• Title/Summary/Keyword: Solar conversion efficiency

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The performance of large-area organic solar cells by spray deposition process

  • Park, Seon-Yeong;Park, Dong-Seok;Kim, Do-Geun;Kim, Jong-Guk;Kim, Ju-Hyeon;Gang, Jae-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.291-291
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    • 2010
  • Organic solar cells have attracted much interest due to the potential advantage of the lightness, simple solution processing and flexibility. Until recently, the focus of organic solar cells research has been on optimization of material processing to improve the power conversion efficiency. However, area scaling is an important position for alternative to the market dominating solar cells. Spray deposition technologies have advantage of less material wastage and possibility of large scale photoactive area coating when compared with spin coating process. We investigated the performance of organic solar cells as a function of active area using two types of deposition process. The commonly used process is spin coating which can be fabricated organic materials deposition for devices. Spray deposition process compare with spin coating for large-area organic solar cells. The spray deposition organic layer shows excellent performance up to the active area of $4\;cm^2$ with the PCE of ~3.0 % under AM.1.5 simulated illumination with an intensity of $100mW/cm^2$. This indicates that the spray deposition process can be used as a mass production process for evaluating large-area organic solar cells.

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A study of small size battery charging characteristic by serial-parallel connected DSC module (단위 DSC셀의 직병렬 연결을 통한 소형 배터리 충전특성에 관한 연구)

  • Hong, Ji-Tae;Choi, Jin-Young;Seo, Hyun-Woong;Kim, Mi-Jeong;Sim, Ji-Young;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.192-194
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    • 2006
  • To elucidate possible challenges for outdoor practical use of dye-sensitized solar cells(DSC), compared with conventional Si solar cells. DSC modules still need the larger area than conventional Si solar modules to attain the same rated output because of lower photoelectron-chemical conversion efficiency. However, using batteries backup systems, the measured data shows that DSCs gathered over 12% more electricity than Si solar cells of the same rated output power in same outdoor condition. Moreover, battery charging time of DSC is about 1 hour faster than same rate of Si solar module. In this paper, 12 single DSC cells prepared for 4 serialized DSC cells was connected in 3 row parallel which have same output power rate of Si solar module. This DSC module was practiced generating characteristic experiment over outdoor daylight condition and applied with PV battery charger by using DC-DC converter. The main advantages of DSC module battery charger as compared with conventional Si solar module one are shorter charge time and lower cost.

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Photoelectrochemical Properties of $TiO_2$ Electrodes Prepared Using Chemical Functionalized Binders

  • Song, Yongwhan;Kim, Sangki;Yang, Jaechang;Park, Junho;Kim, Myoungsoo;Gu, Halbon;Park, Kyunghee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.60.1-60.1
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    • 2010
  • Chemically functionalized plant oils such as acrylated epoxidized soybean oil (AESO) and maleinized acrylated epoxidized soybean oil (MAESO) were used as new bio-based binders for $TiO_2$ electrodes of dye-sensitized solar cells (DSSC). More porous networks and larger porosities were fabricated on the $TiO_2$ films using plant oil binders due to the larger number of functionalities, in comparison with the film using polyethylene glycol (PEG). The charge-transfer resistance in the $TiO_2$ films was considerably shrunk due to the reduced impurity states. The short circuit photocurrent (Isc) and the open circuit photovoltage (Voc) of the cell using plant oil binders increased and the conversion efficiency improved significantly.

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Aqueous Electrolytes Based Dye-sensitized Solar Cells using I-/I3- Redox Couple to Achieve ≥ 4% Power Conversion Efficiency

  • Choi, Hyeju;Han, Jinjoo;Kang, Moon-Sung;Song, Kihyung;Ko, Jaejung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1433-1439
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    • 2014
  • We report on the influence of water as an electrolyte on the photovoltaic performances. The photovoltaic performance was shown to be quite sensitive to the substituent on the donor group. An optimized efficiency of 4.41% in the presence of 100% water content using $I^-/I{_3}^-$ redox couple was obtained using the D21L6 organic dye.

Nanoarchitectures for Enhancing Light-harvesting and Charge-collecting Properties in Dye-sensitized Solar Cells

  • Jeong, Hyeon-Seok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.13.1-13.1
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    • 2011
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO) [1-5]. In this presentation, we introduce inverse opal-based scattering layers containing highly crystalline anatase nanoparticles and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength. A new ITO nanowire-based photoelecrode is also introduced and its unique charge collection property is presented, demonstrating potential use for highly efficient charge collection in DSSC.

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Nanostructured Photoelectrode Materials for Improving Light-Harvesting Properties in DSSCs

  • Jeong, Hyeon-Seok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.7.2-7.2
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    • 2011
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO). In this presentation, we introduce monodisperesed TiO2 nanoparticles prepared by forced hydrolysis method and their superiority as photoelectrode materials was characterized with aids of optical and electrochemical analysis. Inverse opal-based scattering layers containing highly crystalline anatase nanoparticles are also introduced and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength.

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Design and Fabrication of Compound Semiconductor Solar Cells Grown by MOCVD-Field Aided Heteroface Cell (MOCVD를 이용한 화합물 반도체 Solar Cell의 개발-Field Aided Heteroface 전지)

  • 창기근;엄우용;임성규
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.28A no.9
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    • pp.752-760
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    • 1991
  • The computer aided analysis is performed to investigate the influence of physical parameters (thickness and doping concentration, etc.) in the window, emitter, base on the efficiency characteristics of a uniformly doped hetroface cell. A field aided heteroface cell is newly designed on a basis of optimum data obtained from the theoretical analysis. The field aided heteroface cell fabricated using MOCVD exhibits a total/active area conversion efficiency of EFF. (tot) = 18.9% /EFF. (act.) = 21.4% under the natural incident light of 56.2 mW/cm\ulcorner having a low series resistance of Rs = 0.94 \ulcornercm\ulcornerand a high spectral response of S.R. (ext) > 90% in a range of $7700{\AA}$ < $8500{\AA}$.

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Flower like Buffer Layer to Improve Efficiency of Submicron-Thick CuIn1-xGaxSe2 Solar Cells

  • Park, Nae-Man;Cho, Dae-Hyung;Lee, Kyu-Seok
    • ETRI Journal
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    • v.37 no.6
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    • pp.1129-1134
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    • 2015
  • In this article, a study of a flower like nanostructured CdS buffer layer for improving the performance of a submicron-thick $CuIn_{1-x}Ga_xSe_2$ (CIGS) solar cell (SC) is presented. Both its synthesis and properties are discussed in detail. The surface reflectance of the device is dramatically decreased. SCs with flower like nanostructured CdS buffer layers enhance short-circuit current density, fill factor, and open-circuit voltage. These enhancements contribute to an increase in power conversion efficiency of about 55% on average compared to SCs that don't have a flower like nanostructured CdS buffer layer, despite them both having the same CIGS light absorbing layer.

A Efficient MPPT Control Algorithm for LED Street Lighting System using Photovoltaic Systems (태양광을 이용한 LED가로등 시스템을 위한 효율적인 MPPT 충전제어 알고리즘)

  • Kim, Byun-gon;Jeong, Dong-su
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2014.10a
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    • pp.675-676
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    • 2014
  • Photovoltaic (PV) systems bosed on solar energy offer an environmentally friendly source of electricity. A key feature of such PV sysem is the efficiency of conversion at which the power converter stage can extract the energy from the PV arrays and deliver to the load. The Maximum power point tracking (MPPT) of the PV output for all sunshine conditions allows reduction of the cost installation and maximizes the power output from the PV panel. The proposed algorithm is to control the width of the pulse for battery charging based on the open voltage of the PV panel. As a lab results, the proposed system was implemented functions to adapt to the changes of the PV open voltage, and improved the charging efficiency.

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Properties in Organic Photovoltaic Cell Depending on the Exciton Blocking Layer Thickness (엑시톤 억제층 두께에 따른 유기 광기전력 소자의 특성)

  • Oh, Hyun-Seok;Lee, Joon-Ung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.12
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    • pp.1148-1151
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    • 2005
  • Photovoltaic effects in organic solar cell were studied in a cell configuration of ITO/PEDOT:PSS/CuPc(20 nm)/$C_{60}$(40 nm)/BCP/Al(150 nm) at room temperature. Here, the BCP layer works as an exciton blocking layer. The exciton blocking layer must transport electrons from the acceptor layer to the metal cathode with minimal increase in the total cell series resistance and should absorb damage during cathode deposition. Therefore, a proper thickness of the exciton blocking layer is required for an optimized photovoltaic cell. Several thicknesses of BCP were made between $C_{60}$ and Al. And we obtained characteristic parameters such as short-circuit current, open-circuit voltage, and power conversion efficiency of the device under the illumination of AM 1.5.