• Title/Summary/Keyword: Soda glass

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The effect of Al2O3 on the isokom temperatures in soda-lime glass (소다석회유리에서 Al2O3가 isokom 온도에 미치는 영향)

  • Kang, Seung Min;Kim, Chang-sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.3
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    • pp.103-106
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    • 2022
  • The effect of Al2O3 on isokom temperatures in soda-lime glass is estimated by comparing calculated isokom temperatures using viscosity model proposed by Lakatos. Substitution of SiO2 with Al2O3 by 0.5 mol% raises the isokom temperatures by 3.1, 3.3, 3.6 and 7.2℃ at the viscosity of log η = 12.3, 10, 6.6 and 1 (Pa·s), respectively. Meanwhile, replacing 0.5 mol% of CaO with Al2O3 raises the isokom temperatures by 1.6, 2.3, 4.1 and 17.7℃ at the viscosity of log η = 12.3, 10, 6.6 and 1 (Pa·s), respectively.

The effect of SiO2, Na2O, and CaO on the isokom temperatures in soda-lime glass (소다석회유리에서 SiO2, Na2O, CaO가 isokom 온도에 미치는 영향)

  • Kang, Seung Min;Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.1
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    • pp.12-15
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    • 2022
  • The effect of SiO2, Na2O and CaO on isokom temperatures in soda-lime glass is estimated by comparing calculated isokom temperatures using viscosity model proposed by Lakatos. The isokom temperatures at the viscosity of log η = 12.3, 10, 6.6 and 1 (Pa·s) are lowered by 6, 7, 10 and 24℃, respectively, by the substitution of SiO2 with Na2O by 1 mol%. Meanwhile, replacing 1 mol% of SiO2 with CaO raises the isokom temperatures by 3~4 and 2℃ at the viscosity of log η = 12.3 and 10 (Pa·s), respectively, but lowers the temperatures by 1 and 21℃ at the viscosity of log η = 6.6 and 1(Pa·s), respectively.

Pozzolanic reaction of the waste glass sludge incorporating precipitation additives

  • You, Ilhwan;Choi, Jisun;Lange, David A.;Zi, Goangseup
    • Computers and Concrete
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    • v.17 no.2
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    • pp.255-269
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    • 2016
  • The waste glass sludge is a waste produced in the glass industry. It is in a dust form and disposed with water. In the disposal process, various cohesive agents are incorporated in order to precipitate the glass particles efficiently. In this paper, we investigate the pozzolanic reaction of the waste glass sludge incorporating precipitation additives experimentally. The consumption of calcium hydroxide, the setting time and the compressive strength and the pore structure were tested for two different types of the waste glass sludge depending on whether precipitation additives were used. It was found that the waste glass sludge incorporating the precipitation additives had a higher pozzolanic potential than the reference waste glass sludge without precipitation additives.

An Experimental Study on the Damage Mechanism of Particle Impact in a Scratched Glass (표면거칠기를 가진 유리의 입자충격 손상기구에 관한 실험적 연구)

  • Suh, Chang-Min;Chung, Seong-Muk;Lee, Mun-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.7
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    • pp.2196-2204
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    • 1996
  • The damage mechanism by the impact of steel ball on the soda-lime glass having a different surface roughness was investigated. An initiation and a propagation behavior of cracks formed by each impact velocity were quantitatively studied. A 4-point bending test was carried out to evaluate the remaining bending strength of a scratched soda-lime glass which impacted by the steel ball. As the surface roughness was increased, the shape of cracks became more irregular rather than those of the smooth specimens. The phenomenon of turning up in the wing of cone cracks occurred even at the lower velocity than the critical velocity caused the crushing. The threshold velocity of cracks initiation generally became lower than those of smooth specimen. An initiation and a propagation behavior of radial cracks had no relation with the direction of scratch on the surface. The remaning benidng strength of the scratched specimen according to impact velocity had no big difference compared with those of the smooth specimen.

Damage Mechanism of Particle Impact in a $Cr_2O_3$ Plasma Coated Soda-lime Glass ($Cr_2O_3$ 플라스마 용사 코팅된 유리의 입자충격에 의한 손상기구)

  • Suh, Chang-Min;Lee, Moon-Whan;Kim, Sung-Ho;Jang, Jong-Yun
    • Journal of Ocean Engineering and Technology
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    • v.12 no.3 s.29
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    • pp.49-59
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    • 1998
  • The damage mechanism of $Cr_2O_3$ plasma coated soda-lime glass and uncoated glass by steel ball particle impact was analyzed in this study. And the shape variation of the cracks was investigated by stereo-microscope according to the impact velocity and steel ball diameter. In order to improve the damage reduction effect by $Cr_2O_3$ coating layer, crack size was measured and surface erosion state was observed for both of two kinds of specimen after impact experiment. And the results were compared with each other. The 4-point bending test was performed according to ASTM D790 testing method to evaluate the effect of coating layer for bending strength variation. As a result, it was found that the crack size of $Cr_2O_3$ coated specimen was smaller than that of uncoated one, because of the impact absorption by interior pores in the coating layer and the load dispersion by the structural characteristic of the coating layer. For the specimens subjected to the steel ball impact, the bending strength of coated specimen was higher than that of uncoated specimen.

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Electrical and Optical Properties of Cu(InGa)$Se_2$ Thin Films Prepared on Difference Substrates (이종기판에 형성된 Cu(InGa)$Se_2$ 박막의 전기.광학적 특성)

  • Kim, S.K.;Lee, J.C.;Kang, K.H.;Yoon, K.H.;Park, I.J.;Song, J.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1625-1627
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    • 2000
  • Cu(InGa)$Se_2$(CIGS) thin film absorbers with various Cu/(In+Ga) atomic ratios were prepared by a three-stage process using a co-evaporation appartus. The effect of Na on the structural and electrical properties of CIGS films were studied and their effects on the CIGS/Mo thin film solar cells were investigated. Soda-lime glass and Corning glass were used as substrates to compare the effect of Na diffusion into CIGS film. The resistivity of CIGS films was not changed in the Cu-poor lesion due to diffusion of Na from soda-lime glass but was mainly determined by the surface resistivity controlled by excess Na.

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Preparation of Porous Glass by the Sintering (소결법에 의한 다공질유리의 제조)

  • 박용완;이준영
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.957-968
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    • 1994
  • Manufacturing process of porous glass by the filler method was studied. Commercial soda-lime-silicate glass powder was mixed with inorganic salt as the filler such as KCl, K2SO4, Na2SO4. Sintering shrinkages of mixed powders with the variation of sintering temperature were compared, and the effects of the fillers to shrinkages of mixed powder were increased in the order of Na2SO4${\mu}{\textrm}{m}$ of pore diameter were manufactured when the filler sizes 100~200 ${\mu}{\textrm}{m}$. The open pore volume of porous glass is determined by the quantity of filler and porous glasses having open pore volume between 30 and 70 vol% are available. Available sintering temperature range for preparation of porous glass is from the softening temperature of the glass powder to eutectic melting temperature of DTA curve of mixed powder.

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Effects of Sodium and Gallium on Characteristics of CIGS Thin Films and CdS/CIGS Solar Cells by Co-evaporation Method (Na확산과 Ga첨가에 따른 동시진공증발법으로 제조된 CIGS 박막과 CdS/CIGS 태양전지의 특성)

  • Kwon, S.H.;Lee, J.C.;Kang, K.H.;Kim, S.K.;Yoon, K.H.;Song, J.S.;Lee, D.Y.;Ahn, B.T.
    • Solar Energy
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    • v.20 no.2
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    • pp.43-54
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    • 2000
  • We prepared and characterized $Cu(In_{1-x}Ga_x)Se_2$(CIGS) films using a elemental co-evaporation method for absorbing layer of high efficiency thin film solar cells. The CIGS films deposited on a soda-lime glass exhibited low resistivity because of higher carrier concentration. Na was accumulated at the CIGS surface and the 0 and Se were also accumulated at the surface, suggesting that oxidation is a driving force of Na accumulation. The structure of CIGS film was modified or a secondary phase was formed in the Cu-poor CIGS bulk films probably due to the incorporation of Na into Cu vacancy sites. As the Ga/(In+Ga) ratio increased, the diffraction peaks of $Cu(In_{1-x}Ga_x)Se_2$ films were shifted to larger angle and splitted, and the grain size of $Cu_{0.91}(In_{1-x}Ga_x)Se_2$ films became smaller. All $Cu_{0.91}(In_{1-x}Ga_x)Se_2$ films showed the p-type conductivity regardless of the Ga/(In+Ga) ratio. Ag/n-ZnO/i-ZnO/CdS/$Cu_{0.91}(In_{0.7}Ga_{0.3})Se_2$/Mo solar cells were fabricated. The currently best efficiency in this study was 14.48% for $0.18cm^2$ area ($V_{oc}=581.5mV,\;J_{sc}=34.88mA$, F.F=0.714).

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A Study on the Flaking Mechanism of Glass (유리의 Flaking 생성기구에 관한 기구)

  • 김명석;심명재;김정환;이기강
    • Korean Journal of Crystallography
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    • v.11 no.4
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    • pp.224-230
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    • 2000
  • We have been investigated the flaking mechanism of the soda-line glass. The pH of aqueous solution approached to 10 and increased with reaction time by ion exchange reaction between Na/sup +/ ion of glass and H/sup +/ ion of aqueous solution under the conditions of below pH 9 of start solution. The relationship between the pH of solution and reaction time shows logarithm. Total dissolution reaction of glass components by OH/sup -/ ion in aqueous seems to be dominant after the pH solution reached to 10 and the dissolution rate linearly increased with reaction time. The above tow reactions are simultaneously occurred. The dissolved Ca/sup 2+/ ions are reprecipitated on the glass surface to Ca-compound. The flakes are formed by the separation of leached layer of glass due to the different thermal expansion coefficient.

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