• Title/Summary/Keyword: Smoke particulate

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Formation of particulate-phase and gas-phase polycyclic aromatic hydrocarbons in cigarette smoke

  • Shimazu, Haruki;Yata, Tsuyoshi;Ozaki, Naoto
    • Advances in environmental research
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    • v.6 no.3
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    • pp.189-202
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    • 2017
  • This study examines the concentrations of particulate-phase polycyclic aromatic hydrocarbons (PAHs) and gas-phase PAHs in sidestream cigarette smoke. Sixteen PAHs were determined for four brands of cigarettes. The volume of the experimental room is approximately $66m^3$. The air samples in the room were collected before and after smoking. The median total of particulate-phase and gas-phase PAH concentrations before smoking $3.13ng/m^3$and $48.0ng/m^3$, respectively. The median concentrations of them after smoking were $10.0ng/m^3$ and $79.6ng/m^3$. The median increases in the total of 16 PAH concentrations per cigarette during smoking were 271 ng for the particulate-phase PAHs and 1960 ng for the gas-phase PAHs. According to the relationship between particulate-phase and gas-phase PAHs after smoking, the two- to four-ring gas-phase PAHs and the higher molecular weight particulate-phase PAHs were probably formed from similar precursors. The relationship between the total suspended particulate (TSP) concentration and the increase in the total particulate-phase concentration of the 16 PAHs per cigarette during smoking were significantly positive. The increase in the total gas-phase concentration of the 16 PAHs tended to increase as the TSP concentration increased. This may indicates that decreasing the amount of TSP produced inhibit the production of PAHs during smoking.

Study on the pH of the Particulate matter in Cigarette Smoke (궐련담배 연기 응축물의 pH에 관한 연구)

  • 안기영;지상운
    • Journal of the Korean Society of Tobacco Science
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    • v.12 no.1
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    • pp.3-7
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    • 1990
  • Cigarette smoke is an aerosol consisted of both vapor and Particulate phases. In this study, the smoke condensates from several blended cigarettes were dissolved in water and the pH of the resulting solution was determined. The pH of the smoke condensate decreased with increase of puff number. In the beginning the pH decreased a little, while decreased remarkably from puff No.5 to puff No.10.

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An Experimental Study on the Emission Characteristics of Smoke from the Marine Four-Stroke Diesel Engines Operated in Constant Speed and Various Load Steps (선박용 4행정 디젤엔진의 정속 부하변동 운전시 매연배출특성에 대한 실험연구)

  • Oh, Sang-Hoon;Kim, Jae-Min;Kim, Hyun-Kyu;Yoo, Bong-Whan
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.19-20
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    • 2006
  • The emission of particulate matter from marine diesel engines is already restricted by regional regulations in some countries, and IMO has been preparing the regulation for particulate matter from 53rd MEPC. But confusingly, the gravimetric PM measurement methods and procedures are not established clearly yet. On the other hand, smoke measurement method is set clearly, and it can also indicate PM, though it is not direct gravimetric method. As the preparing step for regulations about PM, we measured the smote density of exhaust emission from the marine four-stroke diesel engines operated in constant speed and various load steps on the test-bed, using the filter-type smoke measuring instrument. As a result, we understood the omission characteristics of smoke from the engines. Additionally, to obtain the objective reliability of our measurement data, we carried out experimental studies about various measuring parameters that could affect the smoke density.

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Generation and Decay Phenomena of Environmental Tobacco Smoke in Controlled Experimental Atmosphere Chamber (환경이 조절되는 Chamber 내에서 Environmental Tobacco Smoke의 생성과 감소 현상)

  • 이문수;나도영;안기영;이규서
    • Journal of the Korean Society of Tobacco Science
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    • v.18 no.2
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    • pp.170-176
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    • 1996
  • This paper describes the generation and decay phenomena of gas, vapor and particulate phase components of environmental tobacco smoke in 18 m3 controlled experimental atmosphere chamber. Real time-weighted average concentration ratios of markers were determinated at no ventilation rates and sampling durations of starting to smoking 45 min. Average concentration of major ETS markers was no significant on the mainstream smoke contents of commercial cigarette and decay ratios were dependent on first order kinetic. RSP/nicotine, solanesol and 3-EP were good predictors of ETS concentration in the public indoor field. The concentration ratio of vapor phase and particulate phase components is highly variable to assessment of indoor air quality with ETS. Key words : ETS, chamber study, ETS markers.

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An Experimental Study on the Smoke Filtration System Using Water Injection and Vacuum Pump driven by Exhaust Gas (물 분사 및 배기가스 구동형 진공펌프를 이용한 매연여과장치에 대한 실험적 연구)

  • Lee, Han-Sung;Kim, Kyong-Hyon;Jung, Suk-Ho;Koh, Dae-Kwon
    • Journal of Power System Engineering
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    • v.17 no.3
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    • pp.17-22
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    • 2013
  • Diesel particulate filter has been adopted in new vehicle with diesel engine. Since the flow of exhaust gas was clogged as particulate matters were deposited in the filter, it have bad effects on a fuel consumption and power. It was investigated that a particulate filtering system with vacuum pump in the exhaust gas line could be free from clogging in previous research. In this study, the effects of water injection and position of inlet port in filtering system on reducing in particulate matter were investigated. It was noticed that particulate matter were decreased remarkable by water injection and moving the position of inlet port.

Determination of Free Radicals in Mainstream Cigarette Smoke by Electron Spin Resonance (전자스핀공명에 의한 담배연기 중 자유라디칼 측정)

  • Lee, Jeong-Min;Lee, John-Tae;Park, Jin-Won;Hwang, Keun-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.29 no.2
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    • pp.146-151
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    • 2007
  • Gas phase and particulate phase radicals in mainstream cigarette smoke were determined Electron Spin Resonance(ESR) spectroscopy. The free radicals in particulate phase have been investigated by benzene extract of Cambridge Filter Pad containing the smoke condensate. Spin trapping method in conjunction with ESR was used to investigate free radicals in the gas phase of cigarette smoke. Several analytical experiments were conducted in order to determine the optimal conditions for maximum signal intensities and reproducibility of results. All the tests were optimized and normalized using the University of Kentucky 2R4F reference cigarette. The optimal conditions were 0.6 mL for analysis volume of ESR, $4{\sim}5\;mL$ for collection volume of spin-adducts, and PBN for quantification of free radicals in gas phase. The radical levels of Kentucky 2R4F cigarettes were found $2.18{\times}10^{14}\;spins/cig.$ and $2.10{\times}10^{15}\;spins/cig.$ in gas phase.

A Simulation Study on Distributions of Smoke and Temperature in Accommdation on Shipboard Fires (선박의 거주구역 화재시 연기거동 및 온도변화에 관한 시뮬레이션 연구)

  • Kim, Won-Ouk;Kim, Jong-Su;Oh, Sae-Gin;Kim, Sung-Hwan
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.293-294
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    • 2006
  • This paper aims to simulate by FDS(Fire Dynamics Simulator) the distributions of temperature and smoke on fires in accommodations on boards. The paper focuses on analysis of temperature at fire occurrence and soot density. The purpose of this study is to predict the possibility of safe escape and efficient fire extinguishing method using fire simulation results.

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Study on the Regional Deposition of Smoke Particles in Human Respiratory Tract under the Variation of Fire and Breathing Conditions (화재 및 호흡조건 변화에 따른 연기입자의 인체 호흡기 내 영역별 침착량 분석)

  • Goo, Jaehark
    • Fire Science and Engineering
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    • v.33 no.6
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    • pp.95-104
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    • 2019
  • Smoke generated in a fire consists of gaseous substances and particulate matter, such as unburned carbon that adsorbed the gases. Human injury caused by inhalation of gaseous substances present in smoke is mostly short-term, whereas damage caused by inhalation of particulate matter is relatively a long-term phenomenon depending on the state of the gas-phase adsorption. The amount and location of the deposited smoke particles are important factors in estimating the damage caused to humans, which are affected by the breathing conditions as well as particle conditions, such as the size and concentration affected by the combustion conditions. In this study, in order to understand the characteristics of the deposition of smoke particles in the respiratory tract related to the study of human smoke inhalation injury, the number and mass concentration of smoke particles deposited in different areas of the respiratory tract for different fuel types, combustion conditions and breathing conditions were calculated. In addition, the amount of mass deposition of smoke in the respiratory tract for a certain period of inhalation was compared with the atmospheric standard of fine dust.

Study on Performance and An Exhaust Emission by Bio-Diesel Deterioration and Engine Load Rate at Heavy-Duty Diesel Engine (대형디젤기관에서 바이오디젤 열화와 엔진부하에 따른 배출가스특성 및 성능에 관한 연구)

  • Park, Man-Jae;Kim, Mi-Soo
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.3
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    • pp.56-63
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    • 2007
  • Modern diesel vehicle has to comply with the EURO IV, V regulation with low level of particulate matter and smoke emission Moreover, emission standards of each countries are becoming stringent in advanced countries such as USA and Europe. Because Bio-diesel is similar to diesel fuel, it is essential to judge the environmental and health effects deriving from the use of Bio-diesel in diesel engine. The deterioration characteristics of emission in accordance with aging vehicles must be regulated for Bio-diesel. Therefore, under 1200 driving hours, 220,000km driving distance condition and full load, the deterioration characteristics of emission were estimated. We could reduce sulfur contents of fuel, particulate matter and smoke emission by using Bio-diesel and conform the influence of engine performance, emission, and fuel consumption by Bio-diesel deterioration

Characteristics of Optimized Analytical Method of Hydrogen Cyanide in Cigarette Mainstream Smoke by Using Continuous Flow Analyzer(CFA) (Continuous Flow Analyzer(CFA)를 이용한 담배 주류연 중 Hydrogen Cyanide(HCN)의 최적 분석방법 구명)

  • Na, Seung-Ju;Eo, Sung-Je;Kim, Do-Yeon;Bock, Jin-Young;Hwang, Keon-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.31 no.1
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    • pp.39-44
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    • 2009
  • Hydrogen cyanide (HCN) is present in both the particulate and vapor phase of cigarette mainstream smoke. It is one of the 44 harmful substances on Hoffmann's list and is known to be a major ciliatoxic agent in cigarette mainstream smoke. Typically the determination of HCN in cigarette mainstream smoke has been done through colorimetric and electrochemical techniques, such as UV-spectrophotometry (UV), continuous flow analyzer (CFA), ion chromatography (IC) and capillary GC-ECD. In particular, CFA commonly has been using analysis hydrogen cyanide in cigarette smoke and the basic principle is pyridine-pyrazolone reaction. In this study, the more optimized analytical method is suggested isonicotinic acid-pyrazolone reaction method than previous pyridine-pyrazolone reaction method, a commonly used method for the determination of cyanide in water and air, by CFA. Sample collection was optimized by trapping particulate and vapor phase of smoke separately. The optimum NaOH concentration of the trapping solution was shown to be 0.2 M. HCN was stable up to 6 hours in this concentration but only 3 hours in 0.1 M solution. The sensitivity of this method was fairly good and it might be used in analysis of HCN in cigarette mainstream smoke.