• Title/Summary/Keyword: Soil phosphorus

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A study on selenium quantification using ICP-MS with oxygen reactive gas in soil of Korea

  • Hyun-Young Kim;Young-Kyu Hong;Jin-Wook Kim;Sung-Chul Kim
    • Analytical Science and Technology
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    • v.37 no.4
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    • pp.230-238
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    • 2024
  • This study evaluates a method for quantifying selenium (Se) concentration in soil using inductively coupled plasma mass spectrometry (ICP-MS), with oxygen as a reaction gas. This approach addresses the challenge of detecting low levels of Se in complex soil matrices and aims to effectively minimize interference problems typically associated with argon plasma in traditional ICP-MS analyses. The analytical method utilizes conditions optimized for minimizing spectral interference and were validated by linearity, accuracy, precision, limit of detection (LOD), and limit of quantification (LOQ). The method demonstrated good linearity, high accuracy (90-97 %), and remarkable sensitivity, achieving detection and quantification limits of 0.15 ㎍/kg and 0.44 ㎍/kg, respectively. Developed analysis method for Se in soil was applied to field samples in the different regions of South Korea and Se concentration ranged from 0.11 to 0.52 mg/kg. Correlation analysis between Se concentration and soil properties showed that Se concentration was significantly correlated with cation exchange capacity (CEC) and available phosphorus among other soil properties.

Effects of Nitrogen Sources on Chlorophyll, and Oxidases in Soybean Leaves different in Phosphorus Sensitivity (인산감수성(燐酸感受性)이 다른 대두엽(大豆葉)의 엽록소(葉綠素) 및 산화효소(酸化酵素)에 대(對)한 질소원(窒素源)의 영향(影響))

  • Park, Hoon;Stutte, Charles A.
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.3
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    • pp.185-191
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    • 1973
  • Effects of nitrogen sources on chlorophyll, activity of some oxidases in soybean leaves were investigated in relation to phosphorus sensitivity. Ammonium and urea culture accelerated leaf senescence more in phosphorus sensitive cultivars. The leaf senescence patterns affected by nitrogen sources were clearly indicated by intact leaf absorbance. Absorption maximum (670nm in methanol extraction or 685nm in intact leaf), was not changed by nitrogen source in the same method. According to leaf senesence pattern general physiological sensitivity pattern was discussed. IAA-oxidase activity was higher in the phosphorus tolerant cultivars and nitrate treatment than in the sensitive cultivars and ammonium treatment. Glycolate oxidase activity was higher in the sensitive cultivars and nitrate treatment. Polyphenol oxidase activity was higher in the tolerant cultivars and urea treatment. It is concluded that the excess ammonium, to which excess phosphorus is highly similar in physiological effect, disturbs the photosynthetic system by inhibition of ATP generation (photo-and oxidative phosphorylation).

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Effects of Arbuscular Mycorrhiza Inoculation and Phosphorus Application on Early Growth of Hot Pepper(Capsicum annum L.) (Arbuscular mycorrhiza의 접종방법 및 인산시용량이 고추(Capsicum annum L.)의 초기생장에 미치는 영향)

  • Park, Hyang-Mee;Kang, Hang-Won;Kang, Ui-Gum;Park, Kyeong-Bae;Lee, Sang-Sun;Song, Sung-Dahl
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.1
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    • pp.68-75
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    • 1999
  • This study was conducted to examine the effects of Arbuscular Mycorrhizae inoculation and phosphorus application on early growth of hot pepper. Gigaspora margarita and Acaulospora spinosa were chosen for this investigation and inoculated into soils of different P levels by varying inoculation time and density. After treatment, some relevant growth responses of hot pepper were measured. Regardless of soil P levels, hot peppers treated with arbuscular mycorrhizal fungi had 5~34% more fresh weight than those untreated, but the effect of inoculation time and density was not different between two species. With decreased P levels, the infection rate and dependency of hot peppers increased. The content of P and K of AMF-inoculated hot peppers increased with increasing P levels, but the shoot to root ratio of those elements decreased. The results of this study showed that inoculation of AMF would be effective in promoting growth of hot pepper seedlings and increase transplant adaptation due in part to the resulted higher root development.

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Regional Early Growth Performances of Planted Chamaecyparis obtusa Seedlings in Relation to Site Properties (편백 조림목의 입지 특성에 따른 지역별 초기 생육 특성)

  • Yang, A-Ram;Hwang, Jaehong;Cho, Min Seok
    • Journal of Korean Society of Forest Science
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    • v.103 no.3
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    • pp.375-382
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    • 2014
  • The objective of this study was to investigate suitable plantation site for planted Chamaecyparis obtusa seedlings from the analysis of regional early growth performances. Two years old C. obtusa seedlings were planted with the density of $3,900seedlings{\cdot}ha^{-1}$ in late March, 2011 at Haeman and Jangseong, Jeollanamdo. In each study site, three plots ($400m^2$ per plot) were established and root collar diameter (mm) and tree height (cm) of each C. obtusa were measured in April, 2011 and October from 2011 to 2013. We also analyzed soil physical and chemical properties of sites and compartmental nitrogen and phosphorus concentrations of C. obtusa. Although the concentrations of soil nitrogen, organic matter, and C.E.C. at Haenam site were higher than those at Jangseong site, early growth performances of planted C. obtusa at Jangseong site were significantly better than those at Haenam site. The reasons for these results were probably related to deep available soil depth at Jangseong site and relatively low annual precipitation and sea wind at Haenam site, which was adjacent to the sea. The compartmental nitrogen and phosphorus concentrations of C. obtusa was in the order of needles > current twigs > fine root > stem and branches root above 2 mm in diameter. The phosphorus concentration of needles at Haenam site was significantly higher than that at Jangseong site. The results of this study might be useful for the selection of suitable plantation site for C. obtusa.

Vegetation Structure and Soil Properties of Ilex cornuta Population in Jeju Island (제주도 호랑가시나무개체군의 식생구조와 토양특성)

  • Kwon, Hye-Jin;Lee, Ji-Hye;Kim, Mu-Yeol;Lee, Jeong-Ho;Song, Ho-Kyung
    • Korean Journal of Environment and Ecology
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    • v.25 no.1
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    • pp.10-16
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    • 2011
  • This study was carried out to analyze the vegetation and soil characteristic, and ordination of the Ilex cornuta population, in the Yongsu Reservoir of Jeju Island. The Ilex cornuta population was classified into Cudrania tricuspidata dominant population, Sageretia theezans dominant population, and Mallotus japonicus dominant population. In the study sites, soil organic matter(O.M.), total nitrogen(T.N.), available phosphorus($P_2O_5$), changeable potassium, changeable calcium, changeable magnesium and soil pH were 14.62~17.35%, 0.39~0.51%, 8.83~20.15mg/kg, 0.44~0.64cmol+/kg, 5.79~6.87cmol+/kg, 3.43~4.19cmol+/kg and 5.41~5.80, respectively. The Mallotus japonicus dominant population was mainly found in the high percentage of available phosphorus, organic matter. It was also showed the lowest concentration of exchangeable K, and Mg. Cudrania tricuspidata dominant population and Sageretia theezans dominant population were found in the low percentage of available phosphorus, organic matter and there were also showed the highest concentration of exchangeable K, and Mg. It is one of the evidence that Ilex cornuta community indicated an intensive site management likes clearance of creeper is proper habitat management protocol. Thus, further researches should be followed to determine the other disturbance factors as management techniques.

Optimum Potting Medium and Nitrogen and Phosphorus Levels in the Soil for Root Nodule Formation in Black Locust (Robinia pseudoacacia L.) Seedlings (아까시나무(Robinia pseudoacacia L.) 유묘의 뿌리혹 형성에 적절한 배양토, 질소, 인 수준 구명에 관한 연구)

  • Lee, Kyung Joon;Lee, Hyun Ung;Kim, Taeyoo
    • Journal of Korean Society of Forest Science
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    • v.101 no.3
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    • pp.443-453
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    • 2012
  • The objectives of this study were to find out proper potting medium and nutrient levels in the soil to promote the root nodule formation in black locust (Robinia pseudoacacia L.) seedlings. Commercial potting medium, compost, organic fertilizer, molded forest fertilizer, and compound fertilizer were used at different mixing rates to bring in various levels of mineral nutrients in the soil. Seedlings were grown in pots in a greenhouse for three months. Commercial potting medium containing peatmoss, vermiculite, and geolite was not suited for early nodule formation due to lack of nutrients, even though it produced good total dry weight. Compost was the best medium to promote both high total dry weight production and nodule formation with providing the proper levels of nitrogen and phosphorus in the soil. Molded forest fertilizer was acceptable for nodule formation. Compound fertilizer and organic fertilizer was not suited for nodule formation. The potting medium should contain optimum levels of nitrogen (0.05-0.2%) and phosphorus (100-600ppm) to promote early nodule formation in black locust seedlings.

The Patterns of Inorganic Cations, Nitrogen and Phosphorus of Plants in Moojechi Moor on Mt. Jeongjok. (정족산 무제치늪 식물의 무기이온, 질소 및 인의 양상)

  • 배정진;추연식;송승달
    • The Korean Journal of Ecology
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    • v.26 no.3
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    • pp.109-114
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    • 2003
  • To investigate ecophysiological characteristics of plants species adapted to moor habitat, we selected 22 species plants and analyzed inorganic cations (K, Ca, Mg), heavy metals (Al, Fe, Mn) and total nitrogen and phosphorus quantitatively. Moojechi moor indicated typical acidic and oligotrophic conditions with pH of 5.0∼5.6 (pH 4.3∼5.1 in soil) and EC of 15∼30μ S/cm, and contained very low contents of soil divalent cation such as Ca and Mg but high contents of heavy metals (esp. Al). With respect to inorganic cation contents, investigated plants species showed remarkable interspecific difference. Plant species belonging to J. effusus var. decipiens, M. japonica, I. globosa, M. sacchariflorus, R. mucronulatum, R. yedoense var. poukhanense, H. micrantha, D. rotundifolia showed very low contents of inorganic cation below 400 μ M/g DW, but plant species of C. palustris var. spontanea, L. sessilifolia, P. mandarinorum, C. lineare, S. austriaca sub. glabra, V. mandshurica, A. decursiva showed high cation contents in leaves. Especially, S. austriaca sub. glabra (Compositae) and V. mandshurica (Violaceae) showed pattern accumulating Ca and Mg with plant growth, but I. ensata var. spontanea (Iridaceae) and S. officinalis (Rosaceae) showed decreasing tendency. Meanwhile, most plant species showed low contents of soluble metal ions in leaves in spite of high heavy metal contents on soil, and indicated remarkable interspecific differences in the total contents and composition of heavy metals accumulated. Despite low contents of N and P on soil, most plant species indicated relatively high contents of N and P in leaves at the early stage of growth, and showed slowly decreasing pattern according to growth. Consequently, it seems that plant species inhabited on Moojechi moor cope with acidic-oligotrophic conditions, accumulating inorganic cations and nitrogen at the early growing stage and reutilizing them in the course of growth, and developing heavy metal excluding mechanism.

Determination of Optimal Application Rates of Phosphorus and Potassium Fertilizers for Paddy Rice (벼에 대한 인산 및 칼리질비료의 적정시비량 결정)

  • Song, Yo-Sung;Jun, Hee-Joong;Park, Woo-Kyun;Jung, Beung-Gan;Jung, Kyu-Seok;Lee, Ki-Sang;Yoon, Young-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.2
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    • pp.75-82
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    • 2008
  • In order to establish environmentally friendly phosphorus(P) and potassium(K) fertilizer application rates for rice cultivation in Korea, a field experiment was conducted in two different characterized paddy soils, higher and lower P and K content in soil from 2005 to 2006 in Suwon, Korea. Chuchong which is typical rice variety in Korea, was selected for experiment. Rice yields in base P-K fertilizer level ($30-30kg\;ha^{-1}$) and no P-K fertilizer level were 97~98% and 93~97% of standard P-K fertilizer level ($45-57kg\;ha^{-1}$), respectively. At the lower content of P and K in immatured paddy soil, the yield of no P plot was decreased by 7% compared to that of standard P-K plot. Significant difference in rice yield and yield characteristics was found neither in standard P-K fertilization plot nor in base P-K fertilization plot. There was no significant difference in P and K uptake at the harvest stage between standard P-K fertilizer plot and base P-K fertilizer plot. Phosphorus and K uptake was slightly decreased in no fertilizer plots compared to standard fertilizer plot. Phosphorus and K use efficiency of rice plant in base fertilizer plot was higher than that in standard fertilizer plot. Available phosphorus and exchangeable potassium content in soil at the harvest stage were increased in both standard and base fertilizer plot. But no significant difference of P and K content in ? was found between standard fertilizer plot and base fertilizer plot. Rice quality characteristics such as proportion of brewers rice, damaged kernel, broken rice, and content of amylose and protein were lowered in the base fertilizer plot than the standard fertilized plot, while the proportion of perfect kernel increased in the base fertilizer plot From the results, we generally recommend the base P-K fertilization ($30-30kg\;ha^{-1}$) instead of standard P-K fertilization ($45-57kg\;ha^{-1}$) for rice cultivation in Korea.

Characteristics of Phosphorus Accumulation in Organic Farming Fields (유기농업실천농가 포장내 인산의 분포특성)

  • Kim, Pil-Joo;Lee, Sang-Min;Yoon, Hong-Bae;Park, Yang-Ho;Lee, Ju-Young;Kim, Suk-Chul;Choe, Suk-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.4
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    • pp.234-241
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    • 2000
  • Organic farming (OF) is regarded as alternative farming types against general farming system for sustainable agriculture, recently. However, there is little information on effects of OF on soil properties and watershed condition. In order to determine the effects of OF on soil properties, 36, 10 and 8 sites of organic farming (OF) fields of plastic film houses, paddy and orchard were selected in the national scale, respectively, to evaluate their chemical properties and phosphorus distributing characteristics. The average organic matter (OM) contents in organic farming fields were with $44g\;kg^{-1}$ in plastic film houses, $26g\;kg^{-1}$ in paddies and $39g\;kg^{-1}$ in orchard soils higher than the average OM contents in conventional farming (CF) soils. Available phosphates were accumulated to 986 in plastic film house soils and $754mg\;kg^{-1}$ in orchard soils, respectively, over the optimum range. Furthermore, total P (T-P) reached to $2.973mg\;kg^{-1}$ in plastic film houses and $2303mg\;kg^{-1}$ in orchards in OF soils. It could be attained by applying repeatedly low N/P ratio of manure-based compost. In two types of soils inorganic P was dominant with the ratio of 62~80% of T-P, and then residual and organic Ps followed. However. residual-P was dominant in paddy soils with the rate of 50% of T-P. Fractionation of soil extractable P showed that Ca-P was dominant with about $1,330mg\;kg^{-1}$ in upland soils in OF fields, which is affected by high soil pH of over 6.0. However. Fe-P of extractable P was dominant in paddy soils. Water-soluble P was very high with 65 and $26mg\;kg^{-1}$ in plastic film house and orchard soils in OF. From this results. OF regarded as an environment-friendly farming system may cause serious soil deterioration by accumulated phosphorus and may also cause water pollution.

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Influence of Fly Ash Application on Growth and Yield of Corn(Zea mays L.) (석탄회(石炭灰)(Fly Ash) 시용(施用)이 옥수수의 생육(生育) 및 수량(收量)에 미치는 영향(影響))

  • Kim, Jeong-Je;Yang, Jae-Eui;Cho, Byong-Ok;Choi, Byeong-Seon;Park, Jong-Hyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.3
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    • pp.249-254
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    • 1992
  • This research was conducted to investigate the effects of fly ash applications on growth and yield parameters of corn (Zea mays L.), and soil chemical properties. Corn height at silking stage, and height and dry matter ratio at harvesting stage were enhanced by applications of fly ashes derived from bituminous coal and anthracite, respectively. Effects of fly ash treatment on growth parameters of corn were varied with kinds and levels of fly ash application and growth periods, but relatively small without revealing a major negative effect as compared to the control. Yield of corn was increased by applying fly ash of anthracite origin, but other yield components were not influenced negatively by fly ash treatment. Soil total carbon contents, cation exchange capacity, and phosphorus contents of soils sampled after harvest of corn were significantly increased by fly ash treatment, although there were slightly different effects according to kinds and levels of fly ash application. Exchangeable cations of soils were varied within an experimental error range. Phosphorus taken up by corn was enhanced by treating fly ash of the bituminous coal to the soil and there were a positive correlation between phosphorus uptake and soil Phosphorus level. Cation uptake by corn was changed a little, but no significant reduction was observed in cation uptake due to fly ash treatment. It seems to be difficult to figure out the mechanism of fly ash effects on growth and nutrient uptake by corn with one year field experiment, however treatment of fly ash enhanced some parameters of growth and yield, and nutrient uptake by corn without revealing any major negative effects. To determine the value of fly ash as a fertilizer source, continuous researches under various soil and crop conditions were considered to be necessary.

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