Objectives In this study, we investigated the influence of ionic strength and natural organic matter (NOM) on aggregation and soil adsorption of citrate-coated silver nanoparticles (AgNPs). Methods Time-resolved dynamic light scattering measurements and batch adsorption experiments were used to study their aggregation and soil adsorption behaviors, respectively. Results The aggregation rate of AgNPs increased with increasing ionic strength and decreasing NOM concentration. At higher ionic strength, the AgNPs were unstable, and thus tended to be adsorbed to the soil, while increased NOM concentration hindered soil adsorption. To understand the varying behaviors of AgNPs depending on the environmental factors, particle zeta potentials were also measured as a function of ionic strength and NOM concentration. The magnitude of particle zeta potential became more negative with decreasing ionic strength and increasing NOM concentration. These results imply that the aggregation and soil adsorption behavior of AgNPs were mainly controlled by electrical double-layer repulsion consistent with the Derjaguin-Landau-Verwey-Overbeek theory. Conclusions This study found that the aggregation and soil adsorption behavior of AgNPs are closely associated with environmental factors such as ionic strength and NOM and suggested that assessing the environmental fate and transport of nanoparticles requires a thorough understanding of particle-particle interaction mechanisms.
In order to determine the effects of bedrock, organic matter, calcium and iron oxide on the soil aggregation, this research has performed with soils from bedrock regions of Limestone, Granite and Granite gneiss. This research was also to estimate how organic matter, calcium and iron oxide influence on soil aggregation under different forest conditions in various bedrock regions. And it also had a purpose to rate physical factors relevant to soil aggregation, their characteristics and aggregate diameter which closely relates to stabilities in the process of soil erosion. The following conclusions have been drawn in response to the overall research objectives. The rates of the soil aggregation on different bedrock regions were 21% in Limestone bedrock, 19.8% in Granite bedrock and 9.9% in Granite gneiss bedrock. A main factor in soil aggregation was the orgainc matter content in soils and the rate of soil aggregation increased in the constant proportion with the organic matter content. The relation could be formulated into Y=4.31X-4.37(Y : aggregation ratio X : organic matter content). The soil aggregation ratio under the deciduous forests eras higher than that under the coniferous forests. It was considered that this resulted from differences in organic matter content. Soil aggregates with larger diameter than 0.5mm were found more in Limestone bedrock than other smaller size soil aggregates of 0.25mm diameter were more distributed in Granite gneiss bedrock. Granite bedrock region had normal distribution in soil aggregate sizes with the highest frequency of 0.5mm diameter. Calcium and iron oxides had only partial influences on the soil aggregation in some specific conditions. But in Limestone bedrock region calcium influenced on the soil aggregation with the organic matter content.
Hwang, Wonjae;Park, Minseok;Hyun, Seunghun;Ji, Won hyun;Lee, Sang-Hwan
Ecology and Resilient Infrastructure
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v.4
no.3
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pp.180-185
/
2017
Restoration of min-impacted arable land is often performed through stabilization of trace elements by amendment treatment combined with (clean) soil covering on the surface. Recently, soil loss problem from sloping remediated agricultural lands has risen as an emerging concern. In this study, efficacy of aggregation formation was assessed by single and binary treatments of four potential amendments (bentonite, lime, organic matter, and steel slag) applied on three cover soils having different clay contents (9.4, 14.7, and 21.2% for A, B, and C soils respectively). In results of single treatments, 5% organic matter for A soil and 5% lime for B and C soils were found most effective for the aggregation formation compared to the respective controls (without amendments). Among nine binary treatments, 3% organic matter + 1% lime for A soil and 1% organic matter + 3% lime for both B and C soils led to the highest formation of aggregation (30.4, 25.0, and 36.5% for A, B, and C soils). For a site-application, the soil erodibility difference between the cover soils (0.045, 0.051, and 0.054 for A, B, and C soils, respectively) and the national average of arable land (0.032) was assumed to be compensated by amendment addition, which is equivalent to 29.1% aggregation formation. To achieve the aggregation goal, 5% lime for A and B soils and 3% lime for C soil were best in the consideration of benefit/cost, thereby effectively and economically reducing soil loss from sloping remediation site. Soil alkalinity induced by lime treatment was not considered in this work.
The study was carried out to confirm the changes of soil physico-chemical properties and population of Fusarium solani by soil managements at preplanning fields for ginseng cultivation. Soil porosity and aggregation had been significantly increased during the managements while exchangeable nitrogen content and bulk density of the soil had been decreased. Available phosphate and exchangeable potassium content, in addition, seemed to be slightly increased. And soil aggregation showed positive correlation with clay, organic matter, soil moisture, and Ca content in the soil but negative with K content. Decrease rate of NH4-N and NO3-N content after soil managements were 55% and 41% in average, respectively. And better decrease effect for NH4-N was obtained in sand loam soil whereas no effect for NO3-N with soil textures. The more ploughing seemed to result in less propagules of F solani in the soil, however there was non significant decrease in population of the pathogen after the soil management. Number of F. solani in soil was significantly less in the fields where gramineous and leguminous crops had been grown as a precrop than other crops tested. Meanwhile there was no correlation between soil texture and population of the pathogen in the soil.
We investigated influence of continious application of gypsum (G: $CaSO_4{\cdot}2H_2O$), popped rice hulls (H) and zeolite (Z) on soil aggregation of reclaimed sandy loam soils. The application rates amended to fine sandy loam from reclaimed soils at Kyehwado were varied as follows:1550 (G1), 3100 (G2), 6200 (G3), 1000 (H1), 2000 (H2), 3000 (H3), and 200 (HZ1), 400 (HZ2) and 800 (HZ3) added to 1500(H) kg $10a^{-1}$, respectively. Soil aggregates were analyzed for 60, 90 and 120 days after treatments (DAT). At 60 DAT, The amount of aggregate from soil samples treated with gypsum was slightly increased with G1 while the aggregation was decreased by 4.66% for G3 for soil aggregates than thar of control. The treatments of H or HZ were effective in soil aggregation. The effect of treatment was in the order of H > HZ > G. At 90 DAT, increasing amount of gypsum attributed to decrease in soil aggregates. Therefore, we could conclude that suitable amounts of gypsum for soil aggregation in fine sandy loam might be 1550 kg $10a^{-1}$ or less. H1 increased aggregation by 7% for aggregate size between 1.0 and 2.0 mm. HZ1 was most effective in aggregation by 52.78% among the treatments while H2 and HZ3 51.50% and 48.51% at 120 DAT, respectively. As a result, we found that the effect of the treatment for soil amendments was in order of H > HZ > G.
The effect of soil physico-chemical properties of pre and post soil preparation and permanent bed period on growth and yield was analysed by two models of annual variation and percent annual change (PAC). 1. Aggregation, porosity, bulk density except moisture were significantly different in each year from preparation to the 6th year while all soil chemical properties except Mg were significantly different in each year. 2. Soil physical properties showed significant simple correlation with yield and negative with the missing plant rate in each year while the electroconductivity ($EC_5$) of the 4th year showed significant correlation with yield. 3. Yield showed significant positive correlation with the variation of aggregation in permanent bed period, and negative with variation and PAC of aggregation of preplanting soil and variation of moisture in permanent bed period. Missing plant rate was negatively correlated with porosity variation of preplanting soil and positively with PAC of aggregation in preplanting soil and of moisture in permanent bed period. 4. According to multiple regression between yield and soil physical properties, porosity of preplanting soil was in the greatest contribution. Among aggregations, the variation in permanent bed period was in the greatest contribution.
Koh, Il-Ha;Kwon, Yo Seb;Jeong, Mun-Ho;Ji, Won Hyun
Journal of Soil and Groundwater Environment
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v.26
no.6
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pp.18-26
/
2021
Soil aggregation begins with flocculation of clay particles triggered by interfacial reactions of polyvalent cation such as Ca2+ and Fe3+, and they are also known as important elements to control the mobility of arsenic in soil environment. The objective of this study was to investigate the feasibility of CMDS (coal mine drainage sludge) for soil loss reduction and stabilization of arsenic-contaminated soil in a 37% sloped farmland under rainfall simulation. The amount of soil loss decreased by 43% when CMDS was applied, and this result was not significantly different from the case of limestone application, which yielded 46% decrease of soil loss. However, the relative amount of dispersed clay particles in the sediment CMDS-applied soil was 10% lower than that of limestone-applied soil, suggesting CMDS is more effective than limestone in inducing soil aggregation. The concentrations of bioavailable arsenic in CMDS amended soil decreased by 46%~78%, which was lower than the amount in limestone amended soil. Therefore, CMDS can be used as an effective amendment material to reduce soil loss and stabilize arsenic in sloped farmland areas.
BACKGROUND: Silver grass (Miscanthus sinensis) No. 1 was developed for production of bio-ethanol, and for the purpose the silver grass growing sector was established in Geumgang basin, Iksan, Jeonbuk, in 2011. However, the other application potentials except for using as the bio-energy resources should be considered because of the drop in international oil prices. Therefore, there is the necessity of a scientific basis to use the silver grass instead of rice straw as the organic matter source that is used for improvement of soil quality in the plastic film house. METHODS AND RESULTS: The silver grass was applied at 5, 10, 15 and 20 Mg/ha and tilled before the watermelon was planted in the plastic film-house. The control plot was treated with 10 Mg/ha with rice straw, and watermelons have been cultivated for 3 years(2017~2019). Soil aggregation, soil chemistry, and the growth characteristics were investigated, when the watermelon was harvested every year. Soil aggregation levels at the 2nd and 3rd year of watermelon harvest were similar from the plot applied with the silver grass at 5 Mg/ha and the control plot, and increased in the silver grass treated plots with more than 10 Mg/ha. However, there was no statistically significant difference between the plots. The nitrogen mineralization of silver grass in the control plot tended to be similar to the 5 Mg/ha plot, but the silver grass treated plots with over 10 Mg/ha showed low nitrogen mineralization. Soil EC on harvest stage was proportional to the applied mass of the silver grass, but pH was in inverse with the applied mass. Soil organic matter content, available phosphate, and exchangeable cations increased with the continued use of silver grass. Watermelon weight found to be the best on more than 15 Mg/ha of silver grass, and the sugar content was highest when 10 Mg/ha was treated. CONCLUSION: The use of the silver grass at 10 Mg/ha annually as the organic source was effective in replacing rice straw while growing fruits and vegetables on the plastic film house.
Soil aggregate is a vigorous procedure including soil physical, chemical, and biological processes. Pore space created by binding these particles together improves retention and exchange of air and water. Various researches have reported that the benefits of organic polymers that may increase aggregate stability. The purpose of the study was to determine if a liquid organic polymer mixture has any influence on perennial ryegrass quality or soil aggregation. $Turf2Max^{(R)}$ was applied to two soils as a source of liquid organic polymer. Fine-loamy soil from local Iowa topsoil with 4.0% organic matter was screened and dried. Commercial baseball infield clay, $QuickDry^{(R)}$, was used as the second soil There were three rates of liquid organic polymer (0, 2, and 4%). there was no visual improvement in turf grass color, quality, or growth by using organic polymer. It is possible that aggregate stability increases with use of organic polymer. The aggregate stability study needs to be repeated in the greenhouse and then substantiated under field conditions for these preliminary observations.
KSCE Journal of Civil and Environmental Engineering Research
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v.26
no.6D
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pp.1019-1023
/
2006
The slope information based on DEM is very useful for urban planning, landscape, road design and water resource areas such as rainfall-runoff and soil erosion estimation. The resolution of slope, which is from DEM, can be variously decided by an application fields and the kinds of modeling method. In particular, the more decreased resolution makes the more decreased slope value because of the increased horizontal distance. This study presents slope evaluation method by aggregation method based on discharge and Manning's velocity equation to advance the loss of slope information in according to the resolution, and then applied it to calculate topographic factors of soil erosion model. As a result, conventional method shows 34.8% errors but aggregation method shows 12.6% errors. This study selected up-, middle-, and downstream region in watershed and analyzed the capability of aggregation method in order to estimate the influence of topographic characteristics. As a result of estimation, aggregation method shows more advanced results than conventional method. Therefore, the slope evaluation method by aggregation method can improve efficiently the loss of slope information in according to the variation of resolution in water resource area such as rainfall-runoff model.
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