• 한국세라믹학회지
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• 제39권9호
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• pp.878-883
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• 2002

Mn계 층상 perovskite 세라믹스 $La_{2.1}Sr_{1.9}Mn_3O_{10}$의 전기저항 및 열기전력의 온도의존성을 측정하였다. 실험결과 $La_{2.1}Sr_{1.9}Mn_3O_{10}$의 전기전도는 Emin-Holstein의 단열 small polaron model에 의하여 이루어지고 있었다. Curie 온도이상의 small polaron hopping 영역에서의 열기전력 측정결과는 이론적인 $Mn^{4+}$ 가전자 관점에서 예측되었던 열기전력 측정 결과와 거의 동일하였다. 이 실험결과 역시 $La_{2.1}Sr_{1.9}Mn_3O_{10}$ 세라믹스의 전기전도가 small polaron에 의하여 이루어지고 있음을 의미한다.

• 한국재료학회지
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• 제18권1호
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• pp.26-31
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• 2008

The dc resistivity and thermoelectric power of bilayered perovskite $La_{1.4}(Sr_{0.2}Ca_{1.4})Mn_2O_7$ were measured as a function of the temperature. In the ferromagnetic phase, ${\rho}(T)$ was accurately predicted by $a_0+a_2T^2+a_{4.5}T^{4.5}$ with and without an applied field. At high temperatures, a significant difference between the activation energy deduced from the electrical resistivity and thermoelectric power, a characteristic of small polarons, was observed. All of the experimental data can be feasibly explained on the basis of the small polaron.

• 한국세라믹학회지
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• 제39권3호
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• pp.294-298
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• 2002

다결정 층상 페로브스카이트형 $La_{2.1}Sr_{1.9}Mn_3O_{10}$를 성공적으로 합성하였으며, $La_{2.1}Sr_{1.9}Mn_3O_{10}$의 열기전력, 전기전도 및 자기적 특성을 조사하였다. 0.85T의 자장의 인가 시 자기전이 온도 $T_c$보다 매우 낮은 120K에서 금속-비금속전이 및 약 120%의 음의 $MR(-{\Delta}{\rho}/{\rho}_0)$이 관측되었다. 고온영역에서 small polaron의 특징중의 하나인 매우 큰 전기적 저항 및 열기전력의 활성화 에너지 차가 관측되었다. 전체적인 실험 결과는 small polaron hopping 모델로 설명가능 하였다.

• 한국세라믹학회지
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• 제41권11호
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• pp.858-863
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• 2004

본 연구는 입방정 L $a_{2}$ 3/Ti $O_{2.84}$ 세라믹스의 전기전도율, 열기전력 그리고 자기적 특성에 대하여 조사하였다. 350 K 이하의 은도영역에서의 입방정 L $a_{2}$ 3/Ti $O_{2.84}$ 세라믹스의 열기전력은 음으로 나타났다 열기전력은 온도의 증가와 더불어 선형적으로 증가하여 A+BT의 형태로 표현가능 하였으며, Emin과 Wood가 제안한 모델과 잘 일치하였다. 이와 같은 열기전력의 온도의존성은 L $a_{2}$ 3/Ti $O_{2.84}$ 세라믹스의 전도 carrier가 small polaron임을 의미한다. L $a_{2}$ 3/Ti $O_{2.84}$ 세라믹스는 실온 이하의 특정온도에서 variable range hopping에서 small polaron hopping으로 변화하였다. 저온영역에서는 직류전도 기구해석은 Mott의 접근방식을 이용하였다. Mott의 보조변수 해석결과 Fermi면에서의 상태밀도 [N( $E_{F}$)]는 3.18${\times}$$10^{20}$ $cm^{-3}$e $V^{-1}$이었으며, 무질서에너지 $W_{d}$는 0.93로 고온에서의 활성화 에너지 보다 매우 크다. 200K와 300K온도 범위에서 log($\sigma$T)와 1/T의 직선 관계가 존재 하였으며, small polaron의 hopping energy는 0.15 eV였다.

• 한국재료학회지
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• 제24권11호
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• pp.604-609
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• 2014

The thermoelectric power and dc conductivity of $La_{2/3+x}TiO_{3-{\delta}}$ (x = 0, 0.13) were investigated. The thermoelectric power was negative between 80K and 300K. The measured thermoelectric power of x = 0.13 increased linearly with increased temperatures and was represented by $S_0+BT$. The x = 0 sample exhibited insulating behavior, while the x = 0.13 sample showed metallic behavior. The electric resistivity of x = 0.13 had a linear temperature dependence at high temperatures and a T3/2 dependence below about 100K. On the other hand, the electric resistivity of x = 0 has a linear relation between $ln{\rho}/T$ and 1/T in the range of 200 to 300K, and the activation energy for small polaron hopping was 0.23 eV. The temperature dependence of thermoelectric power and the resistivity of x = 0 suggests that the charge carriers responsible for conduction are strongly localized. This temperature dependence indicates that the charge carrier (x = 0) is an adiabatic small polaron. These experimental results are interpreted in terms of spin (x = 0.13) and small polaron (x = 0) hopping of almost localized Ti 3d electrons.

• 한국재료학회지
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• 제19권4호
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• pp.186-191
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• 2009

Thermoelectric power and resistivity are measured for the perovskite $LaNi_{1-x}Ti_xO_3$ ($x{\leq}0.5$) in the temperature range 77 K - 300 K. The measured thermoelectric power of $LaNi_{1-x}Ti_xO_3$ ($x{\leq}0.5$) increases linearly with temperature and is represented by A + BT. The x = 0.1 sample showed metallic behavior, the x = 0.3 showed metal and insulating transition around 150 K, and x = 0.5 showed insulating behavior the over the whole temperature range. The electrical resistivity of x = 0.1 shows linear temperature dependence over the whole temperature range and $T^2$ dependence. On the other hand, the electrical resistivity of x = 0.3 shows a linear relation between $ln{\rho}$ and $T^{-1/4}$ (variable range hopping mechanism) in the range of 77 K to 150 K. For x = 0.5, the temperature dependence of resistivity is characteristic of insulating materials; the resistivity data was fitted to an exponential law, such as ln(${\rho}/T$) and $T^{-1}$, which is usually attributed to a small polaron hopping mechanism. These experimental results are interpreted in terms of the spin polaron (x = 0.1) and variable range hopping (x = 0.3) or small polaron hopping (x = 0.5) of an almost localized $Ni^{3+}$ 3d polaron.

• 한국세라믹학회지
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• 제40권9호
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• pp.849-854
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• 2003

80-373 K의 온도범위에서 La$_{2.1}$ Sr$_{1.9}$ Mn$_3$O$_{10}$ 의 열기전력의 온도의존성을 조사하였다. 저온강자성영역에서 열기전력(S)의 온도의존성은 광범위한 온도영역에서 S＝S$_{0}$ ＋S$_{1.5}$ T$^{1.5}$ ＋S$_4$T$^4$로 표현할 수 있었다. 강자성 전이온도 이하에서 열기전력의 완만한 피크 및 복잡한 온도의존성은 편력성 강자성체에서 예상되는 electron-magnon 산란으로 이해할 수 있으며, 고온에서의 열기전력은 Mott의 small polaron hopping 모델로 설명 가능하였다.

• 한국재료학회지
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• 제20권3호
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• pp.161-166
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• 2010

The ac, dc conductivity and dielectric properties of $DyCoO_3$ were reported in the temperature range of 77 - 300K and in the frequency range of 20 Hz - 100 kHz. It was observed that at low temperature, ac conductivity is much higher than dc conductivity and the hopping carrier between localized states near the Fermi level was the dominant loss mechanism. A comparison of the measured ac conductivity $\sigma(\omega)$ was made with some of the models of hopping conductivity of the proposed earlier in the literature. It was observed that in $DyCoO_3$ the measured ac conductivity, over the entire frequency and temperature region, can be explained reasonably well by assuming two contributions $\sigma_1(\omega)$ and $\sigma_2(\omega)$ to the measured $\sigma(\omega)$. The first, $\sigma_1(\omega)$, which dominates at low temperature, may be due to impurity conduction in a small polaron; the second, $\sigma_2(\omega)$, which dominates at higher temperatures, depending on the frequency of measurements, may be due to the hopping of a small polaron and is reasonable for the dielectric relaxation peak.

• 한국전기전자재료학회논문지
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• 제14권5호
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• pp.376-382
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• 2001

Magnetic and transport properties in the ceramic specimen of L $a_{0.7}$S $r_{0.3}$Fe $O_3$ with orthohombic structure has been investigated. Weak ferromagnetism has been observed in a ceramic sample of L $a_{0.7}$S $r_{0.3}$Fe $O_3$. Large dielectric relaxation of Debye type is observed in paramagnetic states within the temperature range of 130K~200K. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dispersion is related to holes hopping between F $e^{3+}$ and F $e^{4+}$ ions. The temperature dependencies of thermoelectric power and Dc conductivity suggest that the charge carrier responsible for the conduction are strongly localized. These experimental results have been interpreted in terms of a hopping process involving small polaron.n.laron.n.

• 한국세라믹학회지
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• 제36권8호
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• pp.843-847
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• 1999

The dc resistivity dc magnetization and thermopower of layered perovskite La1.6Ca1.4Mn2O7.07 have been studied. The ceramic sample of La1.6Ca1.4Mn2O7.07 undergoes the metal-insulator transition at 120K while a first-order phase transition from a ferromagnetic phase to a paramagnetic phae is observed at 260 K=TC This behavior is quite different from that of the well-known double exchange ferromagnets such as La1-xCaxMnO3 This phenomenon could be understood by considering the effects of the anisotropic double exchange interaction caused by two dimensional Mn-O-Mn networks in this materials. The dc magnetization between 120K and 250K is nearly constant and decreases rapidly with increasing temperature above 250K The measurements of dc resistivity and thermopower indicate that Zener polaron hopping conduction takes place above 260 K.