• Journal of Soil and Groundwater Environment
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• v.18 no.5
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• pp.46-55
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• 2013

The main objective was to evaluate the efficiencies of different separation techniques, such as gravity separation, magnetic separation, and aerial separation. Zinc and cadmium removal efficiencies by gravity separation and magnetic separation were 28.3~29.3% and 19.1%, respectively, and were higher than the efficiency obtained by aerial separation. Results showed that the combination of gravity separation and magnetic separation in series which was to maximize the removal efficiencies gave removal efficiency of 21.5~38.7% for zinc and 22.1~23.4% for cadmium. The mass of soil meeting the regulation standards for zinc and cadmium after retrieval from the combined separation process accounted for approximately 80% of the treated soil that would be reusable without the pre-treatment procedure as the neutralization process using in the soil washing method. Physical separation techniques utilizing heavy metal properties are the alternative method to remediate heavy-metal contaminated soils in environmental and economic aspects.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.904-909
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• 2012

Acid sulfate soil (ASS) and potential acid sulfate soil (PASS) are distribution in worldwide and originate from sedimentary process, volcanic activity, or metamorphism and are problematic in agriculture and environmental due to their present and potential acidity developed by the oxidation. The PASS was defined as soil materials that had sulfidic layer more than 20 cm thick within 4 m of the soil profile and contained more than 0.15% of total-sulfur (T-S). A tentative interpretative soil classification system was proposed weak potential acid sulfate (T-S, 0.15-0.5%), moderate potential acid sulfate (T-S, 0.5-0.75%) and strong potential acid sulfate (T-S, more than 0.75%). PASS due to excess of pyrite over soil neutralizing capacity are formed. It provides no information on the kinetic rates of acid generation or neutralization; therefore, the test procedures used in acid base account (ABA) are referred to as static procedures. The net acid generation (NAG) test is a direct method to measure the ability of the sample to produce acid through sulfide oxidation and also provides and indication. The NAG test can evaluated easily whether the soils is PASS. The samples are mixed sandy loam and the PAS from the hydrothermal altered andesite (1:3, 1:8, 1:16, 1:20, 1:40, 1:80 and 1:200 ratios) in this study. We could find out that the NAG pH of the soil containing 0.75% of T-S was 2.5, and that of the soil has 0.15% of T-S was 3.8. NAG pH test can be proposed as soil classification criteria for the potential acid sulfate soils. The strong type has NAG pH of 2.5, the moderate one has NAG pH of 3.0, and the weak one has NAG pH of 3.5.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.533-539
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• 2014

Mine wastes such as acid mine drainage (AMD) can cause the detrimental effects on surrounding environment, thereby eventually threatening human health. Main objective of this study was to evaluate the neutralizing effect of fly ash (FA) as a stabilizing material AMD. Field plot was constructed in a coal waste depot which has caused aluminium-whitening adjacent to the stream. Different mixing ratios of FA were applied on a top of the soil, and then the physicochemical properties of runoff and soil were monitored. Constructed plots were as following: control (mine waste only (W)), mine waste + 20% ($w\;w^{-1}$)of FA (WC20M), mine waste + 40% ($w\;w^{-1}$)of FA (WC40M), and WC40M dressed with a fresh soil at the top (WC40MD). Result showed that initial pH of runoff in control was 5.09 while that in WC40M (7.81) was significantly increased. For a plot treated with WC40M, the concentration of Al in runoff was decreased to $0.22mg\;L^{-1}$ compared to the W as the control ($4.85mg\;L^{-1}$). Moreover, the concentration of Fe was also decreased to less than half at the WC40M compared to the control. Application of FA can be useful for neutralizing AMD and possibly minimizing adverse effect of AMD in mining area.

• Journal of Soil and Groundwater Environment
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• v.19 no.1
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• pp.63-69
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• 2014

This paper presents the feasibility of using different iron oxides (microscale hematite (HT), microscale magnetite (MT), and nanoscale maghemite (NMH)) in enhancing nitrate reduction by zero-valent iron (Fe(0)) under two solution conditions (artificial acidic water and real groundwater). Addition of MT and NMH into Fe(0) system resulted in enhancement of nitrate reduction compared to Fe(0) along reaction, especially in groundwater condition, while HT had little effect on nitrate reduction in both solutions. Field emission scanning electron microscopy (FESEM) analysis showed association of MT and NMH with Fe(0) surface, presumably due to magnetic attraction. The rate enhancement effect of the minerals is presumed to arise from its role as an electron mediator that facilitated electron transport from Fe(0) to nitrate. The greater enhancement of MT and NMH in groundwater was attributed to surface charge neutralization by calcium and magnesium ions in groundwater, which in turn facilitated adsorption of nitrate on Fe(0) surface.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.727-733
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• 2011

A new Korean standard for the determination of Cr(VI) in soils has been officially published as ES 07408.1 in 2009. This analytical method is based on the hot alkaline digestion and colorimetric detection prescribed by U.S. EPA method 3060A and 7196A. The hot alkaline digestion accomplished using 0.28 M $Na_2CO_3$ and 0.5 M NaOH solution (pH 13.4) at $90{\sim}95^{\circ}C$ determines total Cr(VI) in soils extracting all forms of Cr(VI), including water-soluble, adsorbed, precipitated, and mineral-bound chromates. This aggressive alkaline digestion, however, proved to be problematic for certain soils which contain large amounts of soluble humic substances or active manganese oxides. Cr(III) could be oxidized to Cr(VI) by manganese oxides during the strong alkaline extraction, resulting in overestimation (positive error) of Cr(VI). In contrast, Cr(VI) reduction by dissolved humic matter or Fe(II) could occur during the neutralization and acidic colorimetric detection procedure, resulting in underestimation (negative error) of Cr(VI). Futhermore, dissolved humic matter hampered the colorimetric detection of Cr(VI) using UV/Vis spectrophotometer due to the strong coloration of the filtrate, resulting in overestimation (positive error) of Cr(VI). Without understanding the mechanisms of Cr(VI) and Cr(III) transformation during the analysis it could be difficult to operate the experiment in laboratory and to evaluate the Cr(VI) results. For this reason, in this paper we described the theoretical principles and limitations of Cr(VI) analysis and provided useful guidelines for laboratory work and Cr(VI) data analysis.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.4
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• pp.393-402
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• 1999

Precipitation samples were collected by the wet-only sampling method in Iksan in the northwest of Chonbuk from March 1995 to February 1997. These samples were analyzed for the concentration of ion components, in addition to pH and electrical conductivity. The annual mean pH of precipitation was 4.8 and the seasonal trend of pH was shown to be low in Fall and Winter(4.5), middle-ranged in Spring(4.7) and high in Summer(5.0). The frequency of pH below 5.6 was about 71%. The seasonal pattern of pH frequency was found to be different in each season. In the case of the pH less than 5.0, the frequency was higher in Spring, Fall and Winter than in Summer, especially higher in Fall than in other seasons. The concentrations of analysed ions showed a pronounced seasonal pattern. However, major ion species for all seasons were $NH^+_4,;Ca^{2+};and;Na^+$ among cations and $SO^{2-}_4,;Cl^-;and;NO^-_3$ among anions. The major acidifying species appeared to be $nss-SO^{2-}_4;and;NO^-_3$, and the main bases responsible for the neutralization of precipitation acidity were $nss-Ca^{2+};and;NH^+_4$. The potential acidity of precipitation, pAi, was found to be between 3.0 and 5.0 for total samples, while the measured pH was approximately between 3.9 and 7.8. The seasonal trend of pAi showed a decreasing order: Summer (4.3), Winter(4.0), Spring and Fall(3.8). During the Fall, both pAi and pH were especially very low, which indicated that during this period the potential acidity of precipitation was high but the neutralizing capacity was low. For Spring, pAi was very low but pH was slightly high. This was likely due to the large amount of $CaCO_3$ in the soil particles transported over a long range from the Chinese continent that were incorporated into the precipitation, and then neutralized the acidifying species with its high concentraton.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.5
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• pp.555-566
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• 1999

The rainwater samples were collected from the 1100 Site of Mt. Halla and Cheju city during the period of March in 1997 to August in 1998, and the major soluble ions were analyzed. The confidence of analytical data was confirmed by using the comparison methods such as ino-balance, electric conductivity and acid fraction, all of which correlation coefficients were above 0.94. The ionic strengths lower than $10^{-4}$ M, the basis for the pure rainwater, were found in 47% and 38% at 1100 Site and Cheju city, respectively. The precipitations in Cheju city were more influenced by the oceanic effect than those in 1100 Site. The acidity contribution was mainly by $SO_4^{2-}$ and $NO_3^-$ in both areas, and the organic acids have contributed to the acidity with only 5~7%. The neutralization factors by $NH_3$ were about 46% at both 1100 site and Cheju city, whereas those by $CaCO_3$ were 11% and 15% at 1100 site and Cheju city respectively, and the free acidity were both about 35% in average. From the MSA analysis, it was found that the air in Cheju island has been influenced by the pollution from the other areas. The sources of the rainwater components in 1100 Site and Cheju city were also studied with a factor analyzing way, and the most probable factors were found to be anthropotgenic, oceanic, and soil-sourced. The results of multiple regression analysis have shown that $SO_4^{2-}$ was dissolved mostly in the form of $H_2SO_4, CaSO_4 and (NH_4)_2SO_4$, and $NO_3^-$ was in the form of $HNO_3, Ca(NO_3)_2 and NH_4NO_3$.

• Korean Journal of Soil Science and Fertilizer
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• v.5 no.1
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• pp.25-32
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• 1972

The effects of limestone and wollastonite on an acid sulfate soil were studied. In addition, the effect of wollastonite was analyzed in terms of those due to calcium and to silica in the paddy field and in the laboratory with equivalent amounts of lime and wollastonite on a calcium basis. 1. Lime and wollastonite as liming materials were equally effective in neutralizing the soil acidity. 2. Lime, however was more reactive, raising the pH up to neutralization point in three days under waterlogged conditions at $25^{\circ}C$, in the lab study, and introduced alkali damage to transplanted rice seedlings showing marked restrictions of tillering in the field even though lime was applied two weeks before transplanting. On the other hand, wollastonite reacted very slowly, taking one week to two weeks to reach neutralization even when thoroughly mixed, and did not restrict the tillering. 3. Both lime and wollastonite effectively reduced the toxic aluminium in soil as well as in the soil solution but not always in the case of ferrous iron. However the reduction effect of the toxic substances in the experimental field was not so great as expected, because typical toxic symptoms were mild only. 4. Lime considerably increased the availability of silica in soil resulting in an increase of silica content in straw. Wollastonite released extra available silica itself resulting in a greater uptake of silica. 5. Increase of silica uptake by these materials was effective in reducing rate of infection of neck blast and resulted in higher rate of ripening, and in turn increased the paddy yield. 6. Application of either one significantly diminished the effect of the other. 7. Wollastonite markedly increased tillering in the early growing stage, but decreased the rate of effective tillers finally, resulting in about the same number of ears per hill at harvesting. 8. These liming materials appear to increase the number of grains per panicle slightly.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.1
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• pp.52-57
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• 2005

Previous studies showed that shell meal fertilizer from the oyster farming industry could be a potential inorganic soil amendment to increase Chinese cabbage productivity and to restore the soil nutrient balance in upland soil (Lee et al., 2004). Herein, shell meal fertilizer was applied at rates of 0, 4, 8, 12, and $16Mg\;ha^{-1}$ to upland soil (Pyeontaeg series, Fine silty, Typic Endoaquepts) for Chinese cabbage cultivation. We found available phosphate increased significantly with shell meal fertilizer application, due to high content of phosphate ($1.5g\;P_2O_5\;kg^{-1}$) in the applied shell meal fertilizer. In addition, high pH of shell meal fertilizer contributed to increase available phosphate content by neutralization of acidic soil. Total and residual P contents increased significantly with increasing shell meal fertilizer application, but we could not find any tendency in organic and inorganic P fraction. Of extractable P fraction, water-soluble phosphorus (W-P) and calcium-bound P (Ca-P) contents increased significantly with increasing application level. By contrast, aluminum and iron-bound P (Al-P and Fe-P) decreased slightly with shell meal application. The present experiment indicated that shell meal fertilizer had a positive benefit on increasing available phosphate content in arable soil. And so the increased available phosphate by shell meal fertilizer may decrease phosphate application level and then reduce phosphorus loss in arable soil.

• Korean Journal of Soil Science and Fertilizer
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• v.40 no.5
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• pp.412-417
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• 2007

This study was to elucidate the effects of layered double hydroxides(LDHs) application on the chemical properties of the soils along with the fate of the applied LDHs. The effects of LDHs application were compared with those of calcium carbonate widely used for the neutralization of acidic soils. Incorporation of LDHs into the soil resulted in higher pH value and $Mg^{2+}$ content in soil leachate than that of $CaCO_3$ treatment. There was no significant difference in water-soluble P content in both the treatments. However, $Al^{3+}$ and $Si^{4+}$ contents were decreased by LDHs and $CaCO_3$ treatment, even though a large amount of $Al^{3+}$ was released into soil solution with the disintegration of LDHs framework. LDHs structure in soil was gradually disintegrated from the its original layered structure under acidic condition of soil. Therefore, this study suggests that LDHs could be utilized as a carrier of functional substances to enhance the efficiency of various ago-chemicals without any ill effects on the soil environments.