• Title/Summary/Keyword: Soil Contaminants

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In-situ Stabilization of Hydrophobic Organic Contaminants in Sediment by Activated Carbon Amendment: Working Principles (활성탄 주입을 통한 퇴적물 내 소수성 유기오염물질 원위치 안정화 기술: 작동 원리)

  • LEE, Hyeonmin;JUNG, Jihyeun;CHOI, Yongju
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.1-16
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    • 2022
  • In-situ activated carbon (AC) amendment is a promising remediation technique for the treatment of sediment impacted by hydrophobic organic contaminants (HOCs). Since its first proposal in the early 2000s, the remediation technique has quickly gained acceptance as a feasible alternative among the scientific and engineering communities in the United States and northern Europe. This review paper aims to provide an overview on in-situ AC amendment for the treatment of HOC-impacted sediment with a major focus on its working principles. We began with an introduction on the practical and scientific background that led to the proposal of this remediation technique. Then, we described how the remediation technique works in a mechanistic sense, along with discussion on two modes of implementation, mechanical mixing and thin-layer capping, that are distinct from each other. We also discussed key considerations involved in establishing a remedial goal and performing post-implementation monitoring when this technique is field-applied. We concluded with future works necessary to adopt and further develop this innovative sediment remediation technique to ongoing and future sediment contamination concerns in Korea.

A Case Study of Site Investigation on XX Gas Station (국내토양오염 유발시설별 오염현황 조사 - XX 인근주유소 오염현황조사 -)

  • 김무훈;강순기;곽무영
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.21-30
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    • 1998
  • The purpose of this study is to assess contaminant transfer and environmental impacts to the surroundings by inadequate control of USTs. Several methodologies can be used to approach for the site assessment depending on the appearance of contaminants on the site and their types. In this case study, randomized and/or triangle matrix techniques were used. As a result, the composition of materials in tank station were appeared in several state. From 1 to 1.5m depth, the soil was composed of reclaimed soils. And 1.8-3.5m depth, silty sand was appeared and about 4m, weathered soil was appeared. Based on the preliminary and actual site investigation by DPT methodologies on the width and depth of the site with analysis of BTEX and TPH, the contamination was found in this tank station and already distributed near areas. Finally, it was found that the hydroflow differences during the season affects the area and depth of contamination.

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Review of Evaluation Methods and Soil Quality Factors for Agriculture Soils (농경지 토양의 토질요소와 평가 방법의 검토)

  • Chung, Doug Young;Lee, Kyo Suk
    • Korean Journal of Agricultural Science
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    • v.32 no.2
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    • pp.243-253
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    • 2005
  • In agricultural ecosystem, soils which play important roles of storage and cycling of substances become a crtitical social problem due to rapid increase of contaminants with respect to our health. Soil as productivity should be interpreted as soil quality, that is important criteria in maintaining sustainable agriculture for production of safe food. Therefore, it needs to set the criteria of soil quality by considering environmental factors including relevant parameters which are involved in soil quality soil health because soils are widely distributed and have various characteristics such as physical, chemical, and biological propevties. Therefore, it requires intensive investigation of evaluation methods and development of related parameters for environmentally sound agriculture and safe soil management.

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Distribution Characteristics of Environmental Contaminant at Soil in an Industrial Complex Area (공단지역 토양 중 환경오염물질 농도 분포 특성)

  • Jung, Jong-Hyeon;Cho, Sang-Won;Lim, Hyun-Sul
    • Clean Technology
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    • v.18 no.2
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    • pp.200-208
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    • 2012
  • This study was performed to prevent the health damage of environmental contaminants in Industrial Complex Area. And, this study aimed to identify the concentration levels and distribution characteristics of environmental contaminants and Polycyclic Aromatic Hydrocarbons (PAHs) at soil in Industrial Complex Area and control area. The concentration of the soil pollution standard such as the heavy metals in the soil, VOCs, PAHs, and PCB were measured and analyzed using the soil specimens in the Industrial Complex Area and control area. Soil specimens from the Industrial Complex Area (the direct exposure area) and the control area were surveyed. Songdo-dong, Haedo-dong and Jechul-dong, which are in the direct exposure area and near the emission source, showed relatively high concentrations of contaminant materials when compared with Jangki-myeon, which is far off and in the control area. The concentration of zinc was 20.8-58.9% of the level of concern (300 mg/kg) in the 1st region, which is a relatively high concentration. The concentration of fluoride was under the standard in every region, but it was about 74% of the level of concern (400 mg/kg) in the 1st region. It is recommended that controlling fluoride emissions is necessary. Levels of organic phosphate, phenol, and VOCs like benzene, toluene, ethylbenzene and xylene were under the detection limit of the analysis instruments. The concentration of TPH was high in Songdo-dong. The concentration of contaminants in Jechul-dong was high. In addition, it was observed that the level of soil contamination changed depending on the distance from the emission source. The concentration of PAH compounds in the soil was 18.71-1744.59 ng/g, and the concentration of six potential cancer-causing PAH materials was 6.54-695.94 ng/g. The highest concentration was in Songdo-dong. The PAH concentration in the direct exposure area near the complex was relatively high compared to the indirect exposure area.

Role of Arbuscular Mycorrhizal Fungi in Phytoremediation of Soil Rhizosphere Spiked with Poly Aromatic Hydrocarbons

  • Gamal, H. Rabie
    • Mycobiology
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    • v.33 no.1
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    • pp.41-50
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    • 2005
  • Results from an innovative approach to improve remediation in the rhizosphere by encouraging healthy plant growth and thus enhancing microbial activity are reported. The effect of arbuscular mycorrhizal fungi (Am) on remediation efficacy of wheat, mungbean and eggplant grown in soil spiked with polyaromatic hydrocarbons (PAH) was assessed in a pot experiment. The results of this study showed that Am inoculation enhanced dissipation amount of PAHs in planted soil, plant uptake PAHs, dissipation amount of PAHs in planted versus unplanted spiked soil and loss of PAHs by the plant-promoted biodegradation. A number of parameters were monitored including plant shoot and root dry weight, plant tissue water content, plant chlorophyll, root lipid content, oxido-reductase enzyme activities in plant and soil rhizosphere and total microbial count in the rhizospheric soil. The observed physiological data indicate that plant growth and tolerance increased with Am, but reduced by PAH. This was reflected by levels of mycorrhizal root colonization which were higher for mungbean, moderate for wheat and low for eggplant. Levels of Am colonization increased on mungbean > wheat > eggplant. This is consistent with the efficacy of plant in dissipation of PAHs in spiked soil. Highly significant positive correlations were shown between of arbuscular formation in root segments (A)) and plant water content, root lipids, peroxidase, catalase polyphenol oxidase and total microbial count in soil rhizosphere as well as PAH dissipation in spiked soil. As consequence of the treatment with Am, the plants provide a greater sink for the contaminants since they are better able to survive and grow.

A study on the removal of heavy metals from soils using electrokinetic soil processing and ion exchange membrane (전기장과 이온교환막을 이용한 토양에서의 중금속 제거에 대한 연구)

  • 김순오
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.43-51
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    • 1999
  • In order to remediate hazardous waste site, a process of electrokinetically purging chemicals from saturated soil is examined by laboratory experiments. Electrokinetic soil remediation is one of the most promising soil decontamination processes that habe igh removal efficiency and time-effectiveness in low-permeability soils such as clay. Being combined with several mechanisms-electromigration, elec troosmosis, diffusion and electrolysis of water, electrokinetic soil processing can remove non-polar organics as well as ionic contaminants. The objectives of this study are; 1) the exploration of the feasibility of electrokinetic soil processing on the removal of heavy metals, 2) the investigation of applicability to the tailing-soils in aban doned mining area, 3) the examination of effects of soil pH and conductivity on the transport phenomena of elements in soils, and 4) the investigation of the applicability of the ionexchange membrance to the efficient collection of heavy metals removed from contaminated soils. With the result of this study, it is suggested that the removal efficiency is significantly influenced by applied voltage & current, type of purging solutions, soil pH, permeability and zeta potentials of soil. Although further study should be needed, it is possible to collect removed heavy metals with ion-exchange membrance in cathode compartment.

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Migration of calcium hydroxide compounds in construction waste soil

  • Shin, Eunchul;Kang, Jeongku
    • Advances in environmental research
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    • v.4 no.3
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    • pp.183-196
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    • 2015
  • Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.

Aeration Factor Used To Design The Container Type of Biopile Systems for Small-Scale Petroleum-Contaminated Soil Projects

  • Jung, Hyun-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.316-319
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    • 2011
  • Biopiles which offer the potential for cost-effective treatment of contaminated soils are above-ground, engineered systems that use oxygen to stimulate the growth and reproduction of aerobic bacteria for degradation of the petroleum constituents adsorbed to soil in excavated soils. This technology involves heaping contaminated soils into piles and stimulating aerobic microbial activity within the soils through the aeration and/or addition of minerals, nutrients, and moisture. Inside the biopile, microbially mediated reactions by blowing or extracting air through the pipes can enhance degradation of the organic contaminants. The influence of a aeration system on the biopile performance was investigated. Air pressure made to compare the efficiency of suction in the pipes showed that there were slightly significant difference between the two piles in the total amount of TPH biodegradation. The normalised degradation rate was, however, considerably higher in the aeration system than in the normal system without aeration, suggesting that the vertical venting method may have improved the efficiency of the biological reactions in the pile.

Characterization of landfarming for bioremediation of petroleum-contaminated soil in Korea (유류오염토양의 생물학적 복원을 위한 국내 토양경작기술의 적용 특성)

  • Lee Kwang-Pyo;Lee Cheol-Hyo
    • 한국생물공학회:학술대회논문집
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    • 2004.07a
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    • pp.107-125
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    • 2004
  • A bioremediation of petroleum-contaminated soil in Korea was evaluated for the optimization of enhanced biodegradation and the minimization of effects of seasonal variations, The short-term bioremediation in combination of biopile pretreatment and landfarming was performed by lowering contaminated levels and overcoming the inhibiting factors in the rainy and winter seasons. A microbial density was maintained with indigenous microbial addition for bioaugmentation and with fertilizers for biostimulation. A lesser volatile and biodegradable fraction due to their abiotic removals following the biopile pretreatment was effectively removed by the laterally applied landfarming. The optimal temperature in greenhouse was maintained by buffering of the soil temperature even with slight decreases in removal rates during the winter and extensive leaching of nutrients and contaminants was restricted with adjusting the water contents during the Korean rainy season. Although the tilling process was effective for biodegradation with aeration only, the simultaneous treatment due to apparent mixing of nutrients and microbes more favorably degraded the petroleum than the sequential treatment.

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Chemical Remediation and Recirculation Technologies of Wastewater from Metal-Contaminated Soil Washing (금속오염(金屬汚染) 토양세척(土壤洗滌) 폐수(廢水)의 화학적(化學的) 처리(處理)와 재순환(再循環) 기술(技術))

  • Lim, Mi-Hee;Abn, Ji-Whan
    • Resources Recycling
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    • v.20 no.3
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    • pp.28-39
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    • 2011
  • This review investigated theoretical principals and practical application examples on recirculation system of soil washing-wastewater treatment-treated water recycling. As for technologies which have attempted to remediating metals-contaminated soil in and around country, there are reactive barriers, encapsulation, solidification/stabilization, soil washing, and phytoremediation. Among those, in particular, this review covers soil washing technology which physicochemically removes contaminants from soils. The major drawbacks of this technology are to generate a large amount of wastewater which contains contaminants complexed with ligands of washing solution and needs additional treatment process. To solve these problems, many chemical treatment methods have been developed as follows: precipitation/coprecipitation, membrane filtration, adsorption treatment, ion exchange, and electrokinetic treatment. In the last part of the review, recent research and field application cases on soil washing wastewater treatment and recycling were introduced. Based on these integrated technologies, it could be achieved to solve the problem of soil washing wastewater and to enhance cost effective process by reducing total water resources use in soil washing process.