• 한국수소및신에너지학회논문집
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• 제25권5호
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• pp.541-549
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• 2014

The monthly-average meteorological data, in particular, the monthly average daily terrestrial horizontal insolation are required for designing solar thermal energy systems. In this paper, the dynamic thermal performance of a flat plate solar collector system is numerically investigated through a year from the monthly average insolation data in Seoul. For a specified data set of solar collector system, the dynamic behaviors of total solar radiation on the tilted collector surfaces, heat loss from the collector system, useful energy and collector efficiency are analyzed from January to December by a mathematical simulation model. In addition, the monthly average daily total solar radiation, useful energy, and daily collector efficiencies through a year are estimated. The simulated results show that the average total radiation is highest in March and the useful energy is highest in October, while the total radiation and the collector efficiency are lowest in July.

• 전기학회논문지P
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• 제59권2호
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• pp.218-221
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• 2010

This paper presents energy efficiency about an electrolyser which is related with the hybrid system of solar cell and fuel cell for using the system more fully. The water electrolyser is the exact reverse of a hydrogen fuel cell; it produces gaseous hydrogen and oxygen from water. Electrolyser technology may be implemented at a variety of scales wherever there is an electricity supply to provide hydrogen and/or oxygen for virtually any requirement. Also, this paper shows optimum operating point in the electrolyser for saving cost of the electrical energy with hybrid system.

• 한국전기전자재료학회논문지
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• 제35권4호
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• pp.366-371
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• 2022

Recently many efforts have been made to develop a novel class of non-fullerene electron acceptor materials for high-performance organic solar cells. In this work, anthraquinone derivatives, TMAQ and THAQ, were prepared and their availability as electron acceptor materials for organic solar cells were investigated in terms of optical, thermal, electrochemical properties, and solar cell devices. Compared to TMAQ, a significant bathochromic shift of absorption band was observed for THAQ owing to intramolecular hydrogen-bond-assisted CT interactions. Thanks to the fused aromatic ring structure and benzoquinone unit, both TMAQ and THAQ exhibited a high thermal stability and an efficient electron reduction process. In particular, the intramolecular O-H---O=C hydrogen bond of THAQ plays an important role in improving the thermal stability and electron reduction properties. In the P3HT:acceptor solar cell system, THAQ-based devices had more than ca. 6 times higher power conversion efficiency than TMAQ -based devices. These results serve as a guide for developing high-efficient anthraquinone-based electron acceptor materials.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.309-311
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• 2007

Supramolecules containing double hydrogen bonding sites at their both chain ends were self-polymerized to become solid state polymer and were utilized to improve the efficiency of solid state DSSCs. Hydrogen bonding sites were attached at the chain ends of PEG of Mw=2000, such as pyrimethamine and glutaric acid. The solar cell with the solid state supramolecular polymer electrolyte resulted in the overall energy conversion efficiency of 4.63 % with a short circuit current density $(J_{sc})$ of 10.41 $mAcm^{-2}$, an open circuit voltage $V_{oc}$, of 0.71 V and a fill factor (FF) of 0.62 at one sun condition ([oligomer]:[1-methyl-3-propyl imidazolium iodide (MPII)]:$[I_2]$ = 20 : 1 : 0.19, active area = 0.16 $cm^2$, $TiO_2$ layer thickness = 10 ${\mu}m$). The ionic conductivity of the sol id state electrolyte was $5.11{\times}10^{-4}$ (S/cm). The cell performance was characterized by electrochemical impedance spectroscopy and ionic conductivity.

• 마이크로전자및패키징학회지
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• 제28권1호
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• pp.13-20
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• 2021

GaN은 III-V족 화합물 반도체로 밴드갭을 조절하는 것이 가능하고 화학적으로 안정하기 때문에 다른 물질에 비해 산성, 염기성 용액에서 부식이 적다. 또한 GaN의 밴드갭이 물의 산화·환원 준위를 포함하고 있어 외부전압 없이 물 분해가 가능하다는 장점이 있다. 하지만 GaN 자체만으로는 태양광-수소 변환 효율(solar-to-hydrogen conversion efficiency, STH)이 낮아 이를 개선하기 위해 최근 활발한 연구가 이루어지고 있다. 본 총설에서는 GaN을 PEC 물분해의 광전극으로 사용하기 위한 방법들과 연구에 대해 정리하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.24-27
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• 2009

Solid-state dye-sensitized solar cells (DSSCs) have been constructed employing supramolecular electrolytes with multiple hydrogen bonding. A supramolecule was facilely synthesized by one-pot reaction between the amines of methyl isocytosine (MIC) and the epoxy groups of poly(ethylene glycol diglycidyl ether) (PEGDGE) to produce quadruple hydrogen bonding units. Hydrogen bonding interactions and dissolution behavior of salt in supramolecular electrolytes are investigated. The ionic conductivity of the supramolecular electrolytes with ionic liquid, i.e. 1-methyl-3-propylimidazolium iodide (MPII) reaches $8.5{\times}10^{-5}$ S/cm at room temperature, which is higher than that with metal salt (KI). A worm-like morphology is observed in the FE-SEM micrographs of $TiO_2$ nanoporous layer, due to the connection of $TiO_2$ nanoparticles resulting from adequate coating by electrolytes. DSSCs employing the supramolecular electrolytes with MPII and KI exhibit an energy conversion efficiency of 2.5 % and 0.5 %, respectively, at 100 $mW/cm^2$, indicating the importance of the cation of salt. Solar cell performances were further improved up to 3.7 % upon introduction of poly(ethylene glycol dimethyl ether) (PEGDME) with 500 g/mol.

• Journal of Electrochemical Science and Technology
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• 제12권3호
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• pp.302-307
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• 2021

Polymer electrolyte membrane (PEM) electrolyzer or alkaline electrolyzer is required to produce green hydrogen using renewable energy such as wind and/or solar power. PEM and alkaline electrolyzer differ in many ways, instantly basic materials, system configuration, and operation characteristics are different. Building an optimal water hydrolysis system by closely grasping the characteristics of each type of electrolyzer is of great help in building a safe hydrogen ecosystem as well as the efficiency of green hydrogen production. In this study, the basic operation characteristics of a kW class alkaline water electrolyzer we developed, and water electrolysis efficiency are described. Finally, a brief overview of the characteristics of PEM and alkaline electrolyzer for large-capacity green hydrogen production system will be outlined.

• 한국수소및신에너지학회논문집
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• 제12권4호
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• pp.239-246
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• 2001

Fossil fuel such as oil and natural gas has been used and will be no longer supplied enough to demand in the beginning of thisg century. The use of the fuel makes a lot of environmental pollution to threaten human being's health especially in big cities and produces a lot of $CO_{2}$ to make green house effect of the earth. It is the time to use clean fuel such as hydrogen to prevent the expected energy crisis and the pollution. A new engine such as fuel cell can be used instead of the conventional internal combustion engine with 2 to 3 times higher efficiency of the conventional engine. The fuel cell uses hydrogen and oxygen and produces electric energy and pure water, which is a calm engine without air pollution. In big cities the city buses and the taxies powered by hydrogen fuel cells are suggested to be operated for clean environment. The energy and cost analysis performed for hydrogen and electricity production from wind power and solar cell.

• 한국수소및신에너지학회논문집
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• 제33권1호
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• pp.113-120
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• 2022

Quantum dots (QDs) are attractive photosensitizer candidates for application not only in solar cells but also in solar hydrogen generation. For the prepartion of highly efficient QD-sensitized photoelectrodes, it is important to reduce electron recombination at the photoanode/electrolyte interface. Here, we study on the coating condition of ZnS passivation layers on the photoanodes in QD-sensitized solar cells (QDSCs). The ZnS passivation layers are coated by successive ionic layer adsorption and reaction method, and as the cation precursor, zinc acetate and zinc nitrate are empolyed. Due to the higher pH of cation precursor solution, the ZnS loading is improved when the zinc acetate is used, compared to the zinc nitrate. This improved loading of ZnS leads to the reduced electron recombination at the surface of photoanodes and the enhaced conversion efficiency of QDSCs from 6.07% to 7.45%.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.83.1-83.1
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• 2010

Hydrogenated a-SiGe middle cell for triple junction solar cell was investigated with various process parameters. a-SiGe I-layer was deposited at substrate temperature $245^{\circ}C$ and hydrogen content(R) was up to 26.7. Low optical bandgap(1.45eV) of a-SiGe cell was applied for middle cell although a-SiGe single cell efficiency with low Ge content was higher. And this cell was applied to the middle cell of a glass superstrate type a-Si/a-SiGe/uc-Si triple junction solar cell. The triple junction solar cell was resulted in the initial efficiency of about 9%, area $0.25cm^2$, under global AM 1.5 illumination.