• 한국토양비료학회지
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• 제49권1호
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• pp.87-92
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• 2016

With the population growth and industrialization, the characteristics of discharged waste water and sewage have become more diverse. The removal of phosphorus (P) in the wastewater is essential for the prevention of eutrophication in the river and stream. This study was performed in order to estimate the field application of the Bacillus sp. 3434 BRRJ. Bacillus sp. 3434 BRRJ was cultured in the raw wastewater and synthetic medium at the 5 L reactor. The best optimum conditions for P removal by Bacillus sp. 3434BRRJ in the synthetic medium at the 5 L reactor were as follows: temperature, $30^{\circ}C$; P concentration, 20 mg/L; carbon sources, glucose + acetate (1:1); oxygen concentration, alternatively anaerobic and aerobic conditions. P removal efficiency under the optimum condition was 89.4%. In case of wastewater, P removal efficiency was 95.5% under controlled at $30^{\circ}C$. Through this study we confirmed that P removal by Bacillus sp. 3434BRRJ in case of wastewater was as effective as the synthetic medium. It is considered that Bacillus sp. 3434 BRRJ can be applied to the treatment of wastewater in order to biologically remove P from the wastewater on a large scale.

• 한국토양비료학회지
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• 제45권5호
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• pp.690-697
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• 2012

Approximately 67% of the total land area of the Korea is covered by forest. Eutrophication, defined as the enrichment of waters beyond natural levels, principally by the nutrient phosphorus (P), is a serious cause of concern at the present time. The contribution of forestry to P loading in catchment waters has not been intensively studied in Korea, but is potentially important because forests are often located in near-pristine environments. Phosphorus is retained by most mineral soils and, as a consequence, losses are usually negligible. However, it is much more mobile in organic soils where it can be relatively easily leached or lost through surface runoff, as these soils have a low capacity to retain free phosphate. This report has been prepared to study the influence of arable land used for paddy, upland, and forestry on water quality in the basin of Daechung reservoir.

• 산업기술연구
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• 제25권B호
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• pp.27-35
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• 2005

Non-point source pollution, which is found in soil, urban area, and agricultural area, is difficult to have its amount to be estimated. Moreover, it is hard to come up with a counterplan to cope with this pollutant. Hence, the watershed of Mandae-cheon located at the upstream of Soyang Lake was chosen as our site of study. We analyzed the relationship between precipitation level of each month and pollution load in the watershed by using statistical methods: measuring BOD, T-N and T-P - which are the causes of eutrophication - in the water; and analyzing the changes in water quality caused by precipitation level of nth.

• 한국농공학회지
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• 제42권2호
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• pp.63-70
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• 2000

The present study was carried out for 7-months (from October 1.1997 to April 30. 1998) at a rice cultivation area blocked from livestock farming, farmstead and industrial complex to investigate the runoff loading of nitrogen and phosphorus in a plot(5,000$m^2$) paddy field areas. The runoff loading of total-N, amminia-N nitrate-N and total-P were 12.96kg/ha, 5.42kg/ha, 1.52kg/ha and 1.41kg/ha , respectively. When the runoff loading of nutrients was compared by dissolved and adsorbed forms, about 66% of total-N by dissolved form and the rest 34% by adsorbed form were flowed into streams. But 56% of total-P by adsorbed form and the rest 44% by dissolved form were flowed into streams. The phosphrous compounds , which were flowed into streams by runoff sediments and then sedimented, keep exchanging with water at water body in undelivered condition. And it moves gradually into water layer. This process can cause eutrophication continually and repeatedly in water environment . So, a sound program is needed to reduce soil erosion from farmlands.

• Applied Biological Chemistry
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• 제43권2호
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• pp.124-129
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• 2000

농업유역에서 영양원소들은 시비 후 강우에 의해 지표 유출이 생기면 용해되거나 토사에 흡착된 상태로 하천에 유입되어 부영양화의 주요한 요인이 되고 있다. 농경지로부터의 영양염류 유실 정도를 평가하기 위해 경북 영천군 임고천 유역의 대표적 영농형태인 과수원 토양에 $14.3{\times}24.8\;m$면적의 유출 시험포를 설치하고 1999년 3월부터 11월 사이에 발생한 26개의 강우 사상에 대하여 지표 유출수량과 토양 유실량을 측정하였으며 이들과 함께 발생하는 질소와 인의 유실량을 조사하였다. 시험 포장에는 화학비료와 혼합유박비료로 질소와 인이 각각 112, 46kg/ha씩 처리되었다 조사 기간 동안 발생한 총 표면 유출수량은 $421.5\;m^3/ha$이었고 토양 유실량은 1,989kg/ha이었다. 유출수중의 T-N, $NO_3-N$, $NH_4-N$, T-P 및 $PO_4-P$의 농도는 각각 $4.7{\sim}171.0,\;0.1{\sim}188.0,\;0.13{\sim}3.36,\;0.58{\sim}4.99$ 및 $0.05{\sim}3.71\;mg/l$ 범위였다 강우에 의해 지표면으로 유실된 총 질소량은 16.39 kg/ha였으며 이중 질산태 질소와 암모늄태 질소가 각각 75%와 3%를 차지하였다. 인의 유실량은 총 16.39 kg/ha였으며 이 중에서 이온형태의 인이 47%였으며 토사와 함께 유실되는 인은 27% 정도였다. 질소와 인의 총 유실량은 각각 총 시비량의 9.5% 및 2.3%였다.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2019년도 정기학술대회 발표논문집
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• pp.134-134
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• 2019

Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

• 한국물환경학회지
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• 제40권2호
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• pp.67-78
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• 2024

The introduction of a significant amount of phosphorous into aquatic environments can lead to eutrophication, which can in turn result in algal blooms. For the effective management of watersheds and the prevention of water quality problems related to nonpoint organic matter (OM) sources, it is essential to pinpoint the predominant OM sources. Several potential OM sources were sampled from upper agricultural watersheds, such as fallen leaves, riparian reeds, riparian plants, paddy soil, field soil, riparian soil, cow manure, and swine manure. Stream samples were collected during two storm events, and the concentrations of dissolved organic carbon (DOC) and phosphorous (DOP) from these OM sources and stream samples were assessed. DOM indicators using fluorescence spectroscopy, including HIX, FI, BIX, and EEM-PARAFAC, were evaluated in terms of their relevance in discerning DOM sources during storm events. Representative DOM descriptors were chosen based on specific criteria, such as value ranges and pronounced differences between low and high-flow periods. Consequently, the spectral slope ratio (S_R) paired with fluorescence index (FI) using end-member mixing analysis (EMMA) proved to be suitable for estimating the contribution of organic carbon (OC). The contribution of each organic phosphorous (OP) in stream samples was determined using the phosphorous-to-carbon (P/C) ratio in conjunction with the OC contribution. Notably, OP derived from swine manure in stream samples was found to make the most dominant contribution, ranging from 61.3% to 94.2% (average 78.1% ± 12.7%). The results of this research offer valuable insights into the selection of suitable indicators to recognize various OM sources and highlight the main sources of OP in forested-agricultural watersheds.

• 한국토양비료학회지
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• 제31권2호
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• pp.162-169
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• 1998

젖소 90 마리, 사슴 35 마리를 노천에서 사육하는 유역면적 약 4ha의 농촌에서 빗물 유거수에 의한 축산분뇨 유출수가 하류에 있는 휴경답과 벼재배지에 유입될 때 빗물에 함유된 영양물질의 행방을 조사하여 논 생태계의 물질순환계에서 식생과 토양의 생태학적 기능을 평가하였다. 하루 56.4 mm의 비가 오는 날의 빗물 유거수중 $NH_4-N$ 함량은 $8.3mg\;{\ell}^{-1}$ 이었고, $P_2O_5$ 함량은 $1.8mg\;{\ell}^{-1}$ 이었다. 약 4 ha의 소수계에서 벼 재배 기간중 최상 위치의 휴경답으로 유입되는 빗물의 양은 20.900 Mg 였으며, 이 빗물 유거수에 함유되어 유입되는 질소의 양은 173 kg, 인산은 38 kg이었다. 축산분뇨 유출수가 휴경답과 벼 재배 포장을 통과한 후의 영양성분 감소율은 질소는 휴경답 50%, 1번답 84%, 2번답/3번답 90%, 4번답을 거친 논물은 92%가 감소하였고, 인산은 휴경답 50%, 1번답 91%, 2번답/3번답/4번답을 통과 후에는 95%가 감소하였다. 빗물 유거수에 의한 축산분뇨 유출수의 영양성분중에서 휴경답의 잡초에 의한 흡수와 토양내에 무기태 및 토양 유기물의 형태로 잔존하는 질소량은 29%이었고, 인산은 30%로서 논의 생태학적 순기능이 인정되었다.

• 한국지반신소재학회논문집
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• 제14권4호
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• pp.79-86
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• 2015

우리나라의 지형은 약 70% 이상이 산악지역으로 형성되어 있으며 평균 pH는 4 ~ 5로 산성화 정도가 심각한 수준이다. 현재 국내에는 약 1,000여개의 휴 폐광된 많은 금속광산이 오염 방지시설이나 처리시설이 갖춰지지 않은 채 중금속을 함유한 광미나 폐석이 장기간 환경 중에 노출되어 왔으며, 지속적인 관리 및 환경오염에 대한 모니터링이 미흡한 실정이다. 대부분의 휴 폐광산은 산림지역에 밀집하여 있어 경사지면으로 이루어진 곳이 많다. 경사지에서의 강우에 의한 토양유실은 작물의 생산성과 함께 수계의 부영양화 등에도 영향을 미치며 이로 인한 2차 오염원으로 발전할 수 있어 심각한 수준의 환경문제를 야기할 수 있다. 따라서 본 연구에서는 실제 산성화경사지와 유사한 조건의 라이시미터를 조성하고 과거 기 수행된 연구의 산출물인 폐자원을 활용한 중화제를 이용하여 중화처리를 실시한 후, 계절별 특성에 따라 인공강우를 살포하여 토양과 유출수의 pH 용탈에 따른 2차 환경오염 여부를 가늠하고 중화처리 후 식물식재 방안을 모색하고자 한다. 실험은 산성토양만을 충진한 대조군과 중화처리를 실시한 실험구 1, 중화처리 후 식물식재를 조성한 실험구 2로 구성하였다. 실험결과, 모든 계절에서 중화처리를 실시한 실험구 1, 2가 낮은 pH 용탈결과를 나타내었으며, 특히 실험구 2에서는 pH 용탈률이 가장 낮은 것으로 나타났다. 강우강도와 강우빈도 등 계절별 특성에 따른 pH 용탈은 큰 영향이 없는 것으로 나타났다.

• 한국환경농학회지
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• 제28권1호
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• pp.15-19
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• 2009

대기중으로 휘산되는 대부분의 암모니아는 농경지에서 시용하는 가축분뇨 퇴비와 질소비료에서 유래한다. 본 연구는 밭 토양에서 돈분 퇴비 시용방법에 따른 암모니아 휘산량을 소형원드터널 방법을 이용해서 정량적으로 평가하였다. 돈분 퇴비(20 Mg/ha) 표층살포(SA), 표층살포 후 즉시 경운(IRA), 표층 살포 3일 후 경운(RA-3d) 처리의 13일 동안 암모니아 휘산량은 각각 28.7, 8.7, 24.3 kg N/ha로 IRA 처리구는 SA 처리구에 비해 70% 저감효과를 가져왔다. 그리고 SA 처리구의 퇴비 처리 후 24시간 이내 휘산된 암모니아 양은 총 휘산량의 61%로 대부분의 암모니아는 시용 초기 짧은 시간 내에 휘산됨을 알 수 있었다. 석회와 퇴비 혼용시용 후 교반(L+C mix), 퇴비표층 살포 3일후 석회시용 교반(C+L3D), 석회시용 3일 후 퇴비시용 교반(L+C3D) 처리구의 22일 동안 총 암모니아 휘산량은 각각 40.1, 31.4, 27.7 kg/ha이었다. 따라서 가축분 퇴비 시용시 석회를 혼용하는 것은 피해야 하며, 만일 동일 작기내 시용이 불가피할 경우는 퇴비시용에 앞서 석회를 먼저 충분한 일수를 앞두고 시용하는 것이 암모니아 휘산량을 저감시킬 수 있다는 결론을 얻었다.