix while the liquid phase of Si was the dispersed in the solid matrix. The dispersion of liquid Si pockets was attributed to the high wetting angle of liquid Si on solid SiO2. Because of relatively high solubility of SiO2 in liquid Si at 145$0^{\circ}C$, SiO2 particles accommodated their shape via a solution-reprecipitation process. The liquid Si pockets grew by coalescing with their neighbour pockets. In the latter stage of the sintering, plate-shape grains appeared in the liquid Si pockets. The grains were SiO2 phase precipitated from the liquid Si which was oversaturated with oxygen during cooling to room temperature. By the formation and subsequent removal of the gaseous SiO phase due to the reaction between SiO2 and Si, the specimens became porous.

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Study on Confirmation of Solid-Meal Lag Phase of Gastric Emptying (고형음식물 위배출시 초기 정체기의 존재에 대한 연구)

  • Lee, Ji-Young;Lee, Kyoung-Soo;Kim, Chang-Guhn;Juhng, Seon-Kwan;Won, Jong-Jin;Nah, Yong-Ho
    • The Korean Journal of Nuclear Medicine
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    • v.25 no.2
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    • pp.207-210
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    • 1991
  • The purpose of this study was to examine the existence of a lag phase of gastric emptying of solid meals. We studied solid phase gastric emptying in 26 normal subject using continuous data aquisition for 30 minutes. Each ingested a 300 g meal containing $^{99m}Tc-labeled$ scrambled egg (solid 150g, milk 150 ml). Lag phase was determined by 1) inspection of the gastric emptying curve 2) time to a 2% decrease in stomach activity 3) the time of visual appearance of duodenal activity on computer image We concluded that solid meal lag phase exist.

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Eulerian Two-Phase Flow Analysis for Solid-Liquid Mixing in a Industrial Mixer (산업용 교반기의 고체-액체 혼합에 대한 Eulerian Two-Phase 유동해석)

  • Song, Ae-Kyung;Hur, Nahm-Keon;Won, Chan-Shik;Ahn, Ick-Jin
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.471-474
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    • 2006
  • The Mixer is apparatus that help precipitation or an inhomogeneous distribution of various phases to be mixed and that user makes necessary material mixing one or the other. Mainly the mixer which is used from chemical and food industry is very important system in engineering that mixes the material. The inside flow of the mixer under the actual states which put a basis in flow of the fluid is formed rotation of the impeller. The inside flow of impeller will be caused by various reasons change with shape of impeller, number of rotation, mixing material and flow pattern of free surface etc. Also mixer study depended in single-phase flow and experimental research. So the numerical analysis of flow mixing solid-fluid particle is simulated. It is become known, that the case where agitator inside working fluid includes the solid particle the sinkage reverse which the solid particle has decreases an agitation efficiency. From the research which it sees the hazard solid which examines the effect where the change of the sinkage territory which it follows agitation number of revolution and diameter of the particle goes mad to an agitator inside flow distribution - numerical analysis the inside flow distribution of liquid state with Eulerian Two-Phase Method.

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Solid Phase Synthesis of 3-(4-Hydroxyphenyl)coumarin: Preliminary Experiments for Combinatorial Synthesis of Substituted 3-Phenylcoumarin Derivatives

  • Bae, Hoon;Kim, Hak-Sung
    • Archives of Pharmacal Research
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    • v.27 no.8
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    • pp.811-815
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    • 2004
  • Coumarin and its derivatives occur widely in nature. Many attempts were made for synthesis of various coumarin derivatives because of their interesting biological activities. In this study, solid phase synthetic approach of 3-(4-hydroxyphenyl)coumarin was achieved for combinatorial synthesis of substituted 3-phenylcoumarin analogues. Starting from 4-hydroxyphenylacetic acid methyl ester, release of 3-(4-hydroxypnehyl)coumarin from polymer support was accom-plished.

Thermodynamic Assessment of the PbO-ZrO2 System

  • Koo, Bon-Keup;Ping Liang;Hans Jiirgen Seifert;Fritz Aldinger
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.205-210
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    • 1999
  • The thermodynamic properties and phase diagram of the$ PbO-ZrO_2$ system have been critically assessed using the Thermo-Calc program. Excess Gibbs energies were expressed by Redlich-Kister polynomials for the solid phases, by the two-sublattice ionic liquid model for the liquid phase and by the compound energy model for the solid solution phase. All solid phases were treated as stoichimetric compounds.

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