• 제목/요약/키워드: Sodium chloride aqueous solution

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A Study on the Effect of Surfactant on the Freezing of Aqueous Solution (수용액의 동결에 영향을 미치는 계면활성제의 효과에 관한 연구)

  • Kim, Myoung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.6
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    • pp.694-698
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    • 2007
  • This present study has dealt with the effect of surfactant on the freezing of aqueous solution Sodium chloride aqueous solution was used to measure the effect of surfactant and the main parameters of this experiment were temperature of bath, revolution of stirrer. and the radial velocity of NaCl solution. The acquired main conclusions are as follows; 1) the lower super-cooling temperature make hardly to attach the ice on beaker, 2) the size of ice become smaller to add the surfactant, 3) the ice packing factor increase with increasing of stirrer revolution.

A Study on the Dyeing of Polyester Fabric by Microwave Heating(II) (Microwave가열에 의한 Polyester직물의 염색성에 관한 연구(II))

  • 임수경;김삼수;허만우
    • Textile Coloration and Finishing
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    • v.11 no.3
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    • pp.49-57
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    • 1999
  • The effect of padding solution for the microwave heat dyeing of polyester fabric was studied variously. The dyeing property of polyester fabric varied with the kinds of added chemicals in the padding solution. Polyester fabrics impregnated in aqueous urea solution and aqueous sodium chloride solution for 10 minutes and then dyed for 7 minutes by microwave apparatus(2450 MHz, 700 W) under optimum conditions give good exhaustion. An aqueous solution of urea and a sodium chloride solution was more effective than water as padding solution for microwave heating dyeing. The K/S values of dyed polyester fabric by microwave were significantly affected by the type of solvent added in padding media and its concentration. Added solvents, n-hexane, acetone and dimethyl formamide were also more effective than water as padding media for the microwave heating dyeing. It is assumed that the effect of used solvents on dyeing property of polyester fabrics depends on the solubility parameter difference between solvent and polyester fabric.

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Microwave Heat Dyeing of Polyester Fabric

  • Kim, Sam-Soo;Lee, Su-Gyung m;Ghim, Han-Do;Kim, Joon-Ho;Lyoo, Won-Seok
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.204-209
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    • 2003
  • The effect of padding solution on the microwave heat dyeing of polyester fabric was studied extensively. Polyester fabrics were impregnated in aqueous urea solution and aqueous sodium chloride solution for 10 min and then dyed for 7 min by microwave apparatus (2450 MHz, 700 W) under optimum conditions which provide good exhaustion. Aqueous solutions of urea and sodium chloride showed more effective than water as a padding solution for microwave heat dyeing. The type of solvent added in padding media and its concentration significantly affects the K/S values of dyed polyester fabric. Added solvents such as n-hexane, acetone, and dimethyl formamide were also more effective than 100 % water as padding media for the microwave heat dyeing. It is supposed that the effect of used solvents on dyeing property of polyester fabrics depends on the solubility parameter difference between solvent and polyester fabric.

A Yew Technique for Infrared Spectroscopy using Polyethylene Film Cell (Polyethylene Film을 利用한 赤外線分光分析用 Cell)

  • Sung, Chwa-Kyung;Noh, Ick-Sam
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.58-64
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    • 1963
  • Authors propose a new technique using polyethylene film instead of sodium chloride window as a cell material. Nujol mulls, liquids and aqueous solutions are sandwitched between two pieces of polyethylene film which are held between cardboards. Ordinary lead or stainless steel spacers could be used if exact cell thickness is desired. A more elaborate cell can be assembled by injecting samples between two pieces of polyethylene film which are placed between sodium chloride windows of ordinary demountable liquid cell. The absorption bands due to polyethylene and Nujol are compensated by placing the polyethylene film of suitable thickness in the reference beam. The absorption bands due to solvents such as water can also be compensated by the polyethylene film cell sandwitched solvent of suitable thickness in the reference beam. This method would be a simple new technique. Especially this technique may offer a new helpful way for the investigation of the state of substances in aqueous system. Using this technique, authors have observed the appearance of an absorption bands at 3.2 micron, in the spectrum of phenol in aqueous solution, that is absent in the spectrum of phenol in benzene solution. The same absorption band also has been observed in the spectra of aqueous formaldehyde solution and aqueous polyvinyl alcohol solution, where the absorption bands due to polyethylene and water are compensated. Although it may be regarded that this absorption band is related to the intermolecular interaction between water and the solute having OH group, that is hydrogen bonding. The exact assignment of this absorption band is out of this work.

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Effect of Polyaniline Film by Electro-synthesis on Corrosion Resistance of Steel Sheets in the Aqueous Solution of Sodium Chloride (NaCl 수용액내에서 강판의 내식성에 미치는 전해합성 폴리아닐린 피막의 영향)

  • Yoon, J.M.;Kim, Y.G.
    • Korean Journal of Materials Research
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    • v.13 no.9
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    • pp.625-630
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    • 2003
  • Increasing environmental concerns require to solve the problem produced due to the use of heavy metals in coating formulations. Therefore, it is necessary to develop new coating strategy employing inherently conducting polymers such as Polyaniline(PANI). Polyaniline films were electrosynthesized by oxidation of aniline on cold rolled and weathering sheets using the potentiostatic mode from an aqueous oxalic acid medium. Potentiodynamic polarization curves were obtained for cold rolled and weathering sheets in the aqueous solution of 3% sodium chloride. The structure and properties of polyaniline film were elucidated using SEM, DSC, SST. A high corrosion resistance of polyaniline films were observed with a gain of the corrosion potential around 600-900 mV positive in the substrate covered with polyaniline than in the case without it.

Solvent Extraction of Lithium Ion in Aqueous Solution Using TTA and TOPO (TTA와 TOPO를 이용한 수용액 중의 리튬이온 용매추출)

  • Lee, Jeon-Kyu;Jeong, Sang-Gu;Koo, Su-Jin;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.53-57
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    • 2013
  • For the purpose of development of the extraction process of lithium ion from concentrated water eliminated from desalination process, an experimental research on the solvent extraction of lithium ion from aqueous solutions was performed. The effects of operating parameters, such as concentration of extractant, ratio of extracting solution/aqueous solution, pH of aqueous solution, were examined. The effect of sodium chloride, the major component of sea water, was also examined. Lithium ion in aqueous solutions of pH=10.2~10.6 adjusted by ammonia solution was most effectively extracted by extracting solution composed of 0.02 M TTA and 0.04 M TOPO in kerosine. The addition of sodium chloride in lithium aqueous solution significantly interfered the extraction of lithium ion.

A Study on the Optimization of Physical and Chemical Parameters for the Precipitate of Sodium Alkylsulfate with Cetylpyridinium Chloride

  • Oh, Sun-Wha;Moon, Sung-Doo;Lee, Don-Keun;Lee, Dong-Jae;Kang, Young-Soo
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.280-284
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    • 2004
  • The optimum conditions for the most effective precipitate of surfactant complex of sodium alkylsulfate with cetylpyridinium chloride were studied in the aqueous solution. The parameters such as the alkyl chain length of anionic surfactants, molar ratio of two surfactants, temperature and the concentration of added NaCl in the aqueous solution were correlatively studied for the productivity of the precipitate formation. By the productivity, the optimum conditions to produce complex of anionic surfactant with cationic surfactant were the longer alkyl chain, equivalent molar ratio between anionic and cationic surfactants, 0 $^{\circ}C$ and 1.5 M NaCl.

Effect of Salt on the Formation of $\alpha$-Calcium Sulfate Hemihydrate from by-Product Gypsum of Phosphoric Acid Process in Aqueous Salt Solution at Atmospheric Pressure (상압수용액중에서 인산석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향)

  • 이구종;최상흘
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.66-72
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    • 1988
  • The effect of salts on the formation of ${\alpha}$-hemihydrated gypsum at boiling temperature under atmospheric pressure was studied by the solubility measurement method, and the formation of ${\alpha}$-hemihydrated gypsum from by-product gypsum of phosphoric acid process in the salts solution were investigated. The order of catalytic effect of salt on the formation of ${\alpha}$-hemihydrated gypsum are as follows: NH4Cl>NaCl>NaNO3. In the salts solution of sodium nitrate, sodium chloride, and ammonium chloride, prismatic ${\alpha}$-hemihydrated gypsum was obtained and the crystal form was converted to needle form in complex solution with sulfuric acid. The P2O5 content in gypsum was largely decreased in this atmosphoric solution process.

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SEPARATION BEHAVIOR OF WATER-ALCOHOL SOLUTION BY PARTIALLY DITHIOCARBAMATED POLY(VINYL CHLORIDE) MEMBRANE

  • Yamada, Sumio;Nakagawa, Tsutomu
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.46-51
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    • 1993
  • Poly(vinyl chloride) was modified by reacting with sodium N-methyldithiocarbamate or N-methyl-N-carboxymethyldithiocarbamate to obtain crosslinked dithiocarbamated PVC(PMD, PSDC). In addition PSDC were substituted with metal ions of $Ma^+, Li^+$ and $Cs^+$. PLMD and PSDC were reacted with copper ions in alcohol or aqueous solution to produce chelate complexes of dithiocarbanated PVC, respectively(PMD-$Cu^{2+}$, PSDC-$Cu^{2+}$). PSDC was irradiated by ultraviolet light to enhance crosslinking(PSDC-UV).

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Molecular-dynamic simulation on the equilibrium and dynamical properties of fluids in a nano-channel

  • Hoang, H.;Kang, S.;Suh, Y.K.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03a
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    • pp.208-214
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    • 2008
  • The equilibrium molecular-dynamic simulations have been performed to estimate the properties of the three kinds of fluids (the Lennard-Jones fluid, water and aqueous sodium-chloride solution) confined between two plates that are separated by 1.086 nm; included in the equilibrium properties are the density distribution and the static structure, and the diffusivity in the dynamic property. Three kinds of fluids considered in this study are. The water molecules are modeled by using the SPC/E model and the ions by the charged Lennard-Jones particle model. To treat the water molecules, we combined the quaternion coordinates with Euler angles. We also proposed a plausible algorithm to assign the initial position and direction of molecules. The influence of polarization of water molecules as well as the presence of ions in the solution on the properties will be addressed in this study. In addition, we performed the non-equilibrium molecular-dynamic simulation to compute the flow velocity for the case with the gravitational force acting on molecules.

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