• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.1
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• pp.16-22
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• 2023

In a solar cell, degradation refers to the decrease in performance parameters caused by defects originated due to various causes. During the fabrication process of solar cells, degradation is generally related to the processes such as passivation or firing. There exist sources of many types of degradation; however, the exact cause of Light and elevated Temperature Induced Degradation (LeTID) is yet to be determined. It is reported that the degradation and the regeneration occur due to the recombination of hydrogen and an arbitrary substance. In this paper, we report the deposition of Al₂O₃ and SiN_X on silicon wafers used in the Passivated Emitter and Rear Contact (PERC) solar structure and its degradation pattern. A higher degradation rate was observed in the sample with single layer of Al₂O₃ only, which indicates that the degradation is affected by the presence or the absence of a passivation thin film. In order to alleviate the degradation, optimization of different steps should be carried out in consideration of degradation in the solar cell fabrication process.

• Rapid Communication in Photoscience
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• v.3 no.3
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• pp.56-58
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• 2014

Single-walled carbon nanotubes (SWNTs) catalyzed hydrogen production from water containing various electron donors under visible light (${\lambda}$ > 420 nm). As-received SWNTs were effective for hydrogen production, yet the effect vanished when they underwent surface chemical treatments. Upon coupling with CdSe particles, however, the surface treated SWNTs were far superior to non-treated SWNTs by a factor of ~30 for hydrogen production.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.24-27
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• 2009

Solid-state dye-sensitized solar cells (DSSCs) have been constructed employing supramolecular electrolytes with multiple hydrogen bonding. A supramolecule was facilely synthesized by one-pot reaction between the amines of methyl isocytosine (MIC) and the epoxy groups of poly(ethylene glycol diglycidyl ether) (PEGDGE) to produce quadruple hydrogen bonding units. Hydrogen bonding interactions and dissolution behavior of salt in supramolecular electrolytes are investigated. The ionic conductivity of the supramolecular electrolytes with ionic liquid, i.e. 1-methyl-3-propylimidazolium iodide (MPII) reaches $8.5{\times}10^{-5}$ S/cm at room temperature, which is higher than that with metal salt (KI). A worm-like morphology is observed in the FE-SEM micrographs of $TiO_2$ nanoporous layer, due to the connection of $TiO_2$ nanoparticles resulting from adequate coating by electrolytes. DSSCs employing the supramolecular electrolytes with MPII and KI exhibit an energy conversion efficiency of 2.5 % and 0.5 %, respectively, at 100 $mW/cm^2$, indicating the importance of the cation of salt. Solar cell performances were further improved up to 3.7 % upon introduction of poly(ethylene glycol dimethyl ether) (PEGDME) with 500 g/mol.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.5
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• pp.501-509
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• 2016

In this study, a flat-type photocatalytic reactor is applied under solar irradiation for simultaneous treatment of target pollutants: reduction of Cr(VI) to Cr(III) and oxidation of EDCs (BPA, EE2, E2). An immobilized type of photocatalyst was fabricated to have self-grown nanotubes on its surface in order to overcome limitations of powdery photocatalyst. Moreover, Ti mesh form was chosen as substrate and modified to have both larger surface area and photocatalyst content. Ti mesh was anodized at 50V and $25^{\circ}C$ for 30min in the mixed electrolytes ($NH_4F-H_2O-C_2H_6O_2$) and annealed at $450^{\circ}C$ for 2 hours in ambient oxygen to have anatase structure. Surface characterization was done with SEM and XRD methodologies. Fabricated NTT was applied to water treatment, and coexisting Cr(VI) and organics (EDCs) enhanced each other's reactions by scavenging holes and electrons and thus impeding recombination. Also, several experiments were conducted outdoor under direct sunlight and it was observed that both solar-tracking and applying modified photocatalyst were proven to enhance reaction efficiency.

• Rapid Communication in Photoscience
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• v.4 no.4
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• pp.82-85
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• 2015

Photoelectrochemical cell (PEC) is one of the attractive ways to produce clean and renewable energy. However, solar to hydrogen production via PEC system generally requires high external bias, because of material's innate electronic band potential relative to hydrogen reduction potential and/or charge separation issue. For spontaneous photo-water splitting, here, we design dye-sensitized solar cell (DSSC) and their monolithic tandem cell incorporated with a $BiVO_4$ photoanode. $BiVO_4$ has high conduction band edge potential and suitable band gap (2.4eV) to absorb visible light. To achieve efficient $BiVO_4$ photoanode system, electron and hole mobility should be improved, and we demonstrate a tandem cell in which $BiVO_4/WO_3$ film is connected to cobalt complex based DSSC.

• Proceedings of the KIEE Conference
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• 1992.07b
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• pp.847-849
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• 1992

Fluorine-doped ($SnO_2$:F) thin films obtained by pyrosol deposition method have been exposed to R.F. excited pure hydrogen plasma under the following conditions; substrate temperature of 200$^{\circ}C$, $H_2$ pressure of 1 Torr, R.F. input power of 50 mW/$\textrm{cm}^{2}$, $H_2$ flow rate of 30cc/min and exposure time of 15-600 seconds. It is found that the sheet resistance of the films remains unchanged or rather slightly reduces for initial exposure time of 30-60 seconds, but increases sharply with further increasing the exposure time. The optical transmittance of $SnO_2$:F films slows a rapid fall with increasing exposure time except for a film obtained with a solution having $CH_3OH/H_2O$ mol ratio of 2.65, its degradations at the exposure time of 30-60 seconds are about 7-15%. In addition, the exposure of the films to hydrogen plasma atmosphere leads to remarkable changes in the microstructure and chemical composition, which should be attributed to the reduction of $SnO_2$ to SnO and to elemental Sn.

• Current Photovoltaic Research
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• v.2 no.4
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• pp.189-194
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• 2014

In this paper, We have simulated the output variation of the PV arrays installation with position & angle change. The existing 3 solar array system are $43^{\circ}$ southeast and each of the mounting angle is $17^{\circ}$. The PV output power is 240 kW. The composite studied systems in this paper arrays altered 2 PV array among 3 PV array system- the output 144kW. We simulated this system using Solar Pro ver.4.1. The simulation conditions are southwest $43^{\circ}/array$, mount angle $27^{\circ}/array$. Because the southeast have shadow effect-higher mountain The purpose of southwest $43^{\circ}$ is reduce the shadow effect. The simulation results of the suggestion design algorithm compared to 1,590 kWh/year output is increased with the southeast.

• Journal of Hydrogen and New Energy
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• v.16 no.2
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• pp.130-135
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• 2005

Cadmium selenide is one of the group IIb-VI compounds, which is the promising semiconductor material due to its wide range of technological applications in optoelectronic devices such as photoelectrochemical cells, solid state solar cells, thin film photoconductors etc. CdSe has optical band gap of 1.7-1.8eV and proper conduction band edge for water splitting. CdSe films are coated with small thickness(20-50nm) nanocrystalline $TiO_2$ film by electrodeposition or chemical bath deposition methods and PEC properties of CdSe and CdSe/$TiO_2$ sandwich structure are studied. The photoactivity of CdSe and CdSe/$TiO_2$ films deposited on titanium substrate is studied in aqueous electrolyte of 1M NaOH solution. Photocurrent and photovoltage obtained were of the order of 2-4 mA/$cm^2$ and 0.5V, respectively, under the intensity of illumination of 100 mW/$cm^2$.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.415-423
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• 2007

Photocatalytic water splitting (PWS) is the most promising technology to produce $H_2$ energy directly from renewable water and solar light. In spite of the remarkable progress made in the last decade, there are still many technical challenges remaining particularly in finding new photocatalytic materials with high efficiency and durability. This article discusses the application of nanocomposite materials in search of new photocatalytic materials for solar hydrogen production from water. It has been demonstrated that smart combination and modification of known materials and functions could be fruitful approach for the purpose.

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.1078_1079
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• 2009

본 논문에서는 태양열 온수급탕에 관한 모티너링 연구를 해석하고 이론을 바탕으로 실 시스템을 적용 운용시 시스템의 운전특성을 비교 분석하였다. 장기 적인 일사량 측정 데이터 수집을 통하여 그래프화, 모티터링 시스템에 관한 연구를 살펴보았다.