• 제목/요약/키워드: Solid composites

검색결과 333건 처리시간 0.026초

미연소 섬유분에 의한 도시 쓰레기 소각재 혼입 시멘트 복합재료의 성능감소 (Performance Degradation of Cement Composite Containing Municipal Solid Waste Incinerator Ash by Unburned Fabric)

  • 김형기
    • 자원리싸이클링
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    • 제24권4호
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    • pp.3-11
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    • 2015
  • 도시 쓰레기 소각재 내 미연소 섬유분(Unburned fabric)이 시멘트 복합재료의 기초 물성에 미치는 부정적 영향에 대해 실험적으로 검증하였다. 먼저, 섬유분을 많이 포함하고 있는 0.6 mm 이하 소각재 미분의 물리적, 화학적 특성을 확인하였다. 그 후, 소각재 미분이 혼입된 모르타르형 시멘트 복합재료의 유동성과 강도를 측정하고, 이 결과를 소각재 미분의 물리적, 화학적 특성과 연계하여 분석하였다. 실험 결과, 시멘트 복합재료의 유동성은 미연소 섬유분에 의해 크게 감소한 반면, 복합재료의 강도는 섬유분 보다 소각재 자체에 의해 감소함을 알 수 있었다. 따라서, 시멘트 복합재료의 성능을 고려 할 때, 복합재료 내 소각재의 혼입률과 함께 소각재 미분에 대한 혼입률도 제한되어야 함을 확인하였다.

Enhanced Electrochemical Properties of Surface Modified LiMn2O4 by Li-Fe Composites for Rechargeable Lithium Ion Batteries

  • Shi, Jin-Yi;Yi, Cheol-Woo;Liang, Lianhua;Kim, Keon
    • Bulletin of the Korean Chemical Society
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    • 제31권2호
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    • pp.309-314
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    • 2010
  • The surface modified $LiMn_2O_4$ materials with Li-Fe composites were prepared by a sol-gel method to improve the electrochemical performance of $LiMn_2O_4$ and were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), and transmission electron microscopy (TEM)-EDS. XRD results indicate that all the samples (modified and pristine samples) have cubic spinel structures, and XRD, XPS, and TEM-EDS data reveal the formation of $Li(Li_xFe_xMn_{2-2x})O_4$ solid solution on the surface of particles. For the electrochemical properties, the modified material demonstrated dramatically enhanced reversibility and stability even at elevated temperature. These improvements are attributed to the formation of the solid solution, and thus-formed solid solution phase on the surface of $LiMn_2O_4$ particle reduces the dissolution of Mn ion and suppresses the Jahn-Teller effect.

Prediction of Withdrawal Resistance of Single Screw on Korean Wood Products

  • AHN, Kyung-Sun;PANG, Sung-Jun;OH, Jung-Kwon
    • Journal of the Korean Wood Science and Technology
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    • 제49권1호
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    • pp.93-102
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    • 2021
  • In this article, withdrawal resistances of axially loaded self-tapping screws on wood products made by Korean Larch were predicted with existing estimation equation, and compared with experimental test data. The research was required because no design methodology for the withdrawal resistance of self-tapping screw is present in Korean building code (KBC). First, the withdrawal resistance of wood screw was predicted to use the withdrawal design value estimation equation in National Design Specification for Wood Construction (NDS). Second, three types of wood products, solid wood, cross-laminated timber (CLT) and plywood, were utilized for withdrawal test. For decades, various engineered wood products have been developed, especially cross-laminated timber (CLT) and hybrid timber composites such as timber composites of solid wood and plywood. Therefore, CLT and plywood were also investigated in this study as well as solid wood. Finally, the predicted values were compared with experimentally tested values. As the results, the tested values of solid wood and CLT were higher than the predicted values. In contrast, it is inaccurate to predict withdrawal resistance of plywood since prediction was higher than tested values.

$MoSi_2$/W 복합재료의 합성과 성질에 관한 연구 (Synthesis and Properties of In-situ $MoSi_2$/W Composites)

  • 장대규
    • 한국재료학회지
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    • 제8권10호
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    • pp.938-944
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    • 1998
  • $MoSi_2$에 W분말을 첨가하여 $MoSi_2$/W 복합재료를 $1600^{\circ}C$에서 3시간 동안 유지하면서 30MPa의 조건하에서 고온진공 가압기를 이용하여 제조하였으며, 텅스텐 분말의 첨가량이 $(Mo)Si_2$의 미세조직과 기계적 성질에 미치는 영향을 조사하였다. 텅스텐은 몰리브덴과 치환하면서 고용체 합금을 이루었으며, 입자의 크기는 텅스텐 분말의 첨가량이 증가할수록 감소하였다. 비커스경도는 텅스텐 분말의 첨가량이 증가할수록 향상되었으나, 반면에 압흔파단 강도는 오히려 감소되었다. 10%정도의 텅스텐 분말을 첨가하였을 때, 압흔파단 강도가 $4.5MPa$\sqrt{m}$로서 순수 $MoSi_2$$2.7MPa\sqrt{m}$에 비하여 향상되었음을 알 수 있었다.

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반용융재료의 제조 및 부품성형공정 (Fabrication of Semi-solid Materials and Components forming Processes)

  • 강충길
    • 소성∙가공
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    • 제3권1호
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    • pp.3-17
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    • 1994
  • The semi-solid metal forming for vigorously agitated semi-solid alloys has been widely studied over the last decade. Metal forming processes are now being developed using alloys in the semi-solid state, among them are rolling, forging, extrusion, and die casting. Some of these are now employed commercially to produce a components and are also used to fabricate metal matrix composites. The semi-solid materials can be processed either directly during solidification and for this purpose mechanical stirring was demonstrated to produce a highly solidification. This paper is concerned with the influence of processing parameters on limitations of semi-solid forming.

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티타늄금속기 복합재료의 강화공정에 관한 미시역학적 모델링 (Micro-mechanical Modeling of the Consolidation Processes in Titanium Metal Matrix Composites)

  • 김준완;김태원
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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    • pp.207-210
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    • 2002
  • Metal matrix composites(MMCs) are increasingly attractive for high technology components such as aerospace applications and transportations due to their high strength, stiffness, and toughness. Many processes for fabricating MMCs have been developed, and relatively simple Foil-Fiber-Foil method is usually employed in solid state consolidation processes. During the consolidation processes at high temperature, densification occurs by the inelastic flow of the matrix materials, and the process is coupled with the conditions of pressure, temperature and volume fraction of fiber and matrix materials. This is particularly important in titanium matrix composites, and thus a generic model based on micro-mechanical approaches enabling the evolution of density over time to be predicted has been developed. The mode developed is then implemented into FEM so that practical process simulation has been carried out. Further the experimental investigation of the consolidation behavior of SiC/Ti-6Al-4V composites using vacuum hot pressing has been performed, and the results obtained are compared with the model predictions.

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Thixoforming을 응용한 금속복합재료의 콤푸레서용 피스톤 제품의 성형 (Forming of Compressor Piston Part of Metal Matrix Composites by Thixoforming Process)

  • 이동건;강충길
    • 소성∙가공
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    • 제10권3호
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    • pp.223-234
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    • 2001
  • The characteristics of thixoforming process can decrease liquid segregation because of the improvement in fluidity in a globular microstructure state and utilizes flow without an air entrapment. Therefore, in order to obtain the sound parts of metal matrix composites by using thixoforming process which has co-existing solidus-liquidus phase, it is very important to design a die shape property and to obtain the fabrication conditions which affect the unifomity of the solid fraction on unfilling state and various defects throughout the fabricated parts. The die designs and fabrication conditions to obtain the good piston part are proposed for thixoforging process of metal matrix composites. When reheated metal matrix composites billets were transferred to the closed die gate, thixoforging were carried out under the various pressure(60, 80, 100MPa) with controled forging speed. The mechanical properties such as hardness and tensile strength for thixoforged parts have been investigated after T6 heat treatment.

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Rheo-Compocasting에 의한 $SiC_p$/6063 Al합금의 복합조직 (Composite Structures of $SiC_p$/6063 Aluminum Alloy by Rheo-Compocasting.)

  • 최정철
    • 한국주조공학회지
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    • 제10권4호
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    • pp.309-315
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    • 1990
  • Aluminum alloy matrix composites reinforced by SiC particles were prepared by rheocompocasting, a process which consists of the incoporation and distribution of reinforcement by stirring within a semi-solid alloy. When the volume fraction of SiCp and stirring speed were fixed, the dispersion of SiCp in Al-matrix alloy depended on stirring time and solid volume fraction in slurry. The results were as follows : 1) As a dispersed SiCp during stirring at $647^{\circ}C$ in 6063-Al alloy, SiC was better dispersed than that other temperature, where solid volume fraction was 43% in slurry. 2) When increased solid fraction in slurry, rate of dispersing SiC increased during stirring and porosities decreased in matrix alloy after casting. 3) Inspite of stirring with 800rpm, since solid particles of matrix alloy in slurry joined each other and occured joining growth, so that SiC was not dispersed into solid particle.

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Covalently-Bonded Solid Solution Formed by Combustion Synthesis

  • Ohyanagi, Manshi;Munir, Zuhair A.
    • The Korean Journal of Ceramics
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    • 제6권3호
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    • pp.250-257
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    • 2000
  • The feasibility of synthesizing SiC-AlN solid solution by field-activated combustion synthesis was demonstrated. At lower fields of 8-16.5V/cm, composites of AlN-rich and SiC-rich phases were synthesized, but at fields of 25-30 V/cm, the product was a 2H structure solid solution. Combustion synthesis of the solid solution by nitridation of aluminum with silicon carbide under a nitrogen gas pressure of 4-8 MPa was also investigated. The maximum combustion temperature and wave propagation velocity were found to be influenced by the electric field in the field-activated combustion synthesis, and by the green density and nitrogen pressure in the combustion nitridation. In both cases the formation of solid solutions is complete within seconds, considerably faster than in conventional methods which require hours.

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충전제-탄성체 상호작용. 9. 실리카/ 폴리우레탄 복합재료의 기계적 계면특성에 미치는 열처리의 영향 (Filler-Elastomer Interactions. 9. Effect of Thermal Treatment on Mechanical Interfacial Characteristics of Silica/Polyurethane Composites)

  • 박수진;조기숙
    • Elastomers and Composites
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    • 제37권4호
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    • pp.258-264
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    • 2002
  • 본 연구에서는 열처리에 의한 실리카의 표면특성과 실리카/폴리우레탄 복합재료의 기계적 계면물성에 대하여 고찰하였다. 열처리에 의한 실리카의 표면특성은 Fourier Transform-IR(FT-IR), Solid-state 29Si NMR spectroscopy, 그리고 접촉각을 통하여 알아보았으며 실리카/폴리우레탄 복합재료의 기계적 계면물성은 인열에너지 (GIIIC)를 측정하여 관찰하였다. 본 실험결과, 열처리 온도가 증가함에 따라 실리카의 Si-OH가 축합하여 Si-O-Si를 형성하고 표면자유에너지의 비극성 요소가 증가하는 것을 확인할 수 있었다. 이러한 결과로부터, 증가된 실리카의 표면자유에너지의 비극성요소는 폴리우레탄 내에 실리카의 분산성을 향상시켜 결과적으로 실리카/폴리우레탄 복합재료의 기계적 계면물성인 인열에너지가 증가된 것으로 사료된다.