• Title/Summary/Keyword: Soft carbon

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Electrical properties of polyethylene composite films filled with nickel powder and short carbon fiber hybrid filler

  • Mironov, V.S.;Kim, Seong Yun;Park, Min
    • Carbon letters
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    • v.14 no.2
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    • pp.105-109
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    • 2013
  • Effects of the amount of nickel powder (Ni) in Ni-carbon fiber (CF) hybrid filler systems on the conductivity(or resistivity) and thermal coefficient of resistance (TCR) of filled high density polyethylene were studied. Increases of the resistivity and TCR with increasing Ni concentration at a given hybrid filler content were observed. Using the fiber contact model, we showed that the main role of Ni in the hybrid filler system is to decrease the interfiber contact resistance when Ni concentration is less than the threshold point. The formation of structural defects leading to reduced reinforcing effect resulted in both a reduction of strength and an increase of the coefficient of thermal expansion in the composite film; these changes are responsible for the increases of both resistivity and TCR with increasing Ni concentration in the hybrid filler system.

On the Relation Between the Crystallite Diameters and the Physical Properties of Soft and Hard Carbons by Heat Treatment Temperature (熱處理溫度에 따른 Soft Carbon과 Hard Carbon 結晶子 크기와 物理的 特性)

  • Ju Seong Lee
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.395-399
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    • 1969
  • On the soft carbon made from petroleum coke, it was found that the graphitization began at around 2,000$^{\circ}C and crystallite diameters were almost saturated at 2,400$^{\circ}C., and that the molecular planes were difficult to arrange into an ideal graphite lattice in spite of the saturation of crystallinity by heat treatment temperature. On the hard carbon made from cross-linked thermosetting plastics, phenol-formaldehyde filler and phenol-benzaldehyde binder, it was very difficult to rotate the molecular planes into a regular directional arrangement and into a consecutive order corresponding to the large graphite crystals. In addition to the above mentioned crystallinity, it was also determined in relation to electric conductivity, resistivity, hardness and apparent density of carbons.

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Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

  • Cho, Hyunjin;Lee, Changhyup;Oh, In Seoup;Park, Sungchan;Kim, Hwan Chul;Kim, Myung Jong
    • Carbon letters
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    • v.13 no.4
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    • pp.205-211
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    • 2012
  • Methanol as a carbon source in chemical vapor deposition (CVD) graphene has an advantage over methane and hydrogen in that we can avoid optimizing an etching reagent condition. Since methanol itself can easily decompose into hydrocarbon and water (an etching reagent) at high temperatures [1], the pressure and the temperature of methanol are the only parameters we have to handle. In this study, synthetic conditions for highly crystalline and large area graphene have been optimized by adjusting pressure and temperature; the effect of each parameter was analyzed systematically by Raman, scanning electron microscope, transmission electron microscope, atomic force microscope, four-point-probe measurement, and UV-Vis. Defect density of graphene, represented by D/G ratio in Raman, decreased with increasing temperature and decreasing pressure; it negatively affected electrical conductivity. From our process and various analyses, methanol CVD growth for graphene has been found to be a safe, cheap, easy, and simple method to produce high quality, large area, and continuous graphene films.

Evaluation of dose distribution from 12C ion in radiation therapy by FLUKA code

  • Soltani-Nabipour, Jamshid;Khorshidi, Abdollah;Shojai, Faezeh;Khorami, Khazar
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2410-2414
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    • 2020
  • Heavy ions have a high potential for destroying deep tumors that carry the highest dose at the peak of Bragg. The peak caused by a single-energy carbon beam is too narrow, which requires special measures for improvement. Here, carbon-12 (12C) ion with different energies has been used as a source for calculating the dose distribution in the water phantom, soft tissue and bone by the code of Monte Carlobased FLUKA code. By increasing the energy of the initial beam, the amount of absorbed dose at Bragg peak in all three targets decreased, but the trend for this reduction was less severe in bone. While the maximum absorbed dose per bone-mass unit in energy of 200 MeV/u was about 30% less than the maximum absorbed dose per unit mass of water or soft tissue, it was merely 2.4% less than soft tissue in 400 MeV/u. The simulation result showed a good agreement with experimental data at GSI Darmstadt facility of biophysics group by 0.15 cm average accuracy in Bragg peak positioning. From 200 to 400 MeV/u incident energy, the Bragg peak location increased about 18 cm in soft tissue. Correspondingly, the bone and soft tissue revealed a reduction dose ratio by 2.9 and 1.9. Induced neutrons did not contribute more than 1.8% to the total energy deposited in the water phantom. Also during 12C ion bombardment, secondary fragments showed 76% and 24% of primary 200 and 400 MeV/u, respectively, were present at the Bragg-peak position. The combined treatment of carbon ions with neutron or electron beams may be more effective in local dose delivery and also treating malignant tumors.

Preparation and Characterization of Spherical Carbon Composite for Use as Anode Material for Lithium Ion Batteries

  • Ahn, Byoung-Hoon;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1331-1335
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    • 2010
  • A novel spherical carbon composite material, in which nanosized disordered carbons are dispersed in a soft carbon matrix, has been prepared and investigated for use as a potential anode material for lithium ion batteries. Disordered carbons were synthesized by ball milling natural graphite in air. The composite was prepared by mixing the ball-milled graphite with petroleum pitch powder, pelletizing the mixture, and pyrolyzing the pellets at $1200^{\circ}C$ in an argon flow. The ballmilled graphite consists of distorted nanocrystallites and amorphous phases. In the composite particle, nanosized flakes are uniformly distributed in a soft carbon matrix, as revealed by X-ray diffractometer (XRD) and transmission electron microscopy (TEM) experiments. The composite is compatible with a pure propylene carbonate (PC) electrolyte and shows high rate capability and excellent cycling performance. The electrochemical properties are comparable to those of hard carbon.

Equilibrium modeling for adsorption of NO3- from aqueous solution on activated carbon produced from pomegranate peel

  • Rouabeh, I.;Amrani, M.
    • Advances in environmental research
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    • v.1 no.2
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    • pp.143-151
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    • 2012
  • Nitrate removal from aqueous solution was investigated using $ZnCl_2$ and phosphoric acid activated carbon developed from pomegranate peel with particle size 0.4 mm. Potassium nitrate solution was used in batch adsorption experiments for nitrate removal from water. The effects of activated carbon dosage, time of contact, and pH were studied. The equilibrium time was fond to be 45 min. Two theoretical adsorption isotherms namely Langmuir and Freundlich were used to describe the experimental results. The Langmuir fit the isotherm with the theoretical adsorption capacity ($q_t$) was fond 78.125 mg g-1. Adsorption kinetics data were modeled using the pseudo-first, pseudo-second order, and intraparticle diffusion models. The results indicate that the second-order model best describes adsorption kinetic data. Results show activated carbon produced from pomegranate is effective for removal of nitrate from aqueous solution.

Research on the Solution of Non-permanence Problem of Forest Carbon Offset Project Focused on the Introduction of Buffer System (산림 탄소상쇄 사업의 비영속성 처리 방안 -버퍼 제도의 도입을 중심으로-)

  • Cha, Junhee;Lee, Jong-Hak;Han, Kijoo;Bae, Jae Soo;Seol, Mihyun;Joo, Rin-Won
    • Journal of Korean Society of Forest Science
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    • v.101 no.1
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    • pp.83-90
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    • 2012
  • Forests as carbon sinks and sources, play an important role in mitigating global climate change. Nonpermanence problem of forest carbon offset projects should be addressed practically and properly for obtaining credible forest carbon credits. This study aims to analyze major non-permanence approaches and their applicability for Korean forest carbon offset projects. Introduction of the buffer system, one of the most generally used non-permanence approaches, should be considered first for domestic forest carbon offset schemes. From the research survey, experts preferred the buffer system to other approaches such as forest certification, conservation easement, and longer conservation period. Standard development including a buffer system with a risk assessment tool is required to assure project participation and permanence of carbon credits.

Effect of Residual Impurity on Magnetic Properties of the Permalloy Soft Magnet by Powder Injection Molding (분말사출성형으로 제조된 퍼말로이 연자성체에서 잔류 불순물이 자기특성에 미치는 영향)

  • 정원용;최준환;정우상
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.291-296
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    • 2000
  • The manufacturing method of permalloy soft magnet with the Ni contents of 46.6 and 47.2 wt% was investigated by powder injection molding technology. The magnetic properties of permalloy were greatly affected on the residual carbon and oxygen content of the sintered magnet. Solvent extraction and thermal debinding process to minimize the residual carbon content in sintered magnet were developed by controlling the debinding atmosphere. The residual carbon content depends on the debinding condition of the binder system for powder injection molding and the residual oxygen content on the sintering atmosphere. The sintered magnet produced by powder injection molding process had a 50 ppm. residual carbon, 150 ppm. residual oxygen. The coercivity and maximum relative permeability of permalloy soft magnet were 0.46 Oe and 14,600 respectively.

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Study on sintering process of woodceramics from the cashew nutshell waste

  • Kieu, Do Trung Kien;Phan, DinhTuan;Okabe, Toshihiro;Do, Quang Minh;Tran, Van Khai
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.472-478
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    • 2018
  • In this study, the sintering mechanism of woodceramics (WCs) from cashew nut shell waste (CNSW) was studied by analyzing chemical reactions and structural changes during the sintering process of of CNSW powder, liquefied wood and green bodies of WCs at $900^{\circ}C$ for 60 minutes in the $CO_2$ atmosphere. The chemical and structural properties of the products were investigated by X-ray diffraction (XRD), Raman spectroscopy, Fourier Transform Infrared (FTIR), and scanning electron microscope (SEM). The results showed that the decomposition reactions of liquefied wood and CNSW occurred simultaneously to form the hard carbon and the soft carbon at high temperature. The sintering mechanism of WCs has been presented.