• Title/Summary/Keyword: Soil-contaminated sites

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Uptake and Accumulation of Arsenate on Lettuce (Lactuca sativa L.) Grown in Soils Mixed with Various Rates of Arsenopyrite Gravel (유비철석 입자 혼합 토양내 상추(Lactuca sativa L.)의 비소이온 흡수와 축적)

  • Shim, Ho-Young;Lee, Kyo-Suk;Lee, Dong-Sung;Jeon, Dae-Sung;Shin, Ji-Su;Kim, Soo-Bin;Cho, Jin-Woong;Chung, Doug-Young
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.59 no.4
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    • pp.532-538
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    • 2014
  • Arsenic (As) is nonessential element toxic to plants. In Korea little is not only known about the extent of actual anthropogenic sources and inputs of arsenic to the agricultural land which plays a active role as a sink, but also systematic research on arsenic as an toxic element entering the food chain via the soil-plant pathway has not been investigated in the fields and greenhouses besides in few places of abandoned mining sites. Therefore, it is important to focus on the effect of As-contaminated soils on As uptake and biomass production of lettuce plants. In this study, As concentrations in the soil and accumulation of As in lettuce transferred by As uptake from soils were investigated. To do this, soil which was mixed with various rates of arsenopyrite gravels containing arsenic from 0 to 100% was packed into a round plastic pot. Then, 10 days old vegetable crops of chinese cabbage and lettuce after germination were transplanted into a pot. Growth of lettuce was observed for four weeks with one week interval. All experiments were done by triplicate. The results showed that the growth rates for number of leaves, width and length of the crop plants were retarded with increasing amount of gravel mixed due to increasing bioavailable amount of arsenate with increasing rate of gravel in soils. With these results, we conclude that the bioavailable amount of arsenate can influence the growth of lettuce.

Characteristics of Heavy Metal Pollution in Contaminated Roadside Sediments in Jeonju City, Korea (전주시 도로변 퇴적물의 중금속 오염 특성)

  • Cho, Ktu-Seong
    • Journal of the Korean earth science society
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    • v.24 no.8
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    • pp.711-720
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    • 2003
  • To study characteristics of the heavy metal pollution, sediment samples were collected at 67 sites on the roadside of Jeonju city during summer and winter, 2002. The total concentration of metals including Cd, Co, Cr, Cu, Ni, Pb, Zn, and Mn in the sediment samples were determined. The results indicate that the roadside sediments in Jeonju city have lower (1/2 to 1/7 times) concentrations of Zn, Cu, Pb and Cd than the metal concentrations previously reported for roadside soil, dust and sewage sludges in Seoul. However, the metal concentrations are higher than environmental quality criteria in soil suggested from several countries, and Zn, Cu, Pb and Cd contents are usually 2-7 times higher than the world average contents of the metals in natural soil. Although pollution index and concentrations of Cr, Ni, Pb and Zn in the roadside sediments at industrial area were usually higher than those of downtown and residential area, the metal having small vehicle- and steel-related industries had high concentrations of metals. The results of chemical partitioning analysis showed that Pb, Zn and Mn are mainly associated with carbonate/adsorbed and Fe-Mn oxide phases but that Cu is largely associated with the organic and sulfide fractions. It thus indicates that both large and small (vehicle- and steel-related) industries are main sources of heavy metal contamination. Due to high solubility of the carbonate phases by natural leaching episodes, the carbonate/adsorbed Cd, Co, Ni, Pb, Zn and Mn in the roadside sediments may serve as a potential source of contamination.

A Case Study on the Creating Artificial Planting Ground on the Waste Landfill Sites -In Case of the Bank Isolated Section Planting Layer at the Landfills of Satellite Cities of Seoul- (폐기물매립지 인공식재지반 조성 사례연구 -수도권매립지 제방이격구간 식재층을 대상으로-)

  • 조주형;이재근
    • Journal of the Korean Institute of Landscape Architecture
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    • v.29 no.1
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    • pp.131-139
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    • 2001
  • This paper aims at surveying through case studies the planting possibility on the interval artificial ground between the bank and the core landfill of the first section of works in the SUDOKWON Landfill area landfill area which was completed, followed by the layer-on-layer landfill process involving the latch or sealing layer against emitting landfill gas from the reclaimed waste. The survey results are as follows; 1. The layers of the artificial planting ground on the landfill were established on the basis of top-on-top procedure for a waste layer, a topping soil layer (T=50cm), a gas blocking layer (broken stones T=30cm), a filter layer (non-woven fabric 700g), a sheet protecting soil layer (T=20cm), and a blocking layer (HDPE SHEET 2.0mm), an irrigation layer (SAND T=30cm), a filter layer (non-woven fabric 700g), a sheet protecting soil layer (T=20cm), and a blocking layer (HDPE SHEET 2.0mm), an irrigation layer (SAND T=30cm), a filter layer (non-woven fabric 700g), a planting layer (T=90cm+), a top mound (T=2m). 2. Since no direct damage on the planting layer affected by the landfill gas was detected, planting is found to be still possible and successful except the severely unequal subsidence portion. 3. The mortality rate is discovered different on different trees: Pinus thunbergii (H3.0$\times$W1.0m) 11.25%, Pinus thunbergii (H2.5$\times$W0.8m) 4.73%, Koelreuteira paniculata 8.67%, Hibiscus syriacus 5.68%, Deutzia parviflora 6.50%, Forsythia koreana 8.17%, Rho. yedoense v. poukhanese 32.22%, and Spiraea pru v. symplicifolia 18.89%; although the last two of which are generally considered to have a strong generic growing character, they are subject to be weakened when exposed to the contaminated microclimate of the site like landfill gas. 4. The damage rates, on Pinus thunbergii, Koelreuteria paniculata, Hibiscus syracus, Forsythia koreana, Deutzia parviflora, Rho. yedoense v. poukhanense were shown to decrease to 7.31-17.69% in the second check (June 2000) lower than 5.77-46.92% in the first examination (June 1999), whereas the damage on Spiraea pru v. symplicifolia relatively increased. It is believed that preparatory method of the air pollution, change of temperature, odor by emitting landfill gas, and minute dust from vehicles should be made, and a research on this matter will be conducted in the near future.

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Application of the Recombinant Bioluminescence Bacterium on the Toxicity Assessment of the Sole Chemicals and Soil Samples (유전자 재조합 생물 발광 균주를 이용한 순수 오염물과 토양시료의 독성도 평가)

  • Kong, In-Chul;Kim, Jin-Yeong;Lee, Sun-Hee;Ko, Kyung-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.2
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    • pp.136-142
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    • 2012
  • Various factors affecting on the bioassay were investigated. Experiments with a low mixture ratio (cell to toxicant solution) of 0.5 : 9.5 (v/v) produced observable bioluminescence intensity for assay. Both sodium lactate and potassium nitrate stimulate bioluminescence activity; 2.6~4.0 times of control. Distilled water and MSM, which gave non significant effects on the bioluminescence activity, were determined as proper diluent or extract solutions. A wide range of toxic responses of metals and organics were observed. In general, organics were much less sensitive than metals. Samples collected from eleven sites showed the bioluminescence activity ranging from 29 to 111% of the control. Significant correlation between toxicity and total metal contents was not observed, but the toxicity of two groups, sorted based on the contaminated arsenic concentration in soils, was 44% and 20%, showing considerable differences.

Estimation of Nitrate Sources in Cheju Island Groundwater using $\delta$$^{15}$ N ($\delta$$^{15}$ N을 이용한 제주도 지하수 중의 질산염 오염원 조사)

  • 송영철;고용구;유장걸
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.3
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    • pp.107-110
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    • 1999
  • 18 boreholes with nitrate contaminated were selected. Samples were collected 4 times between both 1995 and 1996. Stable nitrogen isotope ratio for them all was measured and the contribution to contamination from several sources like fertilizer, sewage, cropland. and landfill was analysed. Nitrogen source for 11 sampling sites of T-3, L-1. O-1∼O-4, F-2∼F-5, and G-2 considered to come from chemical fertilizer and its contribution was around 60% or more. T-4. T-5 were located downward the downtown, which were influenced bydomestic sewage and its contribution were 70.7% and 54.7%. Nitrate concentration of G-2 was 17.7 mg/L, among which 60.7% was estimated to come from landfill leachate. T-1 and T-2 were located in the small village, in which 42.2 and 43.4% of nitrogen was to come from domestic sewage but 52.8% and 56.0% were from fertilizer sprayed in the cropland. L-2 was near livestock by which it was estimated to be influenced, in which 59.9% of nitrogen was from cropland. F-1 was in the cropland, by which 50.0% was influenced and 49.5% was estimated from organic matter of animals.

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Improving Strontium Isotope Ratio Analysis Using MC-ICP-MS (다검출기 유도결합 플라즈마 질량분석기를 이용한 스트론튬 동위원소비 분석법 개선)

  • Lee, Sin-Woo;Park, Jaeseon;Park, Hyun-Woo;Hwang, Jong Yeon;Kim, Kumhee;Chung, Hyun-Mi;Choi, Jong-Woo
    • Journal of Environmental Analysis, Health and Toxicology
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    • v.21 no.4
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    • pp.237-242
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    • 2018
  • Strontium (Sr) commonly exists in rock, groundwater, soil, plants, and animals. The Sr isotope ratio offers important information as a tracer on nature because the Sr isotopic composition is not fractionated by any biological process in these ecosystems. Hence, Sr isotope ratio has been used in several studies on tracing the Sr source for contaminated sites and human migration. In this study, we developed a separation method for Sr content, and then improved Sr isotope analysis using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). A powdered rock standard (NIST 2710a) was used to determine the removal of interference elements (Rb and Ca) and the recovery rate of Sr content. The results ranged from 98% to 106%. Additionally, three standard samples (NBS 987, IAPSO and NIST 1486) were analyzed to evaluate the precision and accuracy of the results. The measured $^{87}Sr/^{86}Sr$ ratio for all the samples were consistent with the reported values, within an error. These results indicate that our established Sr separation and Sr isotope measurement methods are reliable and can hence be useful in the fields of environmental and forensic sciences.

Economical Feasibility of the Treatment Methods of the Dredged Sediments from Contaminated Agricultural Reservoirs (농업용 저수지 준설토의 처리 공법에 따른 경제성 분석)

  • Oh, Kyoung-Hee;Cho, Young-Cheol
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.756-762
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    • 2013
  • The economical feasibility was conducted to find the adequate method to treat the dredged sediments from agricultural reservoirs in a pilot project that had been operated to improve the quality of water and benthic environments by dredging of contaminated sediments. For benefit/cost (B/C) analysis, the net expenses were considered as the costs of project, and the benefits were calculated from the saving of waste-treatment cost through reuse of dredged sediment, the saving of construction cost of settling pond, and the values of retained water by dredging. Although the economic feasibility depended on the sites of operation, the average B/C value of the pilot project was estimated as 1.32, indicating this project is economically feasible. Depending on the treatment methods, the B/C values were in the order of the methods of coagulating sedimentation, machinery dewatering, stabilization through exothermic reaction, and soil improvement and stabilization. The machinery dewatering method is estimated as the most adequate one to treat the dredged sediments because of the minimum riskiness of secondary pollution, the recyclability, and its economic feasibility.

The Extended Site Assessment Procedure Based on Knowledge of Biodegradability to Evaluate the Applicability of Intrinsic Remediation (자연내재복원기술(Intrinsic Remediation)적용을 위한 오염지역 평가과정 개발)

  • ;Robert M. Cowan
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.3-21
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    • 1997
  • The remediation of contamiated sites using currently available remediation technologies requires long term treatment and huge costs, and it is uncertain to achieve the remediation goal to drop contamination level to either back-ground or health-based standards by using such technologies. Intrinsic remediation technology is the remediation technology that relies on the mechanisms of natural attenuation for the containment and elimination of contaminants in subsurface environments. Initial costs for the intrinsic remediation may be higher than conventional treatment technologies because the most comprehensive site assessment for intrinsic remediation is required. Total remediation cost, however may be the lowest among the presently employed technologies. The applicability of intrinsic remediation in the contaminated sites should be theroughly investigated to achieve the remedial goal of the technology. This paper provides the frame of the extended site assessment procedure based on knowledge of biodegradability to evaluate the applicability of intrinsic remediation. This site assessment procedure is composed of 5 steps such as preliminary site screening, assessment of the current knowledge of biodegradability, selecting the appropriate approach, analyzing the contaminant fate and transport and planning the monitoring schedule. In the step 1, followings are to be decided 1) whether to go on the the detailed assessment or not based on the rules of thumb concerning the biodegradability of organic compounds, 2) which protocol document is selected to follow for detailed site assessment according to the site characteristics, contaminants and the relative distance between the contamination and potential receptors. In the step 2, the database for biodegradability are searched and evaluated. In the step 3, the appropriate biodegradability pathways for the contaminated site is selected. In the step 4, the fate and transport of the contaminants at the site are analyzed through modeling. In the step 5, the monitoring schedule is planned according to the result of the modeling. Through this procedure, users may able to have the rational and systematic informations for the application of intrinsic remediation. Also the collected data and informations can be used as the basic to re-select the other remediation technology if it reaches a conclusion not to applicate intrinsic remediation technology at the site from the site assessment procedure.

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Assessment of Groundwater Contamination Using Geographic Information System (지리정보시스템을 이용한 지하수 오염 평가)

  • 전효택;안홍일
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.3
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    • pp.129-140
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    • 1998
  • In this study two sites were selected to investigate groundwater contamination and spatial relationship between pollution level and its source. One is the Asan area, agricultural district where pollution sources are scattered. The other is the Gurogu area of Seoul city, industrial district where industrial complex and residential areas are located. Groundwater samples collected from these districts were analysis for chemical constituents. The attribute value files of the chemical constituents of groundwater and the spatial layers have been constructed and the pollution properties have been investigated to find out spatial relationships between the groundwater constituents and pollution sources using CIS. Relatively high contents of Si and HCO$_3$ in groundwater from the Asan area reflect the effect of water-rock interaction, whereas high contents of Cl, NO$_3$, SO$_4$and Ca in groundwater from the Gurogu area are due to the pollution of various sources. Pollution over the critical level of Korean Dinking Water Standard has been investigated from 15 sampling sites out of 40 in the Asan area, and 33 sampling sites out of 51 in the Gurogu area. There is pollution of NO$_3$, Cl, Fe, Mn, SO$_4$and Zn in groundwater from the Gurogu area, and that of NO$_3$, SO$_4$and Zn in groundwater from the Asan area. Principal pollution in both areas is NO$_3$contamination. Deep groundwater from the Asan area is not contaminated with NO$_3$except for one site and most of shallow groundwater near the potential point sources such as factory and stock farm is contaminated seriously. Groundwater from the Gurogu area has been already polluted seriously considering the fact of contamination of deep groundwater. This study reports a spatial relationship between the pollution level and pollution source using GIS.

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Case Study of Remidation and Investigation of Closed Unsanitary Landfill for Prevention of Leachate (비위생매립지 정밀조사 및 침출수 방지를 위한 정비방안 연구)

  • Kim, Sangkeun;Lee, Yongsoo
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.1
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    • pp.5-13
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    • 2012
  • For the last decade the amount of waste has rapidly been increased in South Korea and many waste landfills have been built according to government guidelines specifying required systems such as landfill liner, leachate collecting facilities, final cover system, etc. This effort has led the recently constructed landfills to be under well managed sanitary condition. In a meanwhile closed waste-landfill sites in the past before the adoption of the government guidelines exits under unsanitary condition. In these cases untreated leachate flew out to the surroundings due to the absence of liner and leachate collecting facilities and caused groundwater and soils to be contaminated. Waste generated odor and gas also brought civil complaints. Because environmental influences bring serious problems nearby sites, it is required to have unsanitary waste-landfills to be appropriately treated and managed. A study to evaluate environmental influence and contamination level of surroundings nearby and on the unsanitary landfills is necessary before the establishment of "Management guide of closed landfill site." This paper presents an environmental evaluation for the closed site, Doil-dong landfill, according to "Closed landfill management regulation" by Ministry of Environment. "D" landfill, located in Pyeongtaek city, has possobility to contaminate surrounding surfacewater and groundwater by leakage of leachate. The in-situ stabilization carried out to build the DMW(deep soil mixing cutoff wall) wall and drainage systems.