• Title/Summary/Keyword: Soil reaction

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Phenanthrene으로 오염된 Kaolinite에 Electrokinetic-Fenton 기법 적용시 묽은 산의 주입에 따른 효과

  • 김정환;김기년;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.318-321
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    • 2003
  • This study explored the feasibility of applying Electrokinetic-Fenton process(EK-Fenton process) to remediation of contaminant sorbed on the soil possessed low-permeability. The addition of 0.01 N H$_2$SO$_4$ in the anode reservoir for the $H_2O$$_2$stabilization improved the stabilization of $H_2O$$_2$and the treatment effect of phenanthrene across the entire soil specimen. The use of $H_2O$$_2$and dilute acid as anode purging solution is a promising method treating of HOCs in low-permeability subsurface environments.

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Modeling of the Formation of Long Grooves in the Seabed by Grounded Ice Keels

  • Marchenko, Aleksey
    • Journal of Ship and Ocean Technology
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    • v.7 no.4
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    • pp.1-15
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    • 2003
  • The motion of passively floating body, whose keel can have a contact with seabed soil, is under the consideration. The body simulates ice ridge floating in shallow water. The force of seabed soil reaction applied to the grounded keel is estimated taking into account soil embankment near the grounded keel. Two-dimensional trajectories of body motion, the shape of the grooves in seabed and the height of soil embankment are calculated when the motion of the body is caused by semidiurnal $M_2$ tide. The influence of wave amplitude and bottom slope on the shapes of body trajectory and the grooves are analyzed.

Proposed dynamic p-y curves on a single pile considering shear wave velocity of soil

  • Song, Sumin;Lim, Hyunsung;Park, Seongyong;Jeong, Sangseom
    • Earthquakes and Structures
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    • v.23 no.4
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    • pp.353-361
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    • 2022
  • The dynamic behavior of a single pile was investigated by using analytical and numerical studies. The focus of this study was to develop the dynamic p-y curve of a pile for pseudo-static analysis considering the shear wave velocity of the soil by using three-dimensional numerical analyses. Numerical analyses were conducted for a single pile in dry sand under changing conditions such as the shear wave velocity of the soil and the acceleration amplitudes. The proposed dynamic p-y curve is a shape of hyperbolic function that was developed to take into account the influence of the shear wave velocity of soil. The applicability of pseudo-static analysis using the proposed dynamic p-y curve shows good agreement with the general trends observed by dynamic analysis. Therefore, the proposed dynamic p-y curve represents practical improvements for the seismic design of piles.

Effects of Organic Acids on Availability of Phosphate and Growth of Corn in Phosphate and Salts Accumulated Soil

  • Kim, Myung-Sook;Park, Seong-Jin;Lee, Chang-Hoon;Yun, Sun-Gang;Ko, Byong-Gu;Yang, Jae E.
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.3
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    • pp.265-270
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    • 2016
  • Accumulated Phosphate can be released by ligand exchange reaction of organic acids. The objective of this study was to evaluate effects of the organic acids on the availability of phosphate and the growth of crop in phosphate and salts accumulated soil. Soil samples were collected from farmer's plastic film house. Available phosphate and electrical conductivity of soil were $3,005mg\;kg^{-1}$ and $16.63mg\;kg^{-1}$ which were 6 and 8 times higher than the optimum range of soil for crop growth, respectively. Corns were cultivated in pots for 2 months. Treatments were no treatment (control), phosphate fertilizer (P), citric acid (CA) 1, 5, 10 mM, and oxalic acid (OA) 1, 5, 10 mM. Water soluble phosphorus, available phosphate, corn growth and uptake were determined after cultivation. Results showed that organic acids increased water soluble phosphorus and available phosphate. For the level of 10 mM, the order of effectiveness of organic acids for water soluble P was citric acid (44%) > oxalic acid (32%). Height and dry weight of corns were increased significantly by the treatment of citric acid 1 and 5 mM. Also, corn absorbed more phosphorus, nitrogen, potassium, calcium and magnesium in the treatment of citric acid 1 mM than these of other treatments. Even though phosphate availability of soil was enhanced by addition of citric acid 10 mM, the growth of corns decreased because high concentration of citric acid caused salt damage by increasement of electrical conductivity. Thus, the citric acid of 1 mM has the potential to improve the availability of phosphate and the healthy growth of corns.

Studies on the Venom Inhibtor (Part Ⅵ) Reaction of the sample in vivo

  • 서정훈
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 1978.10a
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    • pp.209.4-209
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    • 1978
  • Previously, we reported the inhibitory substane which reacts on venoms proteinases and haemorrha-ghagic factors. The active substsnce was originated from soil fungi. This report describes the results of molecular weight determination, the activity by the derivatives, and also the reaction in vivo by the administration of sample L175-68-B.

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Influence of LNAPL and Soil Water on Migration of Gaseous Ozone in Unsaturated Soils (불포화 토양내에서 가스상 오존 이동특성에 대한 LNAPL과 토양수분의 영향)

  • Jung, Hae-Ryong;Choi, Hee-Chul
    • Journal of Soil and Groundwater Environment
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    • v.10 no.6
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    • pp.63-67
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    • 2005
  • Laboratory scale experiments were carried out to delineate the effects of liquid phases, such as soil water and light nonaqeous phase liquid (LNAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevents direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity and decreased air-water interface area. Diesel fuel as LNAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. Ozone breakthrough time was retarded with increased diesel concentration, however, because of high reactivity of diesel fuel with ozone. In unsaturated soil containing two liquids of soil water and LNAPL, the transport of ozone was mainly influenced by nonwetting fluid, diesel fuel in this study.

Bacillus sp. YH-001에 의한 DL-Phenylglycine으로부터 Benzoylformic acid 의 생산

  • 박윤희;이일석;방원기
    • Microbiology and Biotechnology Letters
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    • v.25 no.5
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    • pp.506-511
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    • 1997
  • For the production of benzoylformic acid from DL-phenylglycine, 8 strains of bacteria capable of producing benzoylformic acid were isolated from soil. Among them, the strain YH-001 showed the highest activity for production of benzoylformic acid, and was partially identified as a Bacillus sp. For the production of benzoylformic acid, a reaction mixture and reaction conditions were optimized as follows: the reaction mixture contained 2 g of DL-phenylglycine and 50 g of wet cells in 1 l of 50 mM potassium phosphate buffer (pH 8.0) and the reaction was carried out at 40$circ$C with shaking. After 6 hr incubation, 1.01 g/l of benzoylformic acid was produced which coffesponded to a conversion yield of 50.5%.

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펜톤산화법에 의한 PAH오염토양의 생물분해성증진에 관한 연구

  • 이병대;이창수;이진식
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.26-29
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    • 2002
  • We describe a modified method for effectively pretreating soil highly contaminated with ANT or BaA (both initial Conc. are 500 mg/kg soil), i.e., we apply Fenton oxidation in which ethanol is added to increase ANT and BaA removal. At least 0.5 $m\ell$ or 0.75 $m\ell$ of ethanol were added to 1 g of artificially ANT or BaA-contaminated soils (i.e., alluvial and sandy soil), respectively. This was followed by Feton oxidation in which various amounts of $H_2O$$_2$ and Fe$^{2+}$ were added. The results showed more than 98 % of ANT or BaA removal efficiency However less than 10 % of ANT and BaA removal efficiency was obtained in addition of distilled water or sodium dodecy1 sulfate. Additionally, we employ GC-MS to identify the main oxidation product generated by the optimized Fenton reaction [i.e., ANT or BaA degraded in to 69-73% 9,10-anthracenedione (ANTDI) or 43-51% 7,12-benz(a)anthracenedione (BaADI), respectively]. The biodegradability of ANTDI or BaADI are subsequently confirmed to be much more rapid than that of ANT or BaA, respectively, results suggesting that Fenton oxidation with ethanol-microbial treatment can be effectively applied to remove ANT or BaA from soil.l.

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Influence of Sterilization Methods on Atrazine Assimilation (멸균법이 atrazine의 분해과정에 미치는 영향)

  • 정규혁;오승민
    • Journal of Environmental Health Sciences
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    • v.23 no.1
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    • pp.1-7
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    • 1997
  • We investigated the influence of various known sterilization methods on atrazine assimilation. The present study was designed to investigate the effect of autoclaving, sodium azide and mercuric chloride treatment on the assimilation of atrazine in soil and sediment. The sterilization reactor treated with sodium azide resulted in $^{14}CO_2$ generation and atrazine was rapidly disappeared from reactor through chemical reaction with sodium azide. These findings seem to indicate that sodium azide sterilization is not recommended for atrazine studies. In sample reactors autoclaved or treated with mercuric chloride, $^{14}CO_2$ generation was not detected and most of the disappeared atrazine was found to exist as hydroxyatrazine. These results suggested that autoclaving or mercuric chloride treatment could be effective sterilization methods. However, chemical properties(pH and redox potential) of soil and sediment were altered by any of the sterilization methods applied. So it was suspected that these altered properties could affect distribution and mineralization of atrazine in soil and sediment. In addition, both autoclaving and mercuric chloride treatment have altered $K_d$ values of hydroxyatrazine more significantly than those of atrazine. Consequently, although autoclaving and mercuric chloride treatment are effective sterilization methods, one must be careful in using them in practice as these methods may cause chemical degradation of both of atrazine and its metabolites and changes in chemical properties of soil and sediment. In conclusion, careful assessment of sterilization methods must be made for the degradation studies of chemicals in soil and sediment in order to minimize possible undesirable chemical degradation of sample and/or changes in physico-chemical properties of soil and sediment by the selected sterilization methods.

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The Behavior of Earth Retaining Structures Using p-y Curve with Coupling (p-y 특성곡선의 Coupling을 고려한 토류벽의 거동해석)

  • Kim, Soo Il;Jeong, Sang Seom;Chang, Buhm Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.553-563
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    • 1994
  • The behavior of earth retaining structure was investigated by considering coupling between soil springs in elasto-plastic soil. For the computation of soil reaction, soil on both sides of walls was simplified as e1asto-plastic springs, and the required horizontal displacement to mobilize Terzaghi's active and passive state was applied to construct the p-y curve. Reliability on computer program developed is verified through the comparison between prediction and in-situ measurements. Based on the results obtained, it is found that the prediction by using coupling between soil springs simulates well the general trend observed by the in-situ measurements. It is also found that the horizontal displacement required for the active state gives a very small effect to the displacement of walls in the sandy soil.

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