• Title/Summary/Keyword: Soil column test

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Analytical method of polycyclic aromatic hydrocarbons (PAHs) in oil contaminated soils (유류 오염토양 중 다환방향족탄화수소류(PAHs) 분석방법 고찰)

  • Yoon, Jeong Ki;Park, Jin Soo;Shin, Sun Kyoung;Kim, Tae Seung
    • Analytical Science and Technology
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    • v.21 no.4
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    • pp.296-303
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    • 2008
  • This study was performed to establish an analytical method of PAHs in oil contaminated soil of these methods by evaluating the PAHs test methods from US EPA and ISO etc. The application to domestic contaminated soil leads to a conclusion that alumina column is a more effective clean-up procedure for oil contaminated soil rather than the others. It is proposed with the new analytical method of 12 PAHs except for more volatile compounds (naphthalene, acenaphthylene, acenaphthene, fluorene). The recovery of PAHs in this method ranged 67~107%. The oil contaminated soil samples were analyzed using GC/MSD. The concentration of PAHs ranged $78.68{\sim}275.57{\mu}g/kg$. The predominated compounds were fluoranthene, pyrene and chrysene attributing about 70% of total concentration. The level of Benzo[a]pyrene ranged $1.76{\sim}24.65{\mu}g/kg$.

Studies on Behavior Characteristics of Retrofitted Cut-and-Cover Underground Station Using Centrifuge Test Results (원심모형실험을 이용한 내진 보강된 개착식 지하역사의 거동특성 연구)

  • Kim, Jin-Ho;Yi, Na-Hyun;Lee, Hoo-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.2
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    • pp.24-33
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    • 2017
  • Domestic urban railway underground station structures, which were built in the 1970s ad 1980s, had been constructed as Cut-and-Cover construction system without seismic design. Because the trends of earthquake occurrence is constantly increasing all over the world as well as the Korean Peninsula, massive human casualties and severe properties and structures damage might be occurred in an non-retrofitted underground station during an earthquake above a certain scale. Therefore, to evaluate the retrofit effect and soil-structure interaction of seismic retrofitted underground station, a centrifugal shaking table test with enhanced stiffness on its structural main member are carried out on 1/60 scaled model using the Kobe and Northridge earthquakes. The seismic retrofitted members, which are columns, side walls, and slabs, are evaluated to comparing with existing non-retrofitted centrifuge test results Also, to simulate the scaled ground using variation of shear velocity according to site conditions such as ground depth and density, resonant column test is performed. From the test results, the relative displacement behavior between ground and structures shows comparatively similar in ground, but is increased on ground surface. The seismic retrofit effects were measured using relative displacements and moment behavior of column and side walls rather than slabs. Additionally, earthquake wave can be used to main design factor due to large structural deformation on Kobe earthquake wave than Norhridge earthquake wave.

Study of Surfactant Enhanced Remediation Methods for Organic Pollutant(NAPL) Distributed over the Heterogeneous Medium (계면활성제를 이용한 불균질 매질에서 유기오염물(NAPL)의 정화효율에 관한 실험)

  • 서형기;이민희;정상용
    • Journal of Soil and Groundwater Environment
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    • v.6 no.4
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    • pp.51-59
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    • 2001
  • Column and box tests were performed to investigate the removal efficiency of NAPL using the surfactant enhanced flushing In heterogeneous medium. Homogeneous Ottawa sand and heterogeneous soil were used to verify the increase of remediation efficiency for the surfactant enhanced flushing in column test. Box tests with two different heterogeneous sub-structure were performed to quantify the capability of the surfactant enhanced flushing as a remediation method to remove NAPL from the heterogeneous medium. Two different grain size sand layers were repeated in the box to simulate the heterogeneous layer formation and the modified fault structure was built to simulate the fault system in the box. O-xylene as a LNAPL and PCE as a DNAPL were used and oleamide as a non-ionic surfactant. The maximum NAPL effluent concentration with 1% oleamide flushing in the homogeneous column test increased about 460 times compared to that with only water flushing and about 250 times increased in the real soil column test. In heterogeneous medium, the maximum effluent concentration increased about 150 times in 1% oleamide flushing and most of NAPL were removed from the box within 8 pore volume flushing, suggesting that the removal efficiency increased very much compared to in only water flushing. Results investigated the capability of the surfactant enhanced remediation method to remove NAPL even in heterogeneous medium.

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Evaluation of Oil Infiltration Behavior in Porous Media Using Dielectric Response (유전율에 의한 지반 매질내 유류침투거동 분석)

  • Kim Man-Il;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.15 no.1
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    • pp.29-39
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    • 2005
  • For detecting a ground contamination survey, soil sampling method have been used a drilling or coring technique in general. However these methods are very difficult to systematically real-time monitoring of variation of contamination degree in field. ]'n this research frequency Domain Reflectometry (FDR) system was suggested and carried out to experimental approaches for determination of oil contamination on surface and underground. Experimental method using FDR method was discussed with feasibility of measurement in the laboratory column test. It is determined to degree of oil contamination due to response of dielectric constant re-lated with volumetric water content(θ/sub w/) and volumetric oil content( θ/sub al/ ) of saturated and unsaturated soil media. And physical properties such as effective porosity and oil residual ratio of saturated soil media were also measured through real-time monitoring works using installed FDR measurement sensors, which are defected characteristics of oil movement in the saturated soil media under the soil column tests. In the results of these experiments, a range of effective porosity was estimated to about 0.35 compared with initial porosity 0.40 of manufactured saturated soil media, which is also calculated to about 87.5% to the ratio of initial porosity to effective porosity. Finally oil residual ratio which is compared with volumetric water content and volumetric oil content was calculated about 62.5%.

Purification and Characteriztion of an Antifungal Antibiotic from Bacillus megaterium KL 39, a Biocontrol Agent of Red-Papper Phytophtora Blight Disease. (고추역병균 Phytophthora capsici를 방제하는 길항균주 Bacillus megaterium KL39의 선발과 길항물질)

  • 정희경;김상달
    • Microbiology and Biotechnology Letters
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    • v.31 no.3
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    • pp.235-241
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    • 2003
  • For the biological control of Phytophthora blight of red-pepper caused by Phytophthora capsici, an antibiotic-producing plant growth promoting rhizobacteria (PGPR) Bacillus sp. KL 39 was selected from a local soil of Kyongbuk, Korea. The strain KL 39 was identified as Bacillus megaterium by various cultural, biochemical test and API and Microlog system. B. megaterium KL 39 could produce the highest antifungal antibiotic after 40 h of incubation under the optimal medium which was 0.4% fructose, 0.3% yeast extract, and 5 mM KCl at 30 C with initial pH 8.0. The antifungal antibiotic KL 39 was purified by Diaion HP-20 column, silica gel column, Sephadex LH-20 column, and HPLC. Its RF value was confirmed 0.32 by thin-layer chromatography with Ethanol:Ammonia:Water = 8:1:1. The crude antibiotic KL39 was active against a broad range of plant pathogenic fungi, Rhizoctonia solani, Pyricularia oryzae, Monilinia fructicola, Botrytis cinenea, Alteranria kikuchiana, Fusarium oxysporum and Fusarium solani. The purified antifungal antibiotic KL39 had a powerful biocontrol activity against red-pepper phytophthora blight disease with in vivo pot test as well as the strain B. megaterium KL 39.

The Synthetic Study of Environmental Contamination at the Seokdae Municipal Waste Landfill in Pusan (부산 석대 생활폐기물 매립장의 환경오염에 대한 종합적 연구)

  • 김병우;정상용;이민희;이병헌
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.98-103
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    • 2001
  • In order to understand the characteristics of leachate at the Seokdae municipal waste landfill in the Pusan city, the correlation between leachate pollution loading and volume of gas production. concentration of gas and subsidence of ground, the characteristical methos, geochemical analyses and laboratory column tests using samples of gases, leachate and surface soil of Seokdae waste landfill area. Through the analysis of water balance, leachate flow rate and pollution loading were estimated. Geistatistical analysis of four gas components ( $O_2$, C $H_4$, $H_2$S and CO) shows the possibility of ground subsidence around the group of a site with high concentration of gas. From geochemical analyses of leachate, EC and Total-Alkalinity of ground subsidence around the group of a site with high concentration of gas. From geochemical analysis of leachate, Ec and Total-Alkalinity were increased, and Cl, Cr, Mn, Cu, Zn, Cd and Pb were decreassed comparing to the part, and the type of water quality was Na-HC $O_3$ in trilinear diagram. It shows that biodecomposition of municipal wastes continues actively. From the analysis of water balance, the total leachate flow rate is about 465.11㎥/day and pure pollution loading of Cl, Mn and Fe are estimated to 223.8kg/day, 0.2kg/day, 0.3kg/day, respectively. The laboratory column test of residual soil and landfill soil shows 0.206cm and 0.019cm for linear velocity(equation omitted), 0.234 $\textrm{cm}^2$/min and 0.018$\textrm{cm}^2$/min for diffusion coefficient ( $D_{ι}$), and 1.136cm and 0.095cm longitudinal dispersion index ($\alpha$$_{ι}$), respective]y. It demonstrates that the delay time of contamination for residual soil is shorter than that of landfill soil.

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Estimation of Shear Moduli Degradation Characteristics from Pressuremeter Tests (프레셔미터 시험을 이용한 전단탄성계수 감쇠 특성 평가)

  • Kwon, Hyung Min;Chung, Choong Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.3C
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    • pp.105-113
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    • 2009
  • Pressuremeter test estimates deformational properties of soil from the relationship between applied pressure and the displacement of cavity wall, and the results reflect the in-situ stress condition and the structure of soil particles. This study suggests the overall process of test and analysis for the evaluation of nonlinear degradation characteristics of shear moduli, based on the reloading curve of pressuremeter test. The method estimates the maximum shear modulus, taking into account the difference between the stress states around the probe in reloading and that of the in-situ state, and then combines the degradation characteristics of shear moduli taken from reloading curve. This procedure derives the shear moduli in overall strain range. Pressuremeter tests were carried out in various ground conditions using large calibration chamber, together with various reference tests. Shear moduli taken from pressuremeter tests were compared with bender element test and resonant column test results.

Dynamic Shear Modulus of Compacted Clayey Soil (다짐점성토(粘性土)의 동적전단탄성계수(動的剪斷彈性係數))

  • Kang, Byung Hee
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.3 no.2
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    • pp.109-117
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    • 1983
  • Dynamic shear modulus of the compacted clayey soil was determined by the resonant column test to study the parametric effects of confining pressure, shear strain amplitude, molding water content, compaction energy, void ratio and the degree of saturation. The effect of each of these parameters on the dynamic shear modulus found to be significant and can be explained in terms of the changes in soil by compaction. Dynamic shear modulus of the compacted soil is increased significantly by compaction and compaction at the dry side of the optimum moisture content is much more effective. It is also found that the dynamic shear modulus showes a good correlation to the static shear strength of the compacted soil. Therefore the dynamic shear modulus of the compacted soil for a certain confining pressure may be obtained ea8i1y from the unconfined compression strength.

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Purification of Materials Produced by Amylocolatosis sp. and Anticancer Effect in Oral Cancer Model (Amylocolatosis sp.가 생산하는 항암물질의 정제 및 구강암 모델에 미치는 항암 효과)

  • Kim, Jung;Park, Young-Min;Lim, Do-Seon
    • Journal of dental hygiene science
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    • v.3 no.1
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    • pp.11-14
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    • 2003
  • A methylotrophic Actinomycetes strain, which produce the anti-oral cancer activity compound, was isolated from soil and estimated as Amylocolatosis sp. based on taxonomic studies. A methanol didn't have influence on the production of the anticancer compounds. These compound were isolated by ethylacetate extract, silica gel column chromatography, sephadex LH-20 column and reverse phase HPLC. The compounds were very stable under heat ($121^{\circ}C$), acid(pH 2.0) and alkali(pH 11.0) treatment. The cytotoxic effect of isolated anticancer compounds on various cancer cell lines such as A549, SNU-1, KB, L1210, and Sarcoma 180 was investigated by MTT assay method. And these produced compounds also showed the broad antimicrobial spectrum to test strains such as bacteria and yeast.

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The Interference of Organic Matter in the Characterization of Aquifers Contaminated with LNAPLs by Partitioning Tracer Method (LNAPLs 오염 지반에 분배성 추적자 시험법 적용 시 유기물질의 영향에 관한 연구)

  • Khan, Sherin Momand;Rhee, Sung-Su;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.24 no.9
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    • pp.13-21
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    • 2008
  • Partitioning tracer method is a useful tool to characterize large domains of the aquifers contaminated with light nonaqueous phase liquids (LNAPLs). Sorption of the partitioning tracers to the organic matter content of soil can potentially influence the efficacy of partitioning tracer method. LNAPL-water partitioning coefficients of tracers ($K_{nw}$), measured by static method, showed linear relationship. Sorption isotherm tests were conducted to evaluate the sorption capacity of the soils packed in the columns and the results were appropriately represented by Freundlich sorption isotherm. The sorption of tracers proportionally increased with the increase of the organic matter content of the soil. Laboratory experiments were conducted in four columns each packed with soils of different organic matter contents to determine the potential interference effects of sorption to soil organic matter content and correction factors for the errors in estimation of LNAPLs by partitioning tracer method. Though there were no contaminants added, breakthrough curves from columns packed with mixture of Jumunjin standard sand and organic matter showed separation of tracers. Columns were then contaminated to residual saturation with kerosene and breakthrough curves were obtained. The results show that sorption of tracers to soil organic matter leads to an increase in the retardation factor (R) and hence, to an overestimation of the saturation of LNAPLs. A relation between the percentage of organic matter content and the corresponding percentage error in the estimation of NAPLs has been developed.