• Title/Summary/Keyword: Sn addition

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Studies on the Releasing Effect of Cerium in Calcium Analysis by Atomic Absorption Spectrometry (원자흡수 분광법에 의한 칼슘분석에서 세륨의 해방효과에 관한 연구)

  • Kee Chae Park;Hee Seon Choi;Soo Han Kwon
    • Journal of the Korean Chemical Society
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    • v.29 no.2
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    • pp.129-136
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    • 1985
  • In the atomic absorption spectrometry using an air-acetylene flame, the interferences of Zr, Sn, Al, Sb, $SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$, on the calcium absorption and the repression of this interference by the addition of cerium have been studied. The interference by Zr, Sn, Al, Sb, $SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$ existed as the same concentration as calciurn ($3.0 {\times} 10^{-4}$M) in the sample solution are completely released by the addition of cerium twice as much as interfering cation. The interferences by the mixed interfering cations (Zr, Sn, Al and Sb) and by the mixed interfering anions ($SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$) are larger than by each interfering cation and anion, and the releasing effect by cerium ($1.5 {\times} 10^{-2}$M) is effective up to some degree of the concentration of mixed interfering cations and of mixed interfering anions. The releasing effect by cerium to the mixed solution of interfering cations and anions is applicable to quite wide range of concentration.

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Gene Expression Pattern during Early Embryogenesis and Transcriptional Activities of Estrogen Receptor-Related Receptor(ERR) in Sea Urchin, Strongylocentrotus nudus (둥근성게(Strongylocentrotus nudus) Estrogen Receptor-Related Receptor(ERR)의 초기 발생시 유전자 발현 패턴과 전사 활성)

  • Maeng, Se-Jung;Kim, Mi-Soon;Sohn, Young-Chang
    • Development and Reproduction
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    • v.13 no.4
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    • pp.249-256
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    • 2009
  • The estrogen receptor-related receptors (ERRs) are a group of nuclear receptor superfamily of transcription factors. ERRs and estrogen receptors (ERs) have overlapping affinities for coactivators and DNA binding sites, but differ markedly in ligand binding and activation. The three mammalian ERR genes have been implicated in diverse physiological processes ranging from placental development to maintenance of bone density, whereas the molecular diversity, function, and regulation of ERRs in non-mammalian species are not well understood. In the present study, to investigate the involvement of ERR in transcription and embryogenesis in marine invertebrates, a cDNA encoding ERR (SnERR) was cloned from the gonad in Strongylocentrotus nudus, by polymerase chain reaction (PCR). The amino acid sequence of SnERR showed high homology with that of S. purpuratus (91%). A phylogenetic tree clearly showed that SnERR is a member of the ERR family and clustered in echinodermata group as supported by a high bootstrap value. We examined gene expression of SnERR during embryonic development of S. nudus using real-time PCR. During the embryonic development, the mRNA of ERR was significantly high levels in early development stages (4~64 cell) and larval stages. The SnERR slightly activated transcription through the classical estrogen response elements (EREs) in the presence of genistein. In addition, peroxisome proliferator-activated receptor $\gamma$ coactivator (PGC)-$1\alpha$ knwon as a coactivator of ERR enhanced the snERR-mediated transactivation, suggesting that the PGC-$1\alpha$ is a coactivator of SnERR.

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Micorstructure and Microwave Dielectric Propertics of Ni-doped $(Zr_{0.8}Sn_{0.2})TiO_4$ Ceramics

  • Lee, Dal-Won;Sahn Nahm;Kim, Myong-Ho;Byun, Jae-Dong
    • The Korean Journal of Ceramics
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    • v.2 no.3
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    • pp.162-166
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    • 1996
  • The effects of NiO addition on the microstructure and microwave dielectric properties of ($Zr_{08}Sn_{02}$)$TiO_4$ (ZST) were investigated. With the NiO addition, a higher density of ZST ceramics than 95% of the theoretical values has been obtained in the sintering temperature range of 1400 to 150$0^{\circ}C$. Energy dispersive X-ray spectrometry (EDS) analysis of sintered specimen shows the presence of second phase at grain boundaries, which is considered to be $NiTiO_3$. Dielectric constant of the specimen is found to increase linearly with density. Q-values and TC$_r$ decrease with increasing NiO content. The variation of dielectric properties with NiO content is discussed in terms of the second phase. The ZST ceramics with 0.25 wt% NiO showed ${\varepsilon}_{\gamma}$=38, Q=7000 at GHz and TC$\gamma$=-0.5 ppm/$^{\circ}C$, comparable with the values obtained by the previous investigations.

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Evaluation of Cu Effect on Corrosion Characteristics of Zr Alloys (지르코늄합금의 부식특성에 미치는 Cu 영향 평가)

  • Kim Hyun Gil;Choi Byung Kyun;Jeong Yong Hwan
    • Korean Journal of Materials Research
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    • v.14 no.7
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    • pp.462-469
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    • 2004
  • The effect of Cu addition on the corrosion characteristics of Zr alloys that developed for nuclear fuel cladding in KAERI (Korea Atomic Energy Research Institute) was evaluated. The alloys having different element of Nb, Sn, Fe, Cr and Cu were manufactured and the corrosion tests of the alloys were performed in static autoclave at $360^{\circ}C$, distilled water condition. The alloys were also examined for their microstructures using the optical microscope and the TEM equipped with EDS and the oxide property was characterized by using X-ray diffraction. From the result of corrosion test more than 450 days, the corrosion rate of the Zr-based alloys was changed with alloying element such as Nb, Sn, Fe, Cr and especially affected by Cu addition. The corrosion resistance was increased with increasing the Cu content and the tetragonal $ZrO_2$ layer was more stabilized on the Cu-containing alloys.

Synergistic Inhibition of Carbon Steel Corrosion by Inhibitor-Blends in Chloride - Containing Simulated Cooling Water

  • Shaban, Abdul;Felhosi, Ilona;Vastag, Gyongyi
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.91-99
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    • 2017
  • The objective of this work was to develop efficient synergistic inhibitor combinations comprising sodium nitrite ($NaNO_2$) and an inhibitor-blend code named (SN-50), keeping in view of their application in industrial cooling water systems. The electrochemical characteristics of the carbon steel working electrode in simulated cooling water (SCW), without and with the addition of different combinations of the inhibitors, were investigated using electrochemical impedance spectroscopy (EIS), open circuit potential (OCP). The electrode surface changes were followed by visual characterization methods. It was demonstrated in this study that all the combinations of the inhibitors exhibited synergistic benefit and higher inhibition efficiencies than did either of the individual inhibitors. The addition of SN-50 inhibitor to the SCW shifted the OCP to more anodic values and increased the polarization resistance ($R_p$) values of carbon steel at all applied concentrations. The higher the applied sodium nitrite concentration (in the protection concentration range), the higher the obtained $R_p$ values and the inhibition efficiency improved by increasing the inhibitor concentration.

Effect of Lubricant Addition in Terms of Volume Fraction on Fabrication of Cu/Sn Bonded Diamond Micro Blades (다이아몬드 마이크로 블레이드 제조에 있어 부피비의 관점에서 본 윤활제 첨가 효과)

  • Moon, Jong-Chul;Kim, Song-Hee
    • Journal of the Korean institute of surface engineering
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    • v.43 no.1
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    • pp.41-45
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    • 2010
  • The effect of $MoS_2$ and graphite content on wear resistance and mechanical properties of Cu/Sn bonded diamond micro blades was comparatively investigated in terms of volume and weight fraction. For the evaluation of endurance and cutting performance, instantaneous electric power consumption and cumulative wear loss during cutting glass work piece at constant velocity were measured with the micro blades of the wide range of lubricant content. The energy consumption of blades for glass cutting decreased with the content of lubricants. Wear amount of blade in volume increased with the amount of lubricant addition. It was found to be relevant to the decrease in flexural strength and hardness with the amount of lubricants. With the same amount of lubricant content in volume fraction $MoS_2$ showed superiority in mechanical properties and cutting performance than graphite while graphite could result in stronger effect on lowering electric consumption during cutting work piece for the same weight percent fraction than $MoS_2$ because of lower density.

Study on a Novel Switching Pattern Current Control Scheme Applied to Three-Phase Voltage-Source Converters

  • Zhao, Hongyan;Li, Yan;Zheng, Trillion Q.
    • Journal of Power Electronics
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    • v.17 no.6
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    • pp.1563-1576
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    • 2017
  • This paper presents a novel switching pattern current control (SP-CC) scheme, which is applied in three-phase voltage-source converters (VSCs). This scheme can select the optimal output switching pattern (SP) by referring the basic principle of space vector modulation (SVM). Moreover, SP-CC is a method without a carrier wave. Thus, the implementation process is concise and easy. When compared with the conventional hysteresis current control (C-HCC) and the space vector-based hysteresis current control (SV-HCC), the SP-CC has the performances of faster dynamic response of C-HCC and less switching number (SN) of SV-HCC. In addition, it has less harmonic contents in the three-phase current, along with a lower switching loss and a higher efficiency. Moreover, the hysteresis bandwidth and Clarke conversion are not required in the SP-CC. The effectiveness of the presented SP-CC is verified by simulation and experimental test results. In addition, the advantages of the SP-CC, when compared with the C-HCC and SV-HCC, are verified as well.

The Manufacturing Techniques of the Stone Standing Maitreya Bodhisattva Bronze Wind Chimes of Gwanchoksa Temple, Nonsan (자연과학적 분석을 통한 논산 관촉사 석조미륵보살입상(論山 灌燭寺 石造彌勒菩薩立像) 청동풍탁(靑銅風鐸)의 제작 기법 연구)

  • LEE, Soyeon;CHUNG, Kwangyong
    • Korean Journal of Heritage: History & Science
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    • v.54 no.2
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    • pp.22-37
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    • 2021
  • The wind chime is a longstanding Jangeomgu (majestic article) found in Korea, China, and Japan. However, basic research on wind chimes is currently inadequate as it is difficult to estimate the time of production, and there are few relics. Therefore, this research morphologically classifies the eight bronze wind chimes decorating the baldachin of the Stone Standing Maitreya Bodhisattva of Gwanchoksa Temple, Nonsan. Based on this, the manufacturing techniques and production period are scientifically demonstrated. The synthesis of the research results reveals that the structure and characteristics of the wind chimes of the Stone Standing Maitreya Bodhisattva of Gwanchoksa Temple, Nonsan differ depending on their location on the baldachin. The four large-sized wind chimes on the lower-baldachin were manufactured by casting a Cu-Sn-Pb alloy, and they are estimated to have been made during the early period of Goryeo. The two medium-sized wind chimes of the upper-baldachin's northern direction were manufactured through forging a Cu-Sn or Cu-Sn-Pb alloy, and they appear to have a similar structure to the cylindrical wind chimes appearing during the latter period of Goryeo and the Joseon period. The two small-sized wind chimes of the upper-baldachin's southern direction were manufactured by casting a Cu-Sn-Pb alloy containing Zn, and based on the chemical composition of the alloy and the shape of the clapper, they are estimated to have been manufactured during the latter period of Joseon. Through the observation of microstructures and a chemical composition analysis, it is demonstrated that two wind chimes of the lowerbaldachin were manufactured by casting and slow cooling the alloy with an alloy ratio of Cu:Sn:Pb≒80:15:5. In addition, it is estimated that the wind chimes of the upper-baldachin's northeast direction were manufactured by forging an alloy of Cu-Sn with a similar alloy ratio to that of forged high tin bronze. The results of a comparative analysis of prior research on domestic wind chimes confirm that two wind chimes of the lower-baldachin have a similar composition ratio to the wind chime excavated from Wolnamsaji in Gangjin, containing an amount of tin that corresponds with ancient records. Having a similar alloy ratio to forged high tin bronze, the wind chimes of the upper-baldachin's northeast direction are the only instances among all of the wind chimes that have been examined to date that were manufactured using this forging method. The purpose of this research is to collect baseline data to verify and classify the manufacturing period of wind chimes according to their morphological characteristics based on scientific evidence. It is hoped that this data can be utilized for the restoration and conservation processes of the wind chimes of the Stone Standing Maitreya Bodhisattva of Gwanchoksa Temple, Nonsan.

Twitter Following Relationship Analysis through Network Analysis and Visualization (네트워크 분석과 시각화를 통한 트위터 팔로우십 분석)

  • Song, Deungjoo;Lee, Changsoo;Park, Chankwon;Shin, Kitae
    • The Journal of Society for e-Business Studies
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    • v.25 no.3
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    • pp.131-145
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    • 2020
  • The numbers of SNS (Social Network Service) users and usage amounts are increasing every year. The influence of SNS is increasing also. SNS has a wide range of influences from daily decision-making to corporate management activities. Therefore, proper analysis of SNS can be a very meaningful work, and many studies are making a lot of effort to look into various activities and relationships in SNS. In this study, we analyze the SNS following relationships using Twitter, one of the representative SNS services. In other words, unlike the existing SNS analysis, our intention is to analyze the interests of the accounts by extracting and visualizing the accounts that two accounts follow in common. For this, a common following account was extracted using Microsoft Excel macros, and the relationship between the extracted accounts was defined using an adjacency matrix. In addition, to facilitate the analysis of the following relationships, a direction graph was used for visualization, and R programming was used for such visualization.

Natural Dyeing of Fabrics with Guava (Psidium guajava L.) Leaf Extract II - Dyeability and Functional Property of Cotton Fabrics - (구아바 잎 추출액을 이용한 직물의 천연염색(II) - 면직물의 염색성과 기능성 -)

  • Han, Mi-Ran;Lee, Jeong-Sook
    • Fashion & Textile Research Journal
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    • v.14 no.2
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    • pp.320-330
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    • 2012
  • The natural dyeing of cotton fabrics with guava leaf extract was investigated. The temperature and time of dyeing are $40^{\circ}C$ and $90^{\circ}C$ for eighty minutes, respectively. In addition, the dyebath has been set at pH 5. Sn pre-mordanted fabrics showed the highest K/S value. Regardless of dyeing temperature, K/S values were high when Al, Cu, Fe-mordanted fabrics were dyed in post-mordanting and Sn-mordanted fabrics were dyed in pre-mordanting. The K/S value of dyeing fabrics could be increased with repetitive dyeing and mordanting. Compared to untreated dyed fabrics, the K/ S values of fabrics which had been treated with soybean milk, chitosan and gall nut tannin were increased. The changed surface colors of fabrics that were treated with soybean milk, chitosan and gall nut tannin were Y, YR and achromatic colors. Fabrics dyed with alkaline water extract showed reddish color. Sn-mordanted fabrics dyed with acidic water extract showed vivid yellowish color, and Cu-mordanted fabrics dyed with ethanol extract showed yellowish green color. In case of Sn-mordanted fabrics, the washing fastness was level 4. The dry cleaning fastness also showed very excellent result with level 4-5. The rubbing fastness was better in dry rubbing than in wet rubbing of the fabrics. For the light fastness, all dyed fabrics showed low fastness. For antibacterial activity, the powder of guava leaf extract and the dyed fabrics with guava leaf extract showed 99.9% of high antibacterial activity. All dyed fabrics showed higher deodorization and UV protection rate than control fabric.