• Bulletin of the Korean Chemical Society
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• v.27 no.2
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• pp.322-324
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• 2006

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1533-1536
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• 2013

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.2
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• pp.117-121
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• 2018

Perovskite solar cells have received increasing attention in recent years because of their outstanding power conversion efficiency (exceeding 22%). However, they typically contain toxic Pb, which is a limiting factor for industrialization. We focused on preparing Pb-free perovskite films of Ag-Bi-I trivalent compounds. Perovskite thin films with improved optical properties were obtained by applying an anti-solvent (toluene) washing technique during the spin coating of perovskites. In addition, the surface condition of the perovskite film was optimized using a multi-step thermal annealing treatment. Using the optimized process parameters, $AgBi_2I_7$ perovskite films with good absorption and improved planar surface topography (root mean square roughness decreased from 80 to 26 nm) were obtained. This study is expected to open up new possibilities for the development of high performance $AgBi_2I_7$ perovskite solar cells for applications in Pb-free energy conversion devices.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.358-359
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• 2008

Solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of $TiO_2$ nanofiber added to the $TiO_2$ paste, on surface morphology, good electric of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increased with $TiO_2$ nanofiber addition up to 7wt% in $TiO_2$ films. Maximum increase upto 15% in the efficiently was observed at 7 wt. % of $TiO_2$ nanofiber in $TiO_2$ electrode.

• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.384-388
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• 2015

We prepared blocking layers by adding 0.0 ~ 0.6 wt% nano diamond blends (DBs) to $TiO_2$ blocking layers to improve the energy conversion efficiencies (ECEs) of dye sensitized solar cells (DSSCs). TEM and micro-Raman spectroscopy were used to characterize the microstructure and phases of DBs, respectively. Optical microscopy and FE-SEM were used to analyze the microstructure of the $TiO_2$ blocking layer with DBs. UV-VIS-NIR spectroscopy was used to determine the absorbance of the working electrodes. A solar simulator and a potentiostat were used to determine the photovoltaic properties and the impedance of the DSSCs with DBs. From the results of the DBs analysis, we determined a 6.97 nm combination of nano diamonds and graphite. We confirmed that ECE increased from 5.64 to 6.48 % when the added DBs increased from 0.0 to 0.2 wt%. This indicates that the effective surface area and electron mobility increased when DBs were added to the $TiO_2$ blocking layer. Our results indicate that the ECE of DSSCs can be enhanced by adding an appropriate amount of DBs to the $TiO_2$ blocking layers.

• Applied Chemistry for Engineering
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• v.16 no.2
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• pp.159-168
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• 2005

Dye-sensitized solar cells (DSCs) have been under investigation for the past decade due to their attractive features such as high energy conversion efficiency and low production costs. The basis for energy conversion is the injection of electrons from a photoexcited state of a dye sensitizer into the conduction band of the nanocrystalline $TiO_2$ semiconductor upon absorption of light. It is believed that the DSC is one of the most promising candidates for renewable energy sources. In this review, the development trends and perspectives of DSCs are investigated.

• KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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• v.4B no.2
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• pp.86-91
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• 2004

PV power generation, which directly converts solar radiation into electricity, contains numerous significant advantages. It is inexhaustible and pollution-free, silent, contains no rotating parts, and has size-independent electricity conversion efficiency. The positive environmental effect of photovoltaics is that it replaces the more polluting methods of electricity generation or that it provides electricity where none was available before. This paper highlights a novel simple method to abstract the entire parameters of the solar cell. In development, design and operation of PV power generation systems, a technique for constructing V-I curves under different levels of solar irradiance and cell temperature conditions using basic characteristic values of the PV module is required. Everyone who has performed manual acquisition and analysis of solar cell I versus V data would agree that the job is tedious and time-consuming. A better alternative is to use an automated curve tracer to print out the I versus V curves and compute the four major parameters; $V_{oc}$, $I_{sc}$, FF, and . Generally, the V-I curve tracer indicates only the commonly used solar cell parameters. However, with the conventional V-I curve tracer it is almost impossible to abstract the more detailed parameters of the solar cell; A, $R_{s}$ and $R_{sh}$ , which satisfies the user, who aims at the analysis of the development of the PV power generation system, that being advanced simulation. In this paper, the proposed method provides us with satisfactory results to enable us to abstract the detailed parameters of the solar cell; A, $R_s$ and $R_{sh}$.>.

• Transactions on Electrical and Electronic Materials
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• v.5 no.3
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• pp.89-92
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• 2004

For improving solar efficiencies, down conversion of high-energy photons to visible lights is discussed. The losses due to thermalization of charge carriers generated by the absorption of high-energy photons, can largely be reduced in a solar cell if more than one electron-hole pair can be generated per incident photon. The solar cell was constructed of dye-sensitized anatase-based TiO$_2$, approximately 30nm particle size, 6$\mu\textrm{m}$thickness, and 6${\times}$6$\textrm{mm}^2$ active area, Pt counter electrode and I$_3$$\^$-/I$_2$$\^$-/ electrolyte. After correction for losses due to light reflection and absorption by the conducting glass, the conversion of photons to electric current is practically quantitative in the plateau region of the curves. The incident photon to current conversion efficiency(IPCE) of N3 used as a dye in this work is about 80% at around 590nm and 610nm which is the emission spectrum of Eu doped LGF. The Eu doped LGF powder was prepared by conventional ceramic process, and used as a down converter for DSC after spin coated on the slide glass and fired.

• Journal of the Microelectronics and Packaging Society
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• v.18 no.2
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• pp.57-62
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• 2011

The energy conversion efficiency of DSSCs (Dye-Sensitized Solar Cells) is dependent on the powder size, the structure, and the morphology of $TiO_2$ electrode. The higher efficiency is obtained with high surface area of the nanoanatase-$TiO_2$ powder adsorbed onto a lot more of the dye. Also, the enhancement of light scattering increases the efficiency with high adsorption of the dye. Powder size, crystalline phase, and shape of $TiO_2$ obtained by hydrothermal method have 15-20 nm, anatase and round. $TiO_2$ electrode has fabricated with the mixture of scattering $TiO_2$ particle with 0.4 ${\mu}m$ in nano-sized powder. Conversion efficiency of series of DSSCs was measured with volume fraction of scattering particle. Photovoltaic characteristics of DSSCs with 10% scattering particles are 3.51 mA for Jsc (short circuit current), 0.79 V for Voc(open circuit potential), filling factor 0.619 and 6.86% for efficiency. Jsc was improved by 11% and enhancement of efficiency by 0.77% compared with that of no scattering particles. The confinement of inserted light by light scattering particles has more increase of the injection of exiton(electron-hole pair) and decrease of moving path in electron. Efficiencies of DSSCs with more than 10% for scattering particles have reduced with increasing the pore in the $TiO_2$ electrode.

• Advances in Energy Research
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• v.5 no.1
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• pp.31-55
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• 2017

In the present study, PV/T collector was modeled via analysis of governing equations and physics of the problem. Specifications of solar radiation were computed based on geographical characteristics of the location and the corresponding time. Temperature of the collector plate was calculated as a function of time using the energy equations and temperature behavior of the photovoltaic cell was incorporated in the model with the aid of curve fitting. Subsequently, operational range for reaching to maximal efficiency was studied using Genetic Algorithm (GA) technique. Optimization was performed by defining an objective function based on equivalent value of electrical and thermal energies. Optimal values for equipment components were determined. The optimal value of water flow rate was approximately 1 gallon per minute (gpm). The collector angle was around 50 degrees, respectively. By selecting the optimal values of parameters, efficiency of photovoltaic collector was improved about 17% at initial moments of collector operation. Efficiency increase was around 5% at steady condition. It was demonstrated that utilization of photovoltaic collector can improve efficiency of solar energy-based systems.