• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.19 no.11
• /
• pp.1010-1013
• /
• 2006

Hydrogenated Diamond-like carbon (DLC) films were Prepared by the radio frequency plasma enhanced chemical vapor deposition (RF PECVD) method on silicon substrates using methane $(CH_4)$ and hydrogen $(H_2)$ gas for the application to solid lubricant of MEMS devices. We have checked the influence of varying RF power on tribological properties of DLC film. We have checked their performance as two kinds of method such as FFM (Friction Force Microscope) and BOD (Ball-on Disk) measurement. The friction coefficients and the contact number of cycles to steady state decreased as the increase of RF power with FFM and BOD measurement, respectively.

• Korean Chemical Engineering Research
• /
• v.56 no.5
• /
• pp.738-751
• /
• 2018

The effect of the reaction temperature and reaction time on the thermal oxidative purification quality of detonation nanodiamond (NDsoot) was investigated in a gas-solid fluidized bed reactor of a $0.10m-ID{\times}1.0m$-high stainless steel column with zirconia beads ($d_{SV}=99.2{\mu}m$). The carbon conversion increased with increasing the reaction temperature; however, when the reaction temperature was greater than 773 K, the carbon conversion did not increase. The content of $sp^3$-hybridized carbon at the reaction temperature of 703 K barely changed when the reaction time was more than 30 minutes, but at 773 K, the content decreased as preferred. At 703 K, the purification quality increased with the increasing reaction time; however, at 773 K, the purification quality increased up to 30 minutes and then decreased rapidly.

• Coupled systems mechanics
• /
• v.6 no.1
• /
• pp.1-15
• /
• 2017

Despite the exceptional mechanical properties of individual carbon nanotubes (CNTs), the effective properties of CNT-reinforced composites remain below expectations. The composite's microstructure has been identified as a key factor in explaining this discrepancy. In this contribution, a method for generating representative volume elements of aligned CNT sheets is presented. The model captures material characteristics such as random waviness and entanglement of individual nanotubes. Thus it allows studying microstructural effects on the composite's effective properties. Simulations investigating the strengthening effect of the application of a pre-stretch on the CNTs are carried out and found to be in very good agreement with experimental values. They highlight the importance of the nanotube's waviness and entanglement for the mechanical behavior of the composite. The presented representative volume elements are the first to accurately capture the waviness and entanglement of CNT sheets for realistically high volume fractions.

• Analytical Science and Technology
• /
• v.8 no.4
• /
• pp.477-480
• /
• 1995

Isotopic-spectral method [I] was applicated for determination of carbon in silicate materials (pure silica, guartz glasses, geological probs etc.). Isotopic heterogeneous balancing of carbon in gaseous phase and solid samples was carried out at the temperature of $1500-1900^{\circ}K$. Spectroscopic measuring of isotope concentration in a balanced gas was made using the electron-vibrational band heads of CO molecules excited in HF discharge. Limits of detection of carbon concentrations appear to be $n^*10^{-6}$.

• Proceedings of the Korean Magnetic Resonance Society Conference
• /
• 2002.08a
• /
• pp.83-83
• /
• 2002

• Applied Chemistry for Engineering
• /
• v.29 no.5
• /
• pp.626-629
• /
• 2018

Fuel cell is one of the promising electrochemical technologies enabling power production with various fuel sources such as hydrogen, hydrocarbon and even solid carbon. However, its long-term performance is often unstable and unpredictable. In this work, we observed that gasification-driven hydrocarbons were the culprit of unpredictability. Therefore, we controlled the presence of hydrocarbons with the help of external gas supply, i.e. argon and carbon dioxide, and suggested the optimal amount of carbon dioxide required for predictable fuel cell operations. Our optimization strategy was based upon the following observations; carbon dioxide can work as both an inert gas and a fuel precursor, depending on its amount present in the reactor. When deficient, the carbon dioxide cannot fully promote the reverse Boudouard reaction that produces carbon monoxide fuel. When overly present, the carbon dioxide works as an inert gas that causes fuel loss. In addition, the excessive carbon monoxide may result in coking on the catalyst surface, leading to the decrease in the power performance.

• The Korean Journal of Food And Nutrition
• /
• v.11 no.6
• /
• pp.667-672
• /
• 1998

The possibility of solid-substrate fermentation of Lentinus edoes for the productin of protein-boud polysaccharides (PBP) was studied. Zeolite and orchid-pot soil were used as solid materials for the culture because of the desirable physical properties. Sucrose and starch were good carbon sources for the production of PBP by the solid-substrate fermentatin of L. edodes. Among the nitrogen source, bactosoyton was very effective for the PBP production. The optimum pH for solid-substrate fementation for the production of PBP was at pH of 5.5. The PBP production reached to 5∼5.5mg per 100g solid-substrate.

• Fire Science and Engineering
• /
• v.15 no.2
• /
• pp.6-12
• /
• 2001

The objective of the present work is to examine the cooling effect of a water fire extinguishing agent containing NaBr(30%, w/w). The carbon steel and teflon were used as a hot solid. The temperature on the hot solid surface ranged from $70^{\circ}c$ to $116^{\circ}c$ and water droplet size was 2.6 mm in the experiments. It is suggested that regardless of the hot solid material, the indepth temperature of the case of NaBr solution is lower than that of pure water and the variation of indepth temperature of teflon is higher than that of carbon steel. Regardless of the hot solid material, the time averaged heat flux of the case of pure water is higher than that of NaBr solution. the apparent evaporation time of the case of pure water is shorter than that of NaBr solution.

• Fire Science and Engineering
• /
• v.14 no.3
• /
• pp.13-18
• /
• 2000

The objective of the present work is to examine the cooling characteristics of water droplet on the unburned surface. The hot solid surface material used brass, carbon steel and copper at temperature ranging from 70 to $116^{\circ}$. the droplet size is from 2.4 mm to 3.0 mm. The CCD camera was used to record the evaporation histories of the droplets. and the evaporation time of the droplet on the hot solid surface could be determined by using frame-by-frame analysis of the video records. It is found that during the droplet evaporation process for copper the temperature remains nearly constant, whereas for carbon steel the temperature continuously decreases about $1^{\circ}$. During the droplet evaporation process on the hot solid surface, regardless of solid materials, nondimensional droplet volume decreases nondimensional evaporation time increases.

• Journal of Powder Materials
• /
• v.9 no.4
• /
• pp.235-244
• /
• 2002

The effects of residual impurities on solid state sintering of the powder injection molded (PIMed) W-15wt%Cu nanocomposite powder were investigated. The W-Cu nanocomposite powder was produced by the mech-ano-chemical process consisting of high energy ball-milling and hydrogen reduction of W blue powder-cuO mixture. Solid state sintering of the powder compacts was conducted at $1050^{\circ}C$ for 2~10 h in hydrogen atmosphere. The den-sification of PIM specimen was slightly larger than that of PM(conventional PM specimen), being due to fast coalescence of aggregate in the PIM. The only difference between PIM and PM specimens was the amount of residual impurities. The carbon as a strong reduction agent effectively reduced residual W oxide in the PIM specimen. The $H_2O$ formed by $H_2$ reduction of oxide disintegrated W-Cu aggregates during removal process, on the contrary to this, micropore volume rapidly decreased due to coalescence of the disintegrated W-Cu aggregates during evolution of CO.It can be concluded that the higher densification was due to the earlier occurred Cu phase spreading that was induced by effective removal of residual oxides by carbon.