• 한국토양비료학회지
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• 제44권6호
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• pp.1286-1294
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• 2011

This paper reviews the future directions and perspectives on the soil environmental researches in the 21 century. Previously, the principal emphasis of soil environmental researches had put on the enhancement of food and fiber productions. Beside the basic function of soil, however, the societal needs on soil resources in the 21st century have demands for several environmental and social challenges, occurring regionally or globally. Typical global issues with which soil science should deal include food security with increasing agronomic production to meet the exploding world population growth, adaptation and mitigation of climate change, increase of the carbon sequestration, supply of the biomass and bioenergy, securing the water resource and quality, protection of environmental pollution, enhancing the biodiversity and ecosystem health, and developing the sustainable farming/cropping system that improve the use efficiency of water and agricultural resources. These challenges can be solved through the sustainable crop production intensification (SCPI) or plant welfare concept in which soil plays a key role in solving the abovementioned global issues. Through implementation of either concept, soil science can fulfill the goal of the modern agriculture which is the sustainable production of crops while maintaining or enhancing the ecosystem function, quality and health. Therefore, directions of the future soil environmental researches should lie on valuing soil as an ecosystem services, translating research across both temporal and spatial scales, sharing and using data already available for other purposes, incorporating existing and new technologies from other disciplines, collaborating across discipline, and translating soil research into information for stakeholders and end users. Through the outcomes of these approaches, soil can enhance the productivity from the same confined land, increase profitability, conserve natural resource, reduce the negative impact on environment, enhance human nutrition and health, and enhance natural capital and the flow of ecosystem services. Soil is the central dogma, final frontier and new engine for the era of sustainability development in the $21^{st}$ century and thus soil environmental researches should be carried according to this main theme.

• 한국지하수토양환경학회지:지하수토양환경
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• 제18권1호
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• pp.36-45
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• 2013

We analyzed natural radionuclides in 80 wells in volcanic rock areas and investigated environmental characteristics. Uranium and radon concentrations ranged from ND to $9.70{\mu}g/L$ (median value: 0.21) ${\mu}g/L$, 38~29,222 pCi/L (median value: 579), respectively. In case of gross-${\alpha}$, 26 samples exceeded MDA (minimum detectable activity, < 0.9 pCi/L) value and the activity values ranged from 1.05 to 8.06 pCi/L. The radionuclides concentrations did not exceed USEPA MCL (maximum contaminant level) value of Uranium ($30{\mu}g/L$) and gross-${\alpha}$ (15 pCi/L). But Rn concentrations in 4 samples exceeded USEPA AMCL (Alternative maximum contaminant level, 4,000 pci/L) and one of them showed a significantly higher value (29,222 pCi/L) than the others. The levels of uranium concentrations in volcanic rock aquifer regions were detected in order of andesite, miscellaneous volcanic rocks, rhyolite, basalt aquifer regions. Radon, however, was detected in order of miscellaneous volcanic rocks, rhyolite, andesite, basalt aquifer regions. The correlation coefficient between uranium and radon was r = 0.45, but we found that correlations of radionuclides with in-situ data or major ions were weak or no significant. The correlation coefficient between the depth of wells and uranium concentrations was a slightly higher than that of depth of wells and radons. Radionuclide concentrations in volcanic rock aquifers showed lower levels than those of other rock aquifers such as granite, metamorphic rock aquifers, etc. This result may imply difference of host rock's bearing-radioactive-mineral contents among rock types of aquifers.

• 분석과학
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• 제20권2호
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• pp.91-108
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• 2007

토양 중 PCBs 분석방법을 검토하기 위해 우리나라 토양오염공정시험방법 및 선진국의 분석방법을 비교 검토하고 결과를 근거로, 추출 및 전처리방법, 칼럼정제방법, 분석용 칼럼 조건, 기기분석 조건 및 정량방법을 검토하였다. 또한 검토된 방법에 따라 토양 중 PCBs 세부분석지침(안)을 제시하고, 제시된 세부분석지침(안)에 의해 PCBs 제품으로 오염시킨 토양 5건 시료와 토지이용도별 및 오염원별 23건의 시료를 전처리하여 분석하였다. 기체크로마토그래피/전자포획검출법(GC/ECD)에 의한 토지이용도별 및 오염원별 PCBs 분석결과는 모든 시료에서 피크패턴(GC/ECD)을 확인 할 수 없었으나, 기체크로마토그래피/질량분석법(GC/MS)에 의한 개별이성체 정량결과는 $0.002{\sim}0.487{\mu}g/kg$ 범위로 검출되었다.

• 한국토양비료학회지
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• 제49권2호
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• pp.200-207
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• 2016

To add new groundwater standard, 7 candidate materials (copper, zinc, selenium, manganese, iron, chromium, aluminum) were calculated by CROWN (Chemical Ranking Of groundwater pollutaNts). Copper and zinc were selected as groundwater candidates through the process and monitored total 430 samples for 2 years with 113 groundwater sampling sites. In this study, geological distribution characteristics (igneous rock, metamorphic rock, sedimentary rock) of copper and zinc were evaluated and the geological background levels obtained by a cumulative probability distribution and pre-selection methods were compared. In the results, the highest average concentrations of the copper and zinc were observed both in the igneous rock. The detection concentration ranges of copper and zinc in 430 groundwater samples were $0.002{\sim}0.931mg\;L^{-1}$, and $0.002{\sim}32.293mg\;L^{-1}$, respectively. In addition, detection concentration ranges of copper and zinc were $0.002{\sim}0.931mg\;L^{-1}$, $0.002{\sim}32.293mg\;L^{-1}$ in the igneous rock, $0.002{\sim}0.134mg\;L^{-1}$, $0.004{\sim}7.038mg\;L^{-1}$ in the metamorphic rock and $0.002{\sim}0.008mg\;L^{-1}$, $0.003{\sim}3.948mg\;L^{-1}$ in the sedimentary rock, respectively. As a result of the background concentrations with two methods, zinc concentrations with the pre-selected method are comparatively higher than that of the others with the cumulative distribution.

• 한국지하수토양환경학회지:지하수토양환경
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• 제22권5호
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• pp.71-81
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• 2017

The hydrogeochemical characteristics of groundwater in the small waterworks are examined with 81 groundwater samples in Ulju region, Ulsan. The pH ranged in 6.3-8.2 and did not exceed the drinking water standards. Electrical conductivity ranged from $50{\mu}S/cm$ to $1,719{\mu}S/cm$. It indicated that the electrical conductivities in groundwaters at the study area are relatively low, compared with other groundwaters in Ulsan area. The calcium concentrations in groundwaters ranged from 3.55 to 113.01 mg/L, and sodium concentrations ranged from 2.02 to 65.50 mg/L. Nitrate concentrations ranged from 0 to 100.56 mg/L and potassium concentrations ranged from N.D (not detected) to 2.50 mg/L. Major cations and anions were mainly derived from the water-rock interaction involving feldspar, gypsum and calcite. The groundwaters were mainly the $Ca-(Na)-HCO_3$ type, classified as the early stage of groundwater evolutions. The correlation between electrical conductivities and Ca concentrations in groundwaters was relatively high ($R^2=0.74$). In the correlations between ions, the correlation coefficient between $SO_4$ and Ca was 0.65 and between Mg and $HCO_3$ was 0.65.

• 한국지하수토양환경학회지:지하수토양환경
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• 제21권6호
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• pp.169-178
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• 2016

The Standards, Measurement and Testing Programme (SM&T-formerly BCR) extraction procedure was applied to fractionate Cr, Cu, Ni, Pb and Zn in 23 top soil samples into: (i) exchangeable phase; (ii) reducible phase; (iii) oxidisable(sulfides and organics bound) phase; and (iv) residual phase. Fractions of Cr and Ni were in the order of residual > oxidisable > reducible > exchangeable phase. The oxidisable phase was identified as dominant for Cu and Pb. Zn had the highest ratio of exchangeable phase in comparision to the other metals. The bioavailability and mobility were assessed to be the greatest for Zn, followed by a decreasing order of Pb, Cu, Ni and Cr. All metal average concentrations in topsoil samples was higher in industrial sites than in agricultural sites. Our results revealed higher concentrations in topsoil samples (0~15 cm) than in sub soils (15~30 cm, 30~60 cm) for most metals at six sites (No. 5, 6, 17, 19, 20, 23). The fractions of exchangeable, reducible ad oxidisable phases showed relatively high correlation with soil pH, Fe/Mn oxide concentrations and organic matter contents, respectively.

• 한국토양비료학회지
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• 제48권5호
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• pp.332-339
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• 2015

The objective of this study was to evaluate the effectiveness of different biochars on the removal of heavy metals from aqueous media. The experiment was carried out in aqueous solutions containing $200mg\;CdL^{-1}$ or $200mg\;PbL^{-1}$ using two different biochars derived from soybean stover and orange peel (20 mg Cd or $Pbg^{-1}$ biochar). After shaking for 24 hours, biochars were filtered out, and Cd and Pb in the filtrate were analyzed by flame atomic absorption spectrophotometer (FAAS). In order to provide information regarding metal binding strength on biochars, sequential extraction was performed by modified SM&T (formerly BCR). The results showed that 70~100% of initially added Cd and Pb was adsorbed on biochars and removed from aqueous solution. The removal rate of Pb (95%, 100%) was higher than that of Cd (70%, 91%). In the case of Cd, orange peel derived biochar (91%) showed higher adsorption rate than soybean stover derived biochar (70%). Cd was adsorbed on the biochar mainly in exchangeable and carbonates fraction (1st phase). In contrast, Pb was adsorbed on it mainly in the form of Fe-Mn oxides and residual fraction (2nd and 4th phase). The existence of Cd and Pb as a form of surface-precipitated complex was also observed on the surfaces of biochars detected by field emission scanning electron microscope (FESEM) and energy dispersive X-ray spectrometer (EDAX).

• 한국지하수토양환경학회지:지하수토양환경
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• 제22권6호
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• pp.22-28
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• 2017

The accuracy of analytical results in response to the use of different additives ($NH_4Cl$, KCl, $LaCl_3$) and oxidant gases was evaluated and compared by using Atomic Absorption Spectrometry (AAS). Identification of spectroscopic interferences and possible improvements in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) analysis were also discussed. The average accuracies of total chromium using Certified Reference Materials (CRMs) were found to be 72.1~94.2% in air/acetylene flame condition by AAS, and they were improved to 100.5~110.5% when the oxidants was changed to nitrous oxide rather than adding the additives. The field samples showed similar trends to CRMs, but chromium concentrations were highly variable depending on analytical conditions. The average accuracies using CRMs were estimated to be 89.3~166.1% by ICP-AES, and improved to below 121.7% after eliminating iron interference. Field samples with low chromium and high iron concentration were measured to be > 30% lower in total chromium concentrations by ICP-AES than AAS in nitrous oxide/acetylene flame. Total chromium concentrations in soil could be analyzed with better accuracy under nitrous oxide/acetylene flame by AAS because it was more effective to increase the temperature of the flame than to eliminate the chemical interference for maximizing atomization of chromium. When using ICP-AES, interference substances, total chromium levels, and analytical conditions should be also considered.

• 한국지하수토양환경학회지:지하수토양환경
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• 제17권5호
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• pp.20-30
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• 2012

In case of analyzing PAHs (EPA 16 compounds) in oil-contaminated soils, the lump of peaks may occur because of the aliphatic and polar compounds in oil. This phenomenon is due to the lower accuracy of the analysis. To solve this problem, evaluation of application of silicagel-alumina multi-layer fraction was performed using standard substances and oil-contaminated soils. As a result of application of silicagel-alumina multi-layer fraction cleanup method using standard substances, recovery rates of surrogate standards (5 compounds including Naphthalene-d8) were 83~100% and those of target standards were 75~129%. These were to meet the target values (60~130%) in this study. When used 4% water-silicagel column analyze PAHs in oil-contaminated soils, Some problems were generated for quantitative analysis of PAHs; concentration of PAHs was underestimated due to an upward baseline of internal standard (recovery rate: less than 60%) and overestimated by the lump of peaks which were not purified (the biggest recovery rate: more than 400%). On the other hand, in case of silicagel-alumina multi-layer fraction cleanup method, recovery rate of surrogate standards were 61~101.6%. Therefore this cleanup method was considered a valid method to improve accuracy of analysis of PAHs in oil-contaminated soils.

• Corrosion Science and Technology
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• 제21권5호
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• pp.372-380
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• 2022

The external corrosion control of buried pipes can be achieved by a combination of coatings and cathodic protection to maximize effectiveness. One of the factors affecting cathodic protection is the environmental soil conditions. Because soil is a kind of electrolyte, the environmental conditions of soil may be changed by the atmospheric environment. Therefore, in this study, changes in environmental soil factors by atmospheric environmental factors were monitored. In cathodic protection, on-potential and off-potential were measured from December 2021 to July 2022. The effects of external environmental factors and soil environmental factors on cathodic protection were analyzed. Changes in outdoor temperature affected soil temperature, and soil conductivity had a proportional relationship with soil humidity, but outdoor humidity and precipitation did not significantly affect humidity and conductivity of the soil. In contrast, in cathodic protection, the on-potential was affected by temperature, humidity, the conductivity of the soil, and the anode used, but the off-potential was little affected by these factors.