• Title/Summary/Keyword: Soil mineral

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Geochemistry, Secondary Contamination and Heavy Metal Behavior of Soils and Sediments in the Tohyun Mine Creek, Korea (토현광산 수계에 분포하는 토양과 퇴적물의 지구화학적 특성, 이차적 오염 및 중금속의 거동)

  • 이찬희;이현구;윤경무
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.39-53
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    • 2001
  • Environmental pollution of the Tohyun mine creek area was investigated on the basis of geology, mineralogy and geochemistry. In soils and sediments of the mine area, ${Al_2}{O_3}/{Na_2O}$ and ${K_2}O/{Na_2}O$ ratios are partly negative correlation against ${SiO_2}/{Al_2}{O_3}$, respectively. Geochemical characteristics of some trace and rare earth elements such as V/Ni, Ni/Co, La/Ce, Th/Yb, Th/U, La/Th, ${La_N}/{Yb_N}$, La/Sc and Sc/Th are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. These results suggest that sediments source of the host shale around the mine area could be originated by basic to intermediate igneous rocks. Mineral compositions of soil and sediment near the mine area were partly variable mineralogy, which are composed of quartz, mica, feldspar, chlorite, clay minerals and some pyrite. Soils and sediments with highly concentrated heavy minerals, gravity separated mineralogy, are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various kinds of hydroxide minerals on the polished sections. As normalized by bed rock composition, average enrichment indices of major elements in sediments, precipitates, farmland soils and paddy soils are 1.0, 1.7, 0.9 and 0.8, respectively. Maximum concentration of environmental toxic elements in the mine creek are detected with Ag = 186 ppm, As = 17,100 ppm, Bi = ]27 ppm, Cd = 77 ppm, Cu = 12,299 ppm, Pb = 8,897 ppm, Sb = 1,350 ppm, W = 599 ppm and Zn = 12,250 ppm, which are increasing with total FeO increasing, and extremely high concentrations of surface sediments and precipitates near the waste rock dump. These toxic elements (As, Bi, Cd, Cu, Pb, Sb, W and Zn) of the samples, normalizing by host rock concentration, revealed that average enrichment index is 106.0 for sediments, 279.6 for precipitates, 3.5 for farmland soils and 1.6 for paddy soils. However, on the basis of EPA values, enrichment indices of all the samples are 40.7, 121.4, 1.3 and 0.6, respectively.

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An Initiative Study on Relationship between Algal Blooms and Asian Dust for Regulation of Algal Blooms (조류 성장 억제를 위한 녹조 및 적조 발생과 황사의 상관관계 초기적 연구)

  • Kim, Tai-Jin;Jeong, Jaechil;Seo, Rabeol;Kim, Hyung Moh;Kim, Dae Geun;Chun, Youngsin;Park, Soon-Ung;Yi, Sehyoon;Park, Jun Jo;Lee, Jin Ha;Lee, Jay J.;Lee, Eun Ju
    • KSBB Journal
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    • v.29 no.4
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    • pp.285-296
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    • 2014
  • Although the problems of the algal blooms have been world-widely observed in freshwater, estuary, and marine throughout the year, it is not yet certain what are the basic causes of such blooms. Consequently, it is very difficult to predict when and where algal blooms occur. The constituents of the Asian dust are in a good agreement with the elements required for the algal growth, which suggests some possible relationship between the algal blooms and the Asian dust. There have been frequently algal blooms in drinking water from rivers or lakes. However, there is no any algal blooms in upwelling waters where the Asian dust cannot penetrate into the soil due to its relatively weak settling velocity (size of particles, $4.5{\pm}1.5{\mu}m$), which implies the possible close relationship of the Asian dust with algal blooms. The present initiative study is thus intended firstly in Korea to illustrate such a relationship by reviewing typical previous studies along with 12 years of weekly iron profiles (2001~2012) and two slant culture experiments with the dissolved Asian dust. The result showed bacterial suspected colonies in the slant culture experiment that are qualitatively in a good agreement with the recent Japanese studies. Since the diatoms require cheap energy (8%) compared to other phytoplankton (100%) to synthesize their cell walls by silicate, the present results can be used to predict algal blooms by diatoms if the concentrations of iron and silicate are available during spring and fall. It can be postulated that the algal blooms occur only if the environmental factors such as light, nutrients, calm water surface layer, temperature, and pH are simultaneously satisfied with the requirements of the micronutrients of mineral ions supplied by the Asian dust as enzymatic cofactors for the rapid bio-synthesis of the macromolecules during algal blooms. Simple eco-friendly methods to regulate the algal blooms are suggested for the initial stage of blooming with limited area: 1) to cover up the water surface with black curtain and inhibit photosynthesis during the day time, 2) to blow air (20.9%) or pure oxygen into the bottom of the water and inhibit rubisco for carbon uptake and nitrate reductase for nitrogen uptake activities in algal growth during the night, 3) to eliminate the resting spores or cysts by suction of bottom sediments as deep as 5 cm to prevent the next year germinations.

Importance of Microtextural and Geochemical Characterizations of Soils on Landslide Sites (산사태지역 토층의 미세조직과 지화학적 특성의 중요성)

  • Kim Kyeong-Su;Choo Chang-Oh;Booh Seong-An;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.15 no.4 s.42
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    • pp.447-462
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    • 2005
  • The purposes of this study are to evaluate and discuss the importance of geochemical properties of soil materials that play an important role in the occurrence of the landslide, using analyses of microtexture, particle size distribution, XRC, and FE-SEM equipped with energy dispersive spectrum on soils collected from landslide slopes of gneiss, granite and sedimentary rock areas. Soils from gneiss and granite areas where landslides took place have much clay content relative to those from non landslide areas, particularly pronounced in the granite area. Therefore the clay content is considered a sensitive factor on landslide. Clay minerals contained in soils are illite, chlorite, kaolinite and montmorillonite. Especially the content of clay minerals in soils from the Tertiary sedimentary rocks is highest, with abundant montmorillonite as expandable species. It is believed that this area was much vulnerable to landslide comparable to other areas because of its high content of monoorillonite, even though there might be weak precipitation. Since no conspicuous differentiation in mineralogy between the landslide area and non landslide area can be made, the occurrence of landslide may be influenced not by mineralogy, but by local geography and mechanical properties of soils. Geochemical information on weathering properties, mineralogy, and microtexture of soils is helpful to better understand the causes and patterns of landslide, together with engineering geological analyses.

Characterizing Fluorescence Properties of Dissolved Organic Matter for Water Quality Management of Rivers and Lakes (하천 및 호소 수질관리를 위한 용존 자연유기물질 형광특성 분석)

  • Hur, Jin;Shin, Jae-Ki;Park, Sung-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.940-948
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    • 2006
  • Fluorescence measurements of dissolved organic matter(DOM) have the superior advantages over other analysis tools for applying to water quality management. They are simple and fast and require minimal pretreatment of samples. Fluorescence index($F_{450}/F_{500}$), synchronous spectra, and fluorescence excitation-emission matrices(EEM) of various DOM samples were investigated to discriminate autochthonous/allochthonous composition, protein-like fluorescence, fulvic-like fluorescence, humic-like fluorescence, terestrial humic-like fluorescence by comparing among the real DOM samples of different origins with the help of literature. The samples used included standard purified DOM, lake, river and wastewater treatment effluent. The relative distribution of various DOM composition was derived from the ratios of each fluorescence region. The results were very consistent with those expected from the sample properties. Allochthonous and terrestrial humic-like fluorescence were more prominent in the samples with abundant soil-derived DOM components. In addition, the protein-like fluorescence property was more pronounced in the samples where strong algal or microbial activities were expected. It was also shown that the ratio of protein-like/terrestrial humic-like fluorescence obtained from synchronous spectrum and fluorescence EEM could be used as an indicator for the evaluation of wastewater treatment on the downstream water quality of rivers and for the prediction of the degree of algal/microbial activities in lakes. It is expected that the results of this study will provide the basic information to develop the future water quality management techniques using DOM fluorescence measurements.

Burial Age and Flooding-origin Characteristics of Coastal Deposits at Gwangseungri, Gochanggun, Korea (고창군 광승리 연안 퇴적층의 퇴적 시기와 범람 기원 특성)

  • Kim, Jong Yeon;Yang, Dong Yoon;Shin, Won Jeong
    • Journal of the Korean earth science society
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    • v.36 no.3
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    • pp.222-235
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    • 2015
  • Samples were collected from both places including the coastal area within the height of 5 m above the mean sea level (msl) (DH) and the top of the coastal terrace of 10-15 m msl (KS) high in Gwangseungri, Gochanggun, Korea. To find the origin of the deposit in the coastal area, granulometric analysis and geochemical analysis were performed. The result showed that the DH samples were originated from the reddish soils overlaying weathered bedrock which presented gradual change of chemical composition from the bottom toward the top. Clay minerals were found from the DH samples. These results concluded that the DH samples were found as in-situ weathered materials. The KS samples were originated from the soil layer covering gravel layer at the foot slope of the hill along the coast. The KS samples contained different chemical compositions from the DH. It is inferred that some of this layer was disturbed or experienced the influx of foreign material. The particle size of the KS samples was different from those found on the beach. The particle size of lower parts of KS site was finer than that on the beach, but the particle size of middle part of the site was coarser than that on the beach. The sorting of the KS site was poorer than that on the beach. Thus, it is inferred that some parts of the layer were formed by short-lived high energy event rather than sustained and continuous action of tidal currents and/or waves. Analysis using an optically stimulated luminescence (OSL) method showed that the burial age of samples from KS site were found 0.65-0.71 ka. Though the characteristics of the sediment layer and forming event in this area should be further studied, it can be inferred that this sedimentary layer formed by coastal flooding with storm.

Promotion Directions of Spa Industry Using Local Resources in Jeju Island, Korea (제주도 향토자원을 활용한 스파산업 육성방향)

  • Yoon, Hye Yung
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.8 no.1
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    • pp.69-78
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    • 2013
  • Settled lifestyle as important to health and healing to medical tourism and wellness tourism in the 21st century has emerged as the best promising service industry. Jeju Island has a variety of local resources, and the directions was considered to spa industry promotion application it. Jeju Island has a variety of local resources which can be used for spa industry promotion. Jeju Island's beautiful natural environment, mineral resources, water resources, biological resources, agricultural products, traditional folk remedies available in Jeju's spa treatments. Using the local resources of Jeju, 'Jeju specialized spa treatments' can develop of 12 kinds of spa treatments. Namely, thalssotherapy, stone therapy, black sand poultice, hot-floored therapy using volcanic soil, thalassotherapy, drinking therapy, hydrotherapy, herbal/medicinal plants poultice, forest therapy, Spa cuisine, facial beauty, diet therapy. 12 kinds of Jeju specialized spa treatments development and service to the local resources of basic research on the physical and chemical characteristics, product development, clinical trials, efficacy studies should precede. In addition, customized spa services programs should be developed considering the propensity of customers, customer needs, and a spa type. And standardized program of spa services and need a manual painter. Medical tourism and wellness tourism in conjunction with efforts to be considered in order to increase the competitiveness of the spa industry in Jeju.

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Interpretation of Material Homogenity and Making Techniques of the Jar Coffins from the Oryangdong Kiln Site and the Ungokdong Tomb Site in Naju, Korea (나주 오량동 가마와 운곡동 분묘 유적 출토 대형전용옹관의 재료학적 동질성과 제작기법 해석)

  • Kim, Ran-Hee;Cho, Mi-Soon;Yeon, Ung;Seo, Jeong-Seog;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.26 no.3
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    • pp.229-245
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    • 2010
  • The pupose of this study was to identify the material characteristics, firing environments and making techniques for the jar coffins from the Oryangdong kiln site and the Ungokdong tomb site in Naju. All jar coffins had very similar physical, mineralogical and geochemical characteristics, although it was excavated from the different sites. The wall thickness of the jar coffins was about 2.3 to 5.3 cm. Under the microscopy, the jar coffins include a large quantity of various quartz with some microcrystalline and showed partly orthoclase and biotite. It is presumed that the mineral sherds added to maintain the thick wall and to control the percentage of contraction during drying and firing of jar coffins and it has contained about 11.4 to 19.8 %. Firing temperature of the jar coffins is estimated as 1,000 to $1,150^{\circ}C$. Also, all jar coffins and soils show similar geochemical behavior of elements and clay-mineralization degree within the site. This indicates making that the soil is probable to be a raw material of the jar coffins. But it shows different characteristics in major elements of soils which is collected at the kiln floor and the trench region of the Oryangdong kiln site because of the lack of quartz and feldspar in the soils. Therefore, it can use of the jar coffins making clay, if it goes through a simple special process such as mixing temper.

Analysis of Well Water Quality for Hydroponic Farms in Chollabuk-do Area (전북지역 양액재배 농가의 원수 수질 분석)

  • 배종향;이용범
    • Journal of Bio-Environment Control
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    • v.5 no.2
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    • pp.131-137
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    • 1996
  • This analysis has been conducted to get some basic data of the composition of culture solution mostly in inorganic ions, and water quality in hydroponic farms in Chollabuk - do. pH range was shown from 6.00 to 7.65 and the average was 6.58. EC range was shown from 0.01 to 0.94 mS/cm and the average was 0.28 mS/cm. Na concentration ranged from 4.71 to 145.44 ppm and Cl concentration ranged from 0 to 171.80 ppm were shown and their average were 24.24 ppm and 26.33 ppm, respectively. Na and Cl concentrations were higher as 7.7%, compared to those of other farms, which could cause the salt accumulation in the substrate mats. K, Ca and Mg concentrations were ranged from 0.93 to 17.38 ppm, 2.29 to 34.30 ppm and 0.70 to 18.61 ppm, respectively. Average concentrations were 3.06 ppm in K, 13.00 ppm in Ca and 4.91 ppm in Mg. 50, and PO$_4$ concentration ranged from 0.63 to 59.79 ppm and 0 to 4.28 ppm were shown and their average were 18.11 and 0.51 ppm. Cu concentration was ranged from 0 to 0.32 ppm and 0 to 6.22 ppm in Zn concentration. Their average were 0.02 ppm and 0.52ppm, respectively.

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Geochemical Studies of $CO_2$-rich Mineral Water in the Kangwon Province (강원도지역 탄산약수의 지화학적 연구)

  • 고용권;김천수;최현수;박맹언;배대석
    • Journal of the Korean Society of Groundwater Environment
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    • v.7 no.2
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    • pp.73-88
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    • 2000
  • The geochemistry of the $CO_2$-rich waters ($Pco_2\leq$about 1 atm) in NE part of the Kangwon province was investigated. The $CO_2$-rich waters can be divided to three types based on chemical compositions: Na-$HCO_3$, Ca-Na-$HCO_3$and Ca-$HCO_3$types. The water chemistry indicates that these type waters were evolved through reaction with host rocks by supply of deep-seated $CO_2$during deep circulation, and their geochemical environments in depth might have been different each other. The dissolution process of plagioclase is important in water/granite interactions and its solubility change according to reaction temperature played an important role in the determination of chemical compositions. The higher reaction temperature coincides with the lower different in solubility between albite and anorthite. It means that calcium is mainly released to the water in the lower temperature, whereas sodium in the higher temperature due to high Na/Ca ratio in plagioclase. The application of various chemical geothermometries on the $CO_2$-rich waters shows that the calculated reservoir temperature of Na-$HCO_3$type (about 15$0^{\circ}C$) is higher than those of Ca-$HCO_3$type. Therefore, we now interpret the recognized chemical difference was mainly due to the difference of reaction temperature. Considering normal thermal gradient, we can understand that the Na-$HCO_3$type was evolved from deeper crustal depth than the Ca-$HCO_3$type.

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A Case Study on the Analysis of Cause and Characteristics of a Landslide at the Sedimentary Rock Area (퇴적암 지역에서의 산사태 원인 및 특성 분석에 대한 사례연구)

  • Song, Young-Suk;Hong, Won-Pyo
    • The Journal of Engineering Geology
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    • v.17 no.1 s.50
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    • pp.101-113
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    • 2007
  • A landslide was occurred due to soil cutting for construction to expand the Donghae express highway in Dong-hae-City, Korea. The total area of the landslide was about $9,550m^2$ with 100 m of width and 87m of height. The landslide was occurred due to the internal factor of the unstable geological structure including the clay layer and the external factor of continuous heavy rainfalls. As the result of field instrumentation during the landslide, the horizontal displacement of the slope ground increases with increasing the accumulated rainfall by continuous rainfall during the rainy season. Also, the depth of sliding failure was decided by the horizontal displacement distribution during landslide occurrence. It makes sure that the horizontal displacement starts from the depth of sliding failure and the depth of sliding failure matches well with the location of the clay layer. As the slope stability analysis using Bishop's Simplified Method at the landslide area, the safety factor of slope during the rainy season was 0.53. This safety factor of slope was enough to trigger the landslide at this area. The depth of sliding failure obtained by analytical method matches well with the depth of the clay layer.