• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
• /
• pp.33-36
• /
• 2006

The reductive dechlorination of chlorinated organic compounds by soil minerals in soil and groundwater were carried out in this study. FeS, green rust, and magnetite were chosen as the representative soil minerals which were capable of degrading chlorinated compound in soil system. FeS was the most effective reductant in degradation of carbon tetrachloride. The reductive degradation of CT and 1,1,1-TCA by FeS was much faster than that of 1,2-DCB and 2,4-DCP. The reactivity of FeS was effectively improved by the addition of trace metals. The addition of Co to FeS suspension enhanced the reaction rate of 1,2-DCB by a factor of 46 compared to that by FeS without Co.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
• /
• pp.37-40
• /
• 2006

The batch tests were performed to determine the ratio of hydrogen peroxide on diesel contaminated soil. The objective of test was to determine and optimize the hydrogen peroxide requirements for the remediation of a soil contaminated with diesel fuel. The batch test were done on 5g diesel contaminated soil containing hydrogen peroxide (34.5%). Initial diesel concentration were 2,000mg/kg, 5,000mg/kg, and 10,000mg/kg. The $Diesel(g):H_2O_2(g)$ ratio varied 1:1, 1:10, 1:50, 1:100, with contact reaction time 120 min. Results the batch test, effective ratio of $Diesel(g):H_2O_2(g)$ is 1:100.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
• /
• pp.393-396
• /
• 2003

Soil contains the several kinds of metal oxides. Magnetite in soil may contribute the generation of secondary waste during the decontamination of soil by citric acid. Dissolution of magnetite powders by citric acid was investigated in the pH range between 2.0 and 5.0. The dissolution behaviour of magnetite was well described by the equation, A[1 - $e^{-B(x-c)}$]. The parameters of the equation were optimized by the iteration method, and the physical meaning of each parameter was explained. Concentration of each of the dissociated chemical species of citric acid was calculated using the ionization constants. The dissolution reaction was explained by the concentration of the dissociated chemical species of citric acid.d.

• Steel and Composite Structures
• /
• 제13권2호
• /
• pp.109-122
• /
• 2012

An efficient and accurate algorithm is proposed to evaluate the reliability of cable-stayed bridges accounting for soil-pile interaction. The proposed algorithm integrates the finite-element method and the response surface method. The finite-element method is used to model the cable-stayed bridge including soil-pile interaction. The reliability index is evaluated based on the response surface method. Uncertainties in the superstructure, the substructure and load parameters are incorporated in the proposed algorithm. A long span steel cable-stayed bridge with a main span length of 1088 m built in China is considered as an illustrative example. The reliability of the bridge is evaluated for the strength and serviceability performance functions. Results of the study show that when strength limit states for both girder and tower are considered, soil-pile interaction has significant effects on the reliability of steel cable-stayed bridges. Further, a detailed sensitivity study shows that the modulus of subgrade reaction is the most important soil-pile interaction-related parameter influencing the reliability of steel cable-stayed bridges.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제20권7호
• /
• pp.103-111
• /
• 2015

Soil washing with ethylenediaminetetraacetic acid (EDTA) is highly effective in the remediation of soils contaminated with heavy metals. The EDTA recycling process is a requisite for reducing the operating cost. The applicability of Na₂S addition on the precipitation of heavy metals from the spent soil washing solution and thereby recycling of EDTA was investigated. Addition of Na₂S into the single metal-EDTA and the mixed metal-EDTA solutions ([Na₂S]/[metal-EDTA] ratio = 30, reaction time = 30 min and pH = 7~9) was highly effective in the separation of Cu and Pb from metal-EDTA complexes, but not for Ni. The Zn removal efficiency varied with pH and slightly increased upto 40% as the reaction time increased from 0 to 240 min which was longer than those for Cu and Pb. Ca(OH)₂ was subsequently added to induce further precipitation of Zn and Ni and to reduce the Na₂S dose. At the [Na₂S]/[metal-EDTA] ratio of 10, the removal efficiencies of all heavy metals excluding Ni were above 98% with the dose of Ca(OH)₂ at 0.002, 0.006 and 0.008 g into 100 mL of Cu-, Pb- and Zn-EDTA solutions, respectively. However, Ca(OH)₂ addition was not effective for Ni-EDTA solution. A further research is needed to improve metal removal efficiency and subsequent EDTA recycling for the real application in field-contaminated soils.

• 아시안잔디학회지
• /
• 제5권1호
• /
• pp.47-53
• /
• 1991

A laboratory experiment was conducted in order to learn the effect of a number of organic matters on the ammonification and nitrification of urea, and the reaction of soil, applied to a loamy upland soil poor in orgnic matter(<1.5%, without plants 1.The ammonification of urea was most pronounced in one week period immediatly after fertilizer and water treated, after which a rapid decrease of it was followed showing no accumulation at the end of 3rd week. Owing to the accumlation of ammonium, pHs of treated soils were read 7.0 to 7.3 from 6.8~6.9. 2.Nitrification was also progressed rapidly in the first one week period so that the accumulation of NO$_3$-N surpassed that of ammonia during this period. After the 1st week the accumulation of N0$_3$-N was continuously increased showing the maximum at the end of 4 weeks following a sharp decrease at the end of 5th weeks. The accumulation of NO$_3$-N dropped soil pH from 6.8-7.0 to 6. 0-6.2,but the decrease of NO-N at the end of 5th weeks brought up soil pH to 6.4-6.6. again. 3.Amino acid fermentation byproduct rich in salt, paticularly chloride, slowed down the ammonification and nitrification of urea. 4.The application of organic matter diminished the acidifying effect of chemical fertilizers. The diminishing effect of soluble humic acid and amion acid fermentation byproduct showed greater than that of solid organic matter in this experiment, which might be own to the application of a rather small amount of water soluble organic matters. Rice straw powder among solid organic matters appeared to be the least in the diminishing effect above. It may be reasoned that these soluble organic matters decomposes rapidly so as to affect Soil pH, but solid organic matters, particularly the rice straw powder, form acidic humus.

• 한국물환경학회지
• /
• 제22권4호
• /
• pp.590-598
• /
• 2006

In-situ Air sparging (IAS) is a groundwater remediation technique, in which organic contaminants volatilize into air form the saturated to vadose zone. This study was carried out to evaluate the effect of sludge and soil microbial community structure on air sparging of Total Petroleum Hydrocarbons (TPH) contaminated groundwater soils. In the laboratory, diesel (10,000 mg TPH/kg) contaminated saturated soil. The Air was injected in intermittent (Q=1500 mL/min, 10 minute injection and 10 minute idle) modes. For Terminal-Restriction Fragment Length Polymorphism (T-RFLP) analysis of eubacterial communities in sludge of wastewater treatment plants and soil of experiment site, the 16S rDNA was amplified by Polymerase Chain Reaction (PCR) from the sludge and the soil. The obtained 16S rDNA fragments were digested with Msp I and separated by electrophoresis gel. We found various sequence types for experiment with sludge soil samples that were closely related to Agrococcus, Flavobacterium, Thermoanaerobacter, Flexibacter and Shewanella, etc, in the clone library. The results of the present study suggests that T-RFLP method may be applied as a useful tool for the monitoring in the TPH contaminated soil the fate of microorganisms in natural microbial community.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제15권1호
• /
• pp.29-38
• /
• 2010

Batch tests were carried out to examine the influence of the presence of soil and Fe(II) sorption capacity of soil on the ferrous catalyzed sodium persulfate oxidation for the destruction of organic pollutants in the application of in-situ chemical oxidation. Laboratory column tests were also conducted to investigate the transport of oxidant and catalyst in contaminated groundwater. Test results proved that Fe(II) was adsorbed on soil surface, and thus soil behaved as a heterogeneous catalyst, enhancing the naphthalene removal rate up to 50%. Column tests that were conducted with and without dissolved Fe(II) showed that naphthalene removal ratio were 24% and 25%, respectively. The removal efficiency was not enhanced with dissolved Fe(II), since the dissolved Fe(II) flew out of the column as the oxidant progressively injected into the column saturated with Fe(II). It indicates that the injected oxidant could not interact with dissolved Fe(II). But target organic pollutant was degraded in soil column system, implying that sulfate radical was produced by the reaction of dissolved persulfate with Fe(II) adsorbed on soil.

• 한국지반환경공학회 논문집
• /
• 제24권9호
• /
• pp.15-24
• /
• 2023

지중 매설관 거동은 주변 지반의 비선형성과 복합거동 특성의 영향을 직접적으로 받게 되나, 실무에서는 지반의 복잡한 거동 특성을 단순화한 보-스프링 모델이 현재까지도 널리 활용되고 있다. 따라서, 연구 분야에서는 지반의 비선형 특성과 복합거동 특성을 반영하기 위한 연속체해석 방법을 활용하려는 다양한 연구들이 진행되어 왔고, 본 논문에서도 기존에 연구된 다양한 연속체 해석기법을 활용하여 수치해석을 수행하고, 변위-반력 결과 및 지반파괴 형상을 기존 실대형시험 결과와 비교·검토하였다. 지반과 매설관의 상호작용을 적용한 접촉면 특성을 적용한 경우, 실대형시험에 근접한 반력 결과를 도출할 수 있음을 확인하였으며, 실대형 시험과 유사한 파괴 형상도 확인하였다. 지반과 매설관의 상호작용을 무시한 매설관과 지반 절점 공유 방법의 경우, 과도한 반력 값을 도출하고, 파괴양상도 상이하였다. 또한, 대변형 해석에서 수렴성이 좋은 동적해석 explicit 방법, ALE 방법, CEL 방법을 각각 적용한 결과, 정적해석과 유사한 변위-반력 관계 및 파괴 형상이 확인되어, 향후 지반분야 대변형 해석에서 동적해석법도 충분히 활용될 수 있을 것으로 판단하였다.

• 한국지반공학회논문집
• /
• 제15권2호
• /
• pp.3-16
• /
• 1999

현재 국내에서는 부유식 구조물을 이용하여 소각로 및 담수화 공장을 해상에 축조하는 BMP(Barge Mounted Plant) 시스템에 관한 연구를 수행중에 있다(한국기계연구원 1997). 본 논문에서는 이러한 BMP의 계류 돌핀(mooring dolphin) 구조물하부의 말뚝기초의 거동을 모델하는 기법에 관하여 다루었다. 지반-말뚝계의 축하중 및 횡하중에 대한 거동은 지반을 비선형 스프링으로 모델하고 말뚝을 일축부재 및 보로 모델하여 유한차분적으로 해를 구하는 비선형 지반반력해석을 수행한다. 이러한 말뚝두부에서의 하중-변위관계로부터 지반-말뚝계의 등가강성을 산정할 수 있다. 따라서 본 연구에서는 거제도 주변 해역을 대상으로 지반조사를 수행하였고 이를 토대로 지반의 깊이에 따른 축방향 및 횡방향 하중전이 관계를 도출하였다. 그리고 돌핀하부의 말뚝에 대하여 축하중 및 횡하중에 대한 지반반력해석을 수행하였다. 이러한 해석과정을 통하여 대상지역에 적합한 말뚝의 관입깊이 및 단면을 합리적으로 산정할 수 있었다. 결국 말뚝두부에서의 하중-변위관계로부터 지반-말뚝계의 강성을 모델함으로써, 지반조건을 고려하여 돌핀구조물의 동적해석을 합리적으로 수행할 수 있었다. 해석결과 지반-말뚝계의 강성을 고려할 경우에는 강체로 고려한 경우에 비하여 변위 진폭이 상당히 크게 나타났다. 그리고 돌핀의 케이싱 상부의 모멘트가 더 크게 나타나고 해저지표 말뚝두부에 전달되는 모멘트는 더 작게 나타남을 알 수 있었다.