DOI QR코드

DOI QR Code

A Study on the Optimization of Physical and Chemical Parameters for the Precipitate of Sodium Alkylsulfate with Cetylpyridinium Chloride

  • Oh, Sun-Wha (Basic Science Reserach Institute, Pukyong National University) ;
  • Moon, Sung-Doo (Department of Chemistry, Pukyong National University) ;
  • Lee, Don-Keun (Department of Chemistry, Pukyong National University) ;
  • Lee, Dong-Jae (Department of Chemistry, Pukyong National University) ;
  • Kang, Young-Soo (Department of Chemistry, Pukyong National University)
  • Published : 2004.02.20

Abstract

The optimum conditions for the most effective precipitate of surfactant complex of sodium alkylsulfate with cetylpyridinium chloride were studied in the aqueous solution. The parameters such as the alkyl chain length of anionic surfactants, molar ratio of two surfactants, temperature and the concentration of added NaCl in the aqueous solution were correlatively studied for the productivity of the precipitate formation. By the productivity, the optimum conditions to produce complex of anionic surfactant with cationic surfactant were the longer alkyl chain, equivalent molar ratio between anionic and cationic surfactants, 0 $^{\circ}C$ and 1.5 M NaCl.

Keywords

References

  1. Fujimoto, T. New Introduction to Surface Active Agents; SanyoChemical Industries Ltd.: Tokyo, 1996.
  2. Shaw, D. J. Introduction to Colloid and Surface Chemistry, 2ndEd.; Butterworths: London, 1966.
  3. Bennett, D. E.; Gallard, B. S.; Abott, N. L. J. Am. Chem. Soc.1996, 118, 499.
  4. Gallardo, B. S.; Hwa, M. J.; Abott, N. L. Langmuir 1995, 11, 4209. https://doi.org/10.1021/la00011a008
  5. Kim, H.; Lim, K. Bull. Korean Chem. Soc. 2003, 24, 1449. https://doi.org/10.5012/bkcs.2003.24.10.1449
  6. Lee, B. J. Korean Chem. Soc. 1998, 42, 519.
  7. Tanford, C. The Hydrophobic Effect: Formation of Micelles andBiological Membranes; John Wiley & Sons: New York, 1979.
  8. Amante, J. C.; Scamehorn, J. F.; Harwell, J. H. J. Colloid andInterface Science 1991, 144, 243. https://doi.org/10.1016/0021-9797(91)90255-7
  9. Goddard, E. D.; Hannan, R. B. J. Colloid and Interface Science1976, 55, 73. https://doi.org/10.1016/0021-9797(76)90010-2
  10. Stellner, K. L.; Amante, J. C.; Scamehorn, J. F.; Harwell, J. H. J.Colloid and Interface Science 1988, 123, 186. https://doi.org/10.1016/0021-9797(88)90235-4
  11. Adamson, A. W. Physical Chemistry of Surfaces, 5th Ed.; JohnWiley & Sons, Inc.: New York, 1990.
  12. Hoyer, H. W.; Marmo, A.; Zollner, M. Colloid and InterfaceScience 1984, 119, 1221.
  13. Rekker, R. F. The Hydrophobic Fragmental Constant; Elsevier:New York, 1977.

Cited by

  1. Surface Active Properties and LCST Behavior of Oligo(propylene oxide-block-ethylene oxide) Allyl Ether Siloxane Surfactants in Aqueous Solution vol.25, pp.8, 2004, https://doi.org/10.5012/bkcs.2004.25.8.1182
  2. Spontaneous Vesicle Formation in Aqueous Mixtures of Cationic Gemini Surfactant and Sodium Lauryl Ether Sulfate vol.26, pp.1, 2004, https://doi.org/10.5012/bkcs.2005.26.1.107
  3. Spectroscopic study on the precipitation of sodium alkyl sulfate with cetylpyridinium chloride vol.314, pp.2, 2007, https://doi.org/10.1016/j.jcis.2007.05.075
  4. Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007 vol.29, pp.2, 2008, https://doi.org/10.5012/bkcs.2008.29.2.450