• Title/Summary/Keyword: Sodium nitrate$(NaNO_3)$

Search Result 46, Processing Time 0.025 seconds

Thermal Denitration of High Concentration Nitrate Salts Waste Water (열분해에 의한 고농도 질산염 폐액의 탈질)

  • ;;;;;C. Latge
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2003.11a
    • /
    • pp.665-670
    • /
    • 2003
  • This study investigated the thermodynamic and the thermal decomposition properties of high concentration nitrate salts waste water for the lagoon sludge treatment. The thermodynamic property was carried out by COACH and GEMINI II based on the composition of nitrate Salts waste water. The thermal decomposition property was carried out by TG-DTA and XRD. Ammonium nitrate and sodium nitrate were decomposed at $250^{\circ}C$$730^{\circ}C$$450^{\circ}C$$Na_2O$ into stable $Na_2O$.$Al_2O_3$. The flow sheet for nitrate salts waste water treatment was proposed based on the these properties data. These will be used by the basic data of the process simulation.

  • PDF

Determination of Some Inorganic Anions in Saline Water by Ion Chromatography with UV Detection (이온크로마토그래피를 이용한 소금물중의 무기음이온들의 분리정량)

  • Han, Sun Ho;Park, Yang Soon;Park, Soon Dal;Joe, Kih Soo;Eom, Tae Yoon
    • Analytical Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.99-104
    • /
    • 1999
  • A stepwise gradient elution with two wavelengths detection was performed for the separation and determination of some anions in saline water. The eight anions such as iodate, bromate, nitrite, bromide, nitrate, chromate, iodide and thiocyanate were successfully separated using AS-7 column and sodium chloride/sodium phosphate buffer solution as an eluant within 40 min. The separation behaviors of anions were studied at various sodium chloride concentrations. The peak shapes of anions of bromate, nitrite, bromide and nitrate gradually broadened as the concentration of sodium chloride increased until 1.0 M in the sample solutions. However, no effect was observed in the peak shapes of chromate, iodide and thiocynate. A good linearity was obtained at the range of ppm(mg/L). The detection limit was proved to be $10-720{\mu}g/L$ for the eight anions with $50{\mu}L$ injection volume. This method was applied to the determination of $Br^-$, ${NO_3}^-$ and $I^-$ in sea water.

  • PDF

Cathodic Coloration of Silk Fabric Treated with Silver Nitrate (질산은 처리된 실크의 환원 발색)

  • Jung, Mun-Hwa;Lee, Mun-Cheul
    • Textile Coloration and Finishing
    • /
    • v.21 no.2
    • /
    • pp.14-21
    • /
    • 2009
  • In this article, silk fabric was treated with silver nitrate ($AgNO_3$) as oxidizing agent, with conditions such as concentration, and treating time, and subsequently treated with reducing agents such as sodium boron hydride ($NaBH_4$) and sodium sulfide ($Na_2S$) to obtain cathodic coloration. After coloration of silk fabric, dyeing properties (K/S value), colorfastnesses such as wash, rubbing and light, and antibacterial activity property were examined. $AgNO_3$ treating time and reducing time did not influence K/S value, whereas the pH value at alkaline region showed a high K/S value of silk fabric. The cathodic colorations of silk fabric with both of reducing agents at $30^{\circ}C$ have excellent color fastnesses. Also the high antibacterial activities were obtained by the treatment with silver nitrate even at 1% of lower concentration.

Influence of Sodium Nitrate (NaNO$_3$) of Different Feeds on Growth and Bioenergetics of Bivoltine NB$_4$D$_2$ Race of the Silkworm, Bombyx mori L.

  • Pallavi, V.P.;Kaliwal, B.B.
    • International Journal of Industrial Entomology and Biomaterials
    • /
    • v.9 no.2
    • /
    • pp.249-254
    • /
    • 2004
  • Dietary supplementation of sodium nitrate with different concentrations 50, 100, 200, 500, 700 and 1000 $\mu\textrm{g}$/ml of single, two, three and four feeds to fifth instar larvae of biovoltine NB$_4$D$_2$ race of the silkworm, B. mori resulted in significant increase in the food conversion, conversion rate and conversion efficiency $K_1$ and $K_2$. However, there were significant decrease in the food assimilation, assimilation rate and assimilation efficiency in the sodium nitrate treated groups as compared with that of the corresponding parameters of the carrier control. This indicates that the administration of sodium nitrate may stimulate metabolic activities, thereby influencing conversion of food into body weight in the bivoltine silkworm, B. mori.

The Improvement of Denitrofication by Using Sodium Salts in the SNCR Process (SNCR 공정에서 Sodium Salts 첨가제를 이용한 탈질반응 개선에 관한 연구)

  • Lee, Seung Moon;Park, Kwinam;Kwak, Tae-Heon;Park, Jin-Won;Makin, Sanjeev;Kim, Byung-Hwan
    • Korean Chemical Engineering Research
    • /
    • v.43 no.2
    • /
    • pp.324-329
    • /
    • 2005
  • The efficiency of reducing nitric oxide using urea combined with alkali salt additives is reported in this study. The inlet concentration of NO is 500 ppm with air flow rates of 3 and 5 L/min. Reduction of NO was studied from 650 to $1,050^{\circ}C$ with urea concentrations of 0.3 to 1 mol/L. The efficiency for the reduction of NO increased by 44% when urea is added alone. A further increase in efficiency was observed in the presence of NaOH as additive in fact, the efficiency was increased by more than 25% and 75% when 0.5 mol/L and 1 mol/L NaOH were added with the urea. The efficiency for the reduction of NO increased with all additives, but descended in the order NaOH, $Na_2CO_3$, $NaNO_3$, HCOONa, and CHCOONa. The maximum efficiency of NaOH and $Na_2NO_3$ are 74% and 73%, respectively. All these additives did not alter the comparatively wide operating temperature window for reducing NO. However, sodium compounds do not shift the maximum NO concentration towards lower temperatures when the NO removal activity enhances.

Electrochemical polishing method using the point electrode tools(2nd) (점 전극을 이용한 전해연마 가공특성)

  • 이승훈;박규열;양순용
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
    • /
    • 1999.05a
    • /
    • pp.251-255
    • /
    • 1999
  • In last paper, it was suggested electrochemical polishing method using the point electrode tools. It was aimed that Machining rate in ECM using the point electrode method should be ultimately small and also high dimension accuracy and surface integrity should be fine. In this paper, the machining characteristics were investigated by using the several types of electrolyte.

  • PDF

Effect of High Concentrations of Sodium or Chloride Salts in Soil on the Growth of and Mineral Uptake by Tomatoes (토양에의 고농도 Na 및 Cl 염류가 토마토의 생육 및 무기성분 흡수에 미치는 영향)

  • 강경희;권기범;최영하;김회태;이한철
    • Journal of Bio-Environment Control
    • /
    • v.11 no.3
    • /
    • pp.121-126
    • /
    • 2002
  • This study was conducted to investigate the effect of high concentration of sodium salts and chlorides in soil on the growth of tomato and the uptake of minerals. The growth inhibition rates of plant height and dry weight were different depending on salts, but they were not related to the electric conductivities (EC) and acidities (pH) in the soil solution. The orders of growth inhibition were Cl, SO$_4$, CO$_3$, PO$_4$>NO$_3$ in the sodium salts series, and Na, K, Mg, NH$_4$>Ca in the chlorides. The growth inhibition rates of the sodium salts series tended to be larger than those of the chloride series. Yield was lower 30%~10% in the sodium salt and chloride series than in the control. Chlorophyll content, photosynthetic rate and stomatal conductance were lower in the sodium salts and chloride series than in the control. Mineral concentration was lower in sodium salts and chlorides than in control. The nitrate absorption was inhibited in all salts except for NaNO$_3$ and NH$_4$Cl, and specially in NaCl and Na$_2$SO$_4$ treatments of the sodium salts and in KCl treatment of chloride series. K concentration was reduced NaCl and Na$_2$SO$_4$ treatments compared with the other salts. In the sodium salt series, calcium and magnesium concentration were decreased antagonistically when sodium concentration was increased.

Complete Decomposition of Chlorinated-Organic Compounds(PCB, 4-DCBz) with Improved Supercritical Water Oxidation Method (개량된 초임계수 산화법에 의한 염소계 유기물(PCB, 4-DCBz)의 완전분해반응)

  • Lee Sang-Hwan;Park Ki-Chul;Park Yoon-Yul;Yang Jong-Gyu;Kim Jung-Sung;Hiroshi Tomiyasu
    • Journal of Environmental Science International
    • /
    • v.14 no.5
    • /
    • pp.513-520
    • /
    • 2005
  • For the destruction of toxic chlorinated organic compounds, this study proposes improved supercritical water oxidation method (multistep oxidation) using sodium nitrate as an oxidizer. This method solves the problems involved in the existing supercritical water oxidation method. Multistep oxidation means that $NaNO_3$ is oxidized to $N_2\;via\;NaNO_2$ and NO. Toxic and hard to destroy organic substances like para-dichlorobenzen(4-DCBz), polychlorinate biphenyl(PCB) ware oxidized to non toxic substances in a condition, in which rapid pressure and temperature rise is restrained as much as possible. 4-dichlorobenzene(4-DCBz) and Polychlorinate biphenyl(PCB) in condition$(450^{\circ}C,\;p_w=0.25g/cm^3,\;30min)$ Was discomposed perfectly.

Mutual Separation of Am(III) and Eu(III) by Solvent Extraction with Cyanex 301 (Cyanex 301에 의한 Am(III)과 Eu(III)의 상호분리)

  • Yang, Han-Beom;Lim, Jae-Gwan;Lee, Eil-Hee;Yoo, Jae-Hyung
    • Applied Chemistry for Engineering
    • /
    • v.10 no.1
    • /
    • pp.143-147
    • /
    • 1999
  • The present paper describes the solvent extraction behaviors and the mutual separation of Am and Eu by sulphur bearing Cyanex 301 acidic extractant in sodium nitrate solutions. Original Cyanex 301 was not able to separate the Am and Eu because of their similar extraction behaviors. The saponification of commercial Cyanex 301 was performed by small amounts of 8 M NaOH solutions and saponified Cyanex 301 was able to separate of Am from Eu with high selectivity in sodium nitrate aqueous solution. The separation factors ($SF_{Am/Eu}$) were increased with saponified ratio of commercial Cyanex 301, pH of sodium nitrate solution and initial concentration of Eu. To obtain the homogeneous saponified Cyanex 301, heterogeneous saponified Cyanex 301 was treated with addition of octyl alcohol or filtration. The observed $SF_{Am/Eu}$ was 32.3 for the former and 930 for the latter. Finally, the stripping behaviors of Am and Eu were similar and stripping yields showed 96.1% for the 1 M $NaNO_3$(pH=1.3) and 99% for the mixture solution of 0.05 M DTPA and 1.5 M lactic acid.

  • PDF

Tungsten Recovery from Tungsten Carbide by Alkali Melt followed by Water Leaching (알칼리 용융 및 수 침출을 이용한 탄화텅스텐으로부터 텅스텐 회수)

  • Kim, Byoungjin;Kim, Suyun;Lee, Jaeryeong
    • Resources Recycling
    • /
    • v.26 no.6
    • /
    • pp.91-96
    • /
    • 2017
  • Tungsten (W) recovery from tungsten carbide (WC) was researched by alkali melt followed by water leaching. The experiments of alkali melt were carried out with the change of the sort of alkali material, heating temperature, and the heating duration. Water leaching of W was performed in the fixed conditions ($25^{\circ}C$, 2 hr., slurry density: 10 g/L). From the mixture of WC and sodium nitrate ($NaNO_3$) in the molar ratio of 1:2, treated at $400^{\circ}C$ for 6 hours, only 63.3% of W might be leached by water leaching. With the increase of sodium hydroxide (NaOH) as a melting additive, the leachability increased. Finally it reached to 97.8 % with the melted mixture of ($WC:NaNO_3:NaOH$) in the ratio of (1:2:2). This imply that NaOH may play a role as a reaction catalyst by lowering Gibb's free energy for alkali melt reaction for WC.