• 제목/요약/키워드: Solid carbon

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The Analysis of the temperature distribution in Carbon/Phenolic composite by thermal decomposition parameters (열분해 특성상수를 활용한 탄소/페놀릭 복합재료의 온도분포 해석)

  • Kim Yun-Chul;Park Young-Che
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.45-49
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    • 2006
  • The thermal degradation of carbon fiber reinforced phenolic composites have been studied at high temperature by using thermogravimetry analysis (TGA). The aim is that ultimately it can be used to predict the service temperature during solid rocket firing for any level and type of mechanical loading and to recommend protection systems required. To simulate the high heating rate in firing condition, the modified thermal decomposition constant (1000 K/min) was used for FEM analysis. The temperature distribution and the thickness of thermal decomposition were estimated well and we could predict the thickness of thermal decomposition within ${\pm}1mm$.

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The Distribution and Interannual Variation in Suspended Solid and Particulate Organic Carbon in the Northern East China Sea (동중국해 북부해역에서 부유물질과 입자성유기탄소의 분포 특성 및 연간 변화)

  • Kim, Dong-Seon;Choi, Sang-Hwa;Kim, Kyung-Hee;Kim, Cheol-Ho
    • Ocean and Polar Research
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    • v.31 no.2
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    • pp.219-229
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    • 2009
  • In order to establish annual variations in the marine ecosystem of the East China Sea, suspended solids (SSs) and particulate organic carbon (POC) were extensively investigated in the northern part of the East China Sea from August 2003 to April 2008. Surface SS concentrations showed large spatial variations in spring and fall, but not in summer. Surface SS concentrations in spring were lower than those in summer and fall. In summer, SSs discharged from Changjiang were mostly deposited in the coastal areas and did not reach our study area which was located about 260 km from the river mouth. High SS concentrations were observed near the bottom, which resulted from resuspension of bottom sediments by the bottom currents. Surface POC concentrations did not exhibited large seasonal variations. Phytoplankton biomass was a main factor controlling surface POC concentrations. POC/chlorophyll ratios showed large seasonal variations, with maximum numbers in summer. POC/PON ratios were higher in summer than the Redefied ratio (6.6), while they were lower in spring and fall. In summer, higher POC/chlorophyll and POC/PON ratios were probably attributed to the high phytoplankton mortality caused by nutrient depletion in surface waters.

Wear Characterization of $Al/Al_2O_3$ Composites Reinforced with Hybrid of Carbon Fibers and SiC Whiskers (탄소섬유와 SiC 휘스커를 혼합한 $Al/Al_2O_3$ 복합재료의 마멸특성)

  • 봉하동;송정일;한경섭
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1619-1629
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    • 1995
  • The Al/Al$_{2}$O$_{3}$ SiC and Al/Al$_{2}$O$_{3}$/C hybrid metal matrix composites (MMCs) were fabricated by squeeze infiltration method. Uniform distribution of reinforcements were found in the microstructure of metal matrix composites. Mechanical tests were carried out under various test conditions to clearly identify mechanical behavior of MMCs, and the wear mechanism of Al/Al$_{2}$O$_{3}$/(SiC or C) hybrid metal matrix composites were investigated. The tensile strength and hardness of hybrid composites was resulted in increasing compared with those of the unreinforced matrix alloy. Wear resistance was strongly dependent upon kinds of fiber, volume fraction and sliding speed. The wear resistance of metal matrix composites was remarkably improved by the addition of reinforcements. Especially, the wear resistance of the hybrid composites of carbon fibers was more effective than in the composites reinforced with alumina and SiC whiskers of reinforcements. This was due to the effect of carbon fiber on the solid lubrication. Wear mechanisms of hybrid composites were suggested from wear surface analyses. The major wear mechanism of hybrid composites was the abrasive wear at low to intermediate sliding speed, and the melting wear at intermediate to high sliding speed.

Vibration analysis of porous nanocomposite viscoelastic plate reinforced by FG-SWCNTs based on a nonlocal strain gradient theory

  • Khazaei, Pegah;Mohammadimehr, Mehdi
    • Computers and Concrete
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    • v.26 no.1
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    • pp.31-52
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    • 2020
  • This paper investigates the size dependent effect on the vibration analysis of a porous nanocomposite viscoelastic plate reinforced by functionally graded-single walled carbon nanotubes (FG-SWCNTs) by considering nonlocal strain gradient theory. Therefore, using energy method and Hamilton's principle, the equations of motion are derived. In this article, the effects of nonlocal parameter, aspect ratio, strain gradient parameter, volume fraction of carbon nanotubes (CNTs), damping coefficient, porosity coefficient, and temperature change on the natural frequency are perused. The innovation of this paper is to compare the effectiveness of each mentioned parameters individually on the free vibrations of this plate and to represent the appropriate value for each parameter to achieve an ideal nanocomposite plate that minimizes vibration. The results are verified with those referenced in the paper. The results illustrate that the effect of damping coefficient on the increase of natural frequency is significantly higher than the other parameters effect, and the effects of the strain gradient parameter and nonlocal parameter on the natural frequency increase are less than damping coefficient effect, respectively. Furthermore, the results indicate that the natural frequency decreases with a rise in the nonlocal parameter, aspect ratio and temperature change. Also, the natural frequency increases with a rise in the strain gradient parameter and CNTs volume fraction. This study can be used for optimizing the industrial and medical designs, such as automotive industry, aerospace engineering and water purification system, by considering ideal properties for the nanocomposite plate.

Electrochemical Properties of LiFePO4 Cathode Materials for Lithium Polymer Batteries (리튬폴리머전지용 정극활물질 LiFePO4의 전기화학적 특성)

  • Kong Ming-Zhe;Kim Hyun-Soo;Gu Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.519-523
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    • 2006
  • $LiFePO_4$ has been received attention as a potential cathode material for the lithium secondary batteries. In our study, $LiFePO_4$ cathode active materials were synthesized by a solid-state reaction. It was modified by coating $TiO_2$ and carbon in order to enhance cyclic performance and electronic conductivity. $TiO_2$ and carbon coatings on $LiFePO_4$ materials enhanced the electronic conductivity and its charge/discharge capacity. For lithium polymer battery applications, $LiFePO_4$/solid polymer electrolyte (SPE)/Li and $LiFePO_{4}-TiO_{2}/SPE/Li$ cells were characterized by a cyclic voltammetry and charge/discharge cycling. The electrode with $LiFePO_{4}-carbon-TiO_{2}$ in PVDF-PC-EC-$LiClO_{4}$ electrolyte showed promising capacity of above 100 mAh/g at 1C rate.

Feasibility of Recycling Residual Solid from Hydrothermal Treatment of Excess Sludge

  • Kim, Kyoung-Rean;Fujie, Koichi;Fujisawa, Toshiharu
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.112-118
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    • 2008
  • Residual solid in excess sludge treated by hydrothermal reaction was investigated as raw material for its recycling. Treated excess sludge and residual solid were also focused on their content change during hydrothermal reaction. Two kinds of excess sludge, obtained from a local food factory and a municipal wastewater treatment process, were tested under various conditions. Following hydrothermal reaction, depending on the reaction conditions, biodegradable substrates in treated excess sludge appeared to increase. The separated residual solid was a composite composed of organic and inorganic materials. The proportion of carbon varied from 34.0 to 41.6% depending on reaction conditions. Although 1.89% of hazardous materials were detected, SiO2 (Quartz) was a predominant constituent of the residual solid. X-ray diffraction (XRD) experiments revealed that the residual solid was of a partially amorphous state, suggesting that the residual solids could be easily converted to stable and non harmful substances through a stabilization process. Thus, this technology could be successfully used to control excess sludge and its reuse.

Studies on Electrical Double Layer Capacitor Based on Mesoporous Activated Carbon

  • Meigen, Deng;Yihong, Feng;Bangchao, Yang
    • Carbon letters
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    • v.6 no.2
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    • pp.86-88
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    • 2005
  • Mesoporous activated carbon (AC) was prepared from aged petroleum coke through chemical activation. The AC has a specific surface area of 1733 $m^2/g$ and a mean pore diameter of 2.37 nm. The volume fraction of 2 to 4nm pores is 56.74%. At a current density of 10 mA/$cm^2$, a specific capacitance of 240 F/g is achieved representing the use factor of the surface area of 69.2%. And the electrical double layer capacitor (EDLC) based on the AC shows an excellent power performance. This result suggests that the presence of high fraction of mesopores can effectively increase the adsorption efficiency of the specific surface area of the AC and enhance the power performance of EDLC based on the efficient surface area of the AC.

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Crystallization of Forsterite Xerogel under Carbon Dioxide: A New Crystalline Material Synthesized by Homogeneous Distribution of Carbonaceous Component into Forsterite Xerogel

  • 송미영;김수주;권혜영;박선희;박동곤;권호진;권영욱;James M. Burlitch
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.517-524
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    • 1999
  • By heating the magnesiumsilicate (Mg2SiO4:forsterite) xerogel in carbon dioxide, carbonaceous component was intentionally introduced into the amorphous solid precursor. Carbon was introduced homogeneously as unidentate carbonate. Upon being heated at 800 。C in carbon dioxide, the xerogel which had homogeneously distributed carbonaceous component in it crystallized into a single phase product of a new crystalline material, which had approximate composition of Mg8Si4Ol8C. The powder X-ray diffraction pattern of the new crystalline material did not match with any known crystalline compound registered in the powder diffraction file. Crystallization from amorphous xeroget to the new crystalline phase occurred in a very narrow range of temperature, from 750 。C to 850 。C in carbon dioxide, or in dty oxygen. Upon being heated above 850 。C, carbonaceous component was expelled from the product, accompanied by irreversible transition from the new crystalline material to forsterite.

Synthesis of Silicon Tracelsss Linker for Solid-Phase Reaction

  • Mun Han-Seo;Seong Jin-Hyun
    • Archives of Pharmacal Research
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    • v.27 no.4
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    • pp.371-375
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    • 2004
  • The silicon linker is the foremost traceless linker used in solid-phase reactions. Hydrogen fluo-ride (HF) or trifluoroacetic aicd (TFA) can remove the silicon linker with the silicon atom being replaced by a hydrogen atom. In this experiment, the linkers 1c and 2d, which are the most useful in solid-phase reactions, were synthesized, Linker 1c is composed of seven linearly linked carbons and linker 2d includes an oxygen atom in the linear carbon chain to increase the solvation capacity. The carboxylic acid component of linker 1c and 2d forms an amide or ester bond with resin. The synthesized linkers 1c and 2d could be utilized in constructing a chemical compound library that includes indole, benzodiazepine and phenothiazine (aromatic ring compounds).