• 제목/요약/키워드: Solid Electrolytes

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A Review of Inorganic Solid Electrolytes for All-Solid-State Lithium Batteries: Challenges and Progress

  • Seul Ki Choi;Jaehun Han;Gi Jeong Kim;Yeon Hee Kim;Jaewon Choi;MinHo Yang
    • 한국분말재료학회지
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    • 제31권4호
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    • pp.293-301
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    • 2024
  • All-solid-state lithium batteries (ASSLBs) are receiving attention as a prospective next-generation secondary battery technology that can reduce the risk of commercial lithium-ion batteries by replacing flammable organic liquid electrolytes with non-flammable solid electrolytes. The practical application of ASSLBs requires developing robust solid electrolytes that possess ionic conductivity at room temperature on a par with that of organic liquids. These solid electrolytes must also be thermally and chemically stable, as well as compatible with electrode materials. Inorganic solid electrolytes, including oxide and sulfide-based compounds, are being studied as promising future candidates for ASSLBs due to their higher ionic conductivity and thermal stability than polymer electrolytes. Here, we present the challenges currently facing the development of oxide and sulfide-based solid electrolytes, as well as the research efforts underway aiming to resolve these challenges.

차세대 리튬이차전지를 위한 산화물 고체전해질의 연구동향 (Research progress of oxide solid electrolytes for next-generation Li-ion batteries)

  • 강병우;박희택;우승준;강민석;김아빈
    • 세라미스트
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    • 제21권4호
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    • pp.349-365
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    • 2018
  • Since the electrification of vehicles has been extended, solid-state batteries have been attracting a lot of interest because of their superior safety. Especially, polymer, sulfide, and oxide based materials are being studied as solid electrolytes, and each type of materials has advantaged and disadvantages over others. Oxide electrolytes has higher chemical and electrochemical stability compared to the other types of electrolytes. However, ionic conductivity isn't high enough as much as that of organic liquid electrolytes. Also, there are many difficulties of fabricating solid-state batteries with oxide based electrolytes because they require a sintering process at very high temperature (above ${\sim}800^{\circ}C$). Herein, we review recent studies of solid-state batteries with oxide based electrolytes about the ionic conductivity, interfacial reactions with Li metal, and preparation of solid-state cell.

Effect of Al and Nb Doping on the Electrochemical Characteristics of Garnet-type Li7La3Zr2O12 Solid Electrolytes

  • Ahmed Tarif;Chan-Jin Park
    • Corrosion Science and Technology
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    • 제22권6호
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    • pp.408-418
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    • 2023
  • In this study, we synthesized and characterized garnet-type Li7-xAlxLa3Zr2-(5/4)yNbyO12 (LALZN) solid electrolytes for all-solid-state battery applications. Our novel approach focused on enhancing ionic conductivity, which is crucial for battery efficiency. A systematic examination found that co-doping with Al and Nb significantly improved this conductivity. Al3+ and Nb5+ ions were incorporated at Li+ and Zr4+ sites, respectively. This doping resulted in LALZN electrolytes with optimized properties, most notably enhanced ionic conductivity. An optimized mixture with 0.25 mol each of Al and Nb dopants achieved a peak conductivity of 1.32 × 10-4 S cm-1. We fabricated symmetric cells using these electrolytes and observed excellent charge-discharge profiles and remarkable cycling longevity, demonstrating the potential for long-term application in battery systems. The garnet-type LALZN solid electrolytes, with their high ionic conductivity and stability, show great potential for enhancing the performance of all-solid-state batteries. This study not only advances the understanding of effective doping strategies but also underscores the practical applicability of the LALZN system in modern energy storage solutions.

Ionic liquids to the rescue? Overcoming the ionic conductivity limitations of polymer electrolytes

  • Hendcrson W.A.;Shin J.H.;Alessandrini F.;Passcrini S.
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2003년도 전지기술심포지움
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    • pp.153-168
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    • 2003
  • Polymer electrolytes - solid polymeric membranes with dissolved salts - are being intensively studied for use in all-solid-state lithium-metal-polymer consumer electronic device. The low ionic conductivity at room temperature of existing polymer electrolytes, however, has seriously hindered the development of such batteries for many applications. The incorporation of salts molten at room temperature (room temperature ionic liquids or RTILs) into polymer electrolytes may be the necessary solution to overcoming the inherent ionic conductivity limitations of 'dry' polymer electrolytes.

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리튬이차전지용 고체 전해질의 최근 진전과 전망 (Recent Progress and Perspectives of Solid Electrolytes for Lithium Rechargeable Batteries)

  • 김주미;오지민;김주영;이영기;김광만
    • 전기화학회지
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    • 제22권3호
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    • pp.87-103
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    • 2019
  • 현재 상용화되어 있는 리튬이온전지에 사용하고 있는 비수계 유기 전해액은 가연성, 부식성, 고휘발성, 열적 불안정성 등의 단점 때문에 더욱 안전하고 장수명을 보이는 고체 전해질로 대체하는 연구가 진행되고 있으며, 이것은 전기자동차 및 에너지저장 시스템과 같은 중대형 이차전지에도 효율적으로 활용될 수 있다. 다양한 형태의 고체 전해질 중에서 현재 고분자 매트릭스에 활성 무기 충진재가 포함되어 있는 복합 고체 전해질이 고이온전도도와 전극과의 탁월한 계면접촉을 이루는데 가장 유리한 것으로 알려졌다. 본 총설에서는 우선 고체 전해질의 종류와 연혁에 관해 간단히 소개하고, 고분자 및 무기 충진재 (불활성 및 활성)로 구성되는 고체 고분자 전해질 및 무기 고체 전해질의 기본적 물성 및 전기화학적 특성을 개괄한다. 또한 이 소재들의 형상을 기준으로 입자형 (0D), 섬유형 (1D), 평판형 (2D), 입체형 (3D)의 형식으로 구성된 복합고체 전해질과 이에 따른 전고체 전지의 전기화학적 특성을 논의한다. 특히 리튬금속 음전극을 사용하는 전고체 전지에 있어서 양전극-전해질 계면, 음전극-전해질 계면, 입자간 계면의 특성에 관해 소개하고, 마지막으로 현재까지 보고된 관련 총설들을 참조하여 복합 고체 전해질 기술의 현재 요구조건 및 미래 전망을 알아본다.

전고상 전지를 위한 스파크 플라스마 소결 기술과 응용 (Spark Plasma Sintering Technique and Application for All-Solid-State Batteries)

  • 이석희
    • 세라미스트
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    • 제22권2호
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    • pp.170-181
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    • 2019
  • All-solid-state batteries have received increasing attention because of their high safety aspect and high energy and power densities. However, the inferior solid-solid interfaces between solid electrolyte and active materials in electrode, which cause high interfacial resistance, reduce ion and electron transfer rate and limit battery performance. Recently, spark plasma sintering is emerging as a promising technique for fabricating solid electrolytes and composite-electrodes. Herein, this paper focuses on the overview of spark plasma sintering to fabricate solid electrolytes and composite-electrodes for all-solid-state batteries. In the end, future opportunities and challenges associated with SPS technique for all-solid-state batteries are described.

Fillers for Solid-State Polymer Electrolytes: Highlight

  • Jung, Srun;Kim, Dae-Won;Lee, Sang-Deuk;Cheong, Minserk Cheong;Nguyen, Dinh Quan;Cho, Byung-Won;Kim, Hoon-Sik
    • Bulletin of the Korean Chemical Society
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    • 제30권10호
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    • pp.2355-2361
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    • 2009
  • The current solid polymer electrolytes suffer from poor conductivity, low mechanical and electrochemical stability toward the lithium electrodes. To improve the performance of solid polymer electrolytes, the addition of nanoparticle fillers to the polymer electrolyte is being extensively investigated. In this paper, a brief review on the state of art of solid fillers for lithium battery electrolytes is presented.

계면 제어를 기반으로 한 고성능 전고체 전지 연구 (Review of interface engineering for high-performance all-solid-state batteries)

  • 황인수;이현정
    • 산업기술연구
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    • 제42권1호
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    • pp.19-27
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    • 2022
  • This review will discuss the effort to understand the interfacial reactions at the anode and cathode sides of all-solid-state batteries. Antiperovskite solid electrolytes have received increasing attention due to their low melting points and anion tunability which allow controlling microstructure and crystallographic structures of this material system. Antiperovskite solid electrolytes pave the way for the understanding relationship between critical current density and mechanical properties of solid electrolytes. Microstructure engineering of cathode materials has been introduced to mitigate the volume change of cathode materials in solid-state batteries. The hollow microstructure coupled with a robust outer oxide layer effectively mitigates both volume change and stress level of cathode materials induced by lithium insertion and extraction, thus improving the structural stability of the cathode and outer oxide layer, which results in stable cycling performance of all-solid-state batteries.

Effect of Poly(ethylene glycol) dimethyl ether Plasticizer on Ionic Conductivity of Cross-Linked Poly[siloxane-g-oligo(ethylene oxide)] Solid Polymer Electrolytes

  • Kang, Yongku;Seo, Yeon-Ho;Kim, Dong-Wook;Lee, Chang-Jin
    • Macromolecular Research
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    • 제12권5호
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    • pp.431-436
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    • 2004
  • Cross-linked network solid polymer electrolytes were prepared by means of in situ hydrosilylation between poly[hydromethylslioxane-g-oligo(ethylene oxide)] and diallyl or triallyl group-containing poly(ethylene glycols). The conductivities of the resulting polymer electrolytes were greatly enhanced upon the addition of poly(ethylene glycol) dimethyl ether (PEGDME) as an ion-conducting plasticizer. Conductivities of the cross-linked polymer electrolytes were more dependent on the molecular weight of PEGDME than on the cross-linkers. The maximum conductivity was found to be 5.6${\times}$10$\^$-4/ S/cm at 30$^{\circ}C$ for the sample containing 75 wt% of PEGDME (M$\_$n/ =400). These electrolytes exhibited electrochemical stability up to 4.5 V against the lithium reference electrode. We observed reversible electrochemical plating/stripping of lithium on the nickel electrode.