• Title/Summary/Keyword: Solid Dielectric

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Solid State Reactions and Dielectric Properties of $BaTiO_3-SrTiO_2$ System ($BaTiO_3-SrTiO_2$ 계의 고상반응과 유전성)

  • 윤기현;조경화;이남양
    • Journal of the Korean Ceramic Society
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    • v.22 no.2
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    • pp.63-67
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    • 1985
  • $BaTiO_3$ and $SrTiO_2$ were mixed with the mole ratio of 36:65:50, 50: 50 and 65:35 and then heated at 110$0^{\circ}C$~130$0^{\circ}C$ for 1~64 hrs. The solid state reactions and dielectric properties were investigated as a function of amount of solid solution. Activation energy of solid solution decreased with increasing amount of $BaTiO_3$ due to fast diffusion of $Ba^{2+}$ ions. Dielectric constants increased with increasing the soaking time at 125$0^{\circ}C$and 130$0^{\circ}C$ and Curie Temperature shifted to higher temperature with increasing the soaking time at 125$0^{\circ}C$ and 130$0^{\circ}C$. It attributes to the am-ount of solid solution and grain growth, Dielectric constants decreased and Curie Temperature shifted to lower temperature due to decreasing polari-zability.

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A Study on the Surface Discharge Characteristics by Dielectric Constant and Diameter of Solid Dielectrics to Improve Surface Dielectric Strength in Eco-Friendly Insulation Gas (친환경 절연가스 중 연면절연성 향상을 위한 고체유전체의 유전율과 지름에 따른 연면방전특성 연구)

  • Lim, Dong-Young;Min, Gyeong-Jun;Park, He-Rie;Choi, Eun-Hyeok;Choi, Sang-Tae;Park, Won-Zoo;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.1
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    • pp.85-91
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    • 2013
  • This paper studied surface discharge characteristics by a dielectric constant and diameter of solid dielectrics in $N_2/O_2$ mixture gas. Applied electric field strength at $N_2/O_2$ mixture gas was changed from the dielectric constant and diameter of the solid dielectrics, and insulation performance of the $N_2/O_2$ mixture gas determined surface discharge voltage. In each of the diameter at the solid dielectrics, the surface discharge voltage was increased by lengthening surface distance, whereas increasing rate of the surface discharge voltage was different from gas pressure. Thus, In this paper, main factors of surface discharge are as follows. 1) Insulation performance of $N_2/O_2$ mixture gas, 2) Dielectric constant of solid dielectrics, 3) Surface discharge path. It was clear that the surface discharge voltage depend on the main factors. These results will be applied to useful data for an eco-friendly composite insulation design.

Mechanism and Characteristics of the Surface Flashover on the Laminated Solid Dielectric in N2/O2 Mixture Gas (N2/O2 혼합가스 중 적층된 고체유전체에 대한 연면방전의 메커니즘과 특성)

  • Lim, Dong-Young;Choi, Eun-Hyeok;Choi, Sang-Tae;Bae, Sungwoo;Lee, Kwang-Sik;Choi, Byoung-Ju
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.8
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    • pp.32-39
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    • 2015
  • This paper presents the surface flashover mechanism of a laminated solid dielectric and describes the surface flashover characteristics with the inherent capacitance of the laminated solid dielectric in a $N_2/O_2$ mixture gas (8:2) under an quasi uniform field. It was found that the electron emission at a cathode and the high-local electric field region around an anode were important factors to reasonably describe the surface flashover mechanism. The surface flashover voltage by the mechanism decreased with the inherent capacitance increase of the laminated solid dielectric. In addition to the surface flashover mechanism and its characteristics, the surface flashover voltage equations as a function of the inherent capacitance were derived by considering a gas pressure used in future eco-friendly GIS and the factors influencing the surface flashover.

Microstructural Characterization and Dielectric Properties of Barium Titanate Solid Solutions with Donor Dopants

  • Kim, Yeon-Jung;Hyun, June-Won;Kim, Hee-Soo;Lee, Joo-Ho;Yun, Mi-Young;Noh, S.J.;Ahn, Yong-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1267-1273
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    • 2009
  • The correlation between the sintering temperature and dielectric properties in the $Nb^{5+}\;and\;Ta^{5+}$ doped BaTi$O_3$ solid solutions have been investigated. The samples were sintered at temperatures ranging from 1250 to 1350 ${^{\circ}C}$ for 4 h in air. SEM, XRD and SEM/EDS techniques were used to examine the structure of the samples with particular focus on the incorporation of $Nb^{5+}\;and\;Ta^{5+}$ ions into the BaTi$O_3$ crystal lattice. The X-ray diffraction peaks of (111), (200) and (002) planes of BaTi$O_3$ solid solution doped with different fractions of $Nb^{5+}\;and\;Ta^{5+}$ were investigated. The dielectric properties were analyzed and the relationship between the properties and structure of doped BaTi$O_3$ was established. The fine-grain and high density of the doped BaTi$O_3$ ceramics resulted in excellent dielectric properties. The dielectric properties of this solid solutions were improved by adding a small amount of dopants. The transition temperature of the 1.0 mole% $Ta^{5+}$ doped BaTi$O_3$ solid solution was $\sim$110 ${^{\circ}C}$ with a dielectric constant of 3000 at room temperature. At temperatures above the Curie temperatures, the dielectric constant followed the Curie-Weiss law.

Surface discharge Characteristics for solid dielectric under non-uniform field (불평등전계 하의 고체절연물 연면방전특성)

  • Park, He-Rie;Lee, Jung-Hwan;Choi, Eun-Hyuck;Park, Sung-Gyu;Kim, Lee-Kook;Kim, Ki-Chae;Lee, Kwang-Sik
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.05a
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    • pp.270-272
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    • 2009
  • This paper presents a basic data of the surface discharge characteristics for solid dielectric under non-uniform field in $N_2/O_2$ mixture gas. Used electrodes are needle and plane. Used solid dielectric is expoxy resin. With the variation of the mixture rates of the gas by 80[%]:20[%], 60[%]:40[%] and 40[%]:60[%] in same condition, we can obtain different surface dielectric strength. Increased Pressure and thickness caused increased surface dielectric strength.

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Dielectric Characteristics of PbSc1/2Nb1/2O3 Prepared by Using the One-step Solid State Reaction

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
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    • v.25 no.4
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    • pp.77-80
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    • 2016
  • The $PbSc_{1/2}Nb_{1/2}O_3$ ceramics at a relatively low temperature of $1300^{\circ}C$ was successful synthesized. Solid state reaction of two-step process is not necessary. The dielectric constant, dielectric loss and admittance of ceramic samples were determined. The pyroelectric characteristics are in good agreement with the dielectric properties. Ferroelectric properties of well-formed the $PbSc_{1/2}Nb_{1/2}O_3$ ceramics are in agreement with broad distribution of relaxation phenomenon. Relatively strong frequency dependent of dielectric constant is observed at about $110^{\circ}C$. The distinct thermal hysteresis was observed in the measurement of the dielectric constant and dielectric loss. The critical exponents of during cooling and heating measurements in the $PbSc_{1/2}Nb_{1/2}O_3$ ceramics were 1.14 and 1.59 at 1 kHz, respectively.

Surface Discharge Characteristics of Solid Dielectrics in N2/O2 Mixture Gas for Eco-Friendly Insulation Design (친환경 절연설계를 위한 N2/O2 혼합가스 중 고체유전체 종류에 따른 연면방전특성)

  • Lim, Dong-Young;Park, He-Rie;Choi, Eun-Hyeok;Choi, Sang-Tae;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.3
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    • pp.9-15
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    • 2012
  • In this paper, we deal with a surface discharge that caused an aggravation of the dielectric strength in the $N_2/O_2$ mixture gas, When composit dielectrics were formed from the use of a solid dielectric. It was found from this study that the surface discharge voltage was deeply involved in the mixture ratio of $O_2$, the electrical property of the solid dielectric, kind of the solid dielectric, an electric field at the triple junction and a medium effect. These results expect basic data that will be used to transmission and distribution power system equipment using the $N_2/O_2$ mixture gas.

A Superior Description of AC Behavior in Polycrystalline Solid Electrolytes with Current-Constriction Effects

  • Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.150-161
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    • 2016
  • The conventional brick-layer model is not satisfactory either in theory or in practice for the description of dispersive responses of polycrystalline solid electrolytes with current-constriction effects at the grain boundaries. Parallel networks of complex dielectric functions have been shown to successfully describe the AC responses of polycrystalline sodium conductors over a wide temperature and frequency range using only around ten model parameters of well-defined physical significance. The approach can be generally applied to many solid electrolyte systems. The present work illustrates the approach by simulation. Problems of bricklayer model analysis are demonstrated by fitting analysis of the simulated data under experimental conditions.

The Estimation of the Dielectric Strength Decrease of the Solid-solid Interfaces by using the Applied Voltage to Breakdown Time Characteristics

  • Shin, Cheol-Gi;Bae, Duck-Kweon
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.278-282
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    • 2007
  • In the complex insulation system that is used in extra high voltage(EHV) devices, according to the trend for electric power equipment of high capacity and reduction of its size, macro interfaces between two different bulk materials which affect the stability of insulation system exist inevitably. In this paper, the dielectric strength decrease of the macro interfaces between epoxy and ethylene propylene diene terpolymer(EPDM) was estimated by using the applied voltage to breakdown time characteristics. Firstly, the AC short time dielectric strength of specimens was measured at room temperature. Then, the breakdown time was measured under the applied constant voltage which is 70% of short time breakdown voltage. With these processes, the life exponent n was determined by inverse power law, and the long time breakdown voltage can be evaluated. The best condition of the interface was LOS(low viscosity(350 cSt) silicone oil spread specimen). When 30 years last on the specimens, the breakdown voltage was estimated 44% of the short time breakdown voltage.

Uncertainty Analysis and Compensation of the Cell for Permittivity Measurement of Solid Materials (고체재료의 유전율 측정용 Cell의 불확도 분석과 보상)

  • Kim, Han-Jun;Yu, Kwang-Min;Kang, Jeon-Hong;Han, Sang-Ok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.1
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    • pp.53-56
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    • 2008
  • The commercial parallel plate electrodes system with guard-ring electrode have been widely used for measurement of dielectric constants of solid materials. And the specification of the electrodes system is about 1 % of measurement uncertainty. This measurement uncertainty is only estimated the error come from mechanical measurements such as the area of the electrodes and the gap between the electrodes except the error come from the air gap between the electrodes and dielectric specimen. Because it is impossible to measure the air gap. This study analyze the total measurement uncertainties of the commercial dielectric constant test cell using 3 kinds of Standard Reference Materials. As a results, the total measurement uncertainty is much bigger than 1 % and the most of the uncertainty can be reduced by compensation of the error values evaluated in this study.