• Journal of the Korean Chemical Society
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• v.52 no.3
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• pp.217-222
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• 2008

We investigate the kinetics of diffusion-influenced catalytic reactions occurring in small reaction volume. From a simple exact model study, we find that the reaction rate coefficient decreases with the size of reaction volume. The explicit expression for the average reaction rate constant is presented, which can be regarded as a generalization of well-known Collins-Kimball rate constant into the reactions occurring in a small reaction volume. It turns out that the traditional diffusion influenced reaction dynamics is followed by a single exponential relaxation phase with a rate constant dependent on the reaction volume for the catalytic reactions occurring in small reaction volumes.

• Journal of the Korean Ceramic Society
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• v.45 no.8
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• pp.439-442
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• 2008

A series of reaction-sintered SiC was fabricated from preforms with varying volume fractions of two resin-coated SiC particles of different sizes (63 and $18{\mu}m$). The electrical resistivity and mechanical strength were eventually optimized at the small particle volume fraction of $0.3{\sim}0.4$, at which point the porosity of the preform was minimized. This study experimentally proves that additional processes after the formation of the preform, such as silicon infiltration and reaction sintering, do not apparently alter the optimum volume fraction of the preform packing, predicted by an existing analytical model based on solid packing. Thus, the volume fraction of particles of different sizes can be determined practically through the solid packing model to fabricate RSSCs with optimal properties.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.212-216
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• 2000

Combustion phenomenon in scale-downed combustor is investigated. As the combustor volume decreases surface to volume ratio increases. for increased surface to volume ratio means increased heat loss and this increased heat loss affects reaction in combustion chamber. Plastic mini combustor is made. Stoichiometricaly premixed Hydrogen I air gas is used as fuel. Initial chamber pressure and chamber size are varied and the effects are evaluated. Peak pressure decreases with the decrease in chamber height. As initial chamber pressure decreases peak pressure decreases. And this change is more important than scale down effect till the chamber height of 1mm. With this result and further information following the experiments design parameter for micro engine can be established.

• Proceeding of Spring/Autumn Annual Conference of KHA
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• 2004.11a
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• pp.355-360
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• 2004

This study is a research that evaluates and analyzes on the subjective reaction of Won buddhism small sanctum through psychoacoustics experiment. For doing it, after choosing of 5 Won buddhism small sanctums of which its building volume at $400m^{3}{\sim}650m^{3}$, a psychoacoustics experiment has been conducted. Based on those A, B, C, E temple-halls which appeared as higher than 'average' in the result of subjective reaction evaluation of the Won buddhism small sanctum through psychoacoustics experiment, it could be classified as the conclusion of the factor analysis: the first factor is 'space sense of sound', the second factor is 'intimacy-feeling with sound' and the third factor is 'clearness of sound', respectively.

• Journal of environmental and Sanitary engineering
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• v.14 no.1
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• pp.54-61
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• 1999

The industrial techniques of ultrasound have been used in the various fields, such as cleaning, medical surgery, emulsification, cell disruption etc. Especially the application of cell disruption was interested in the field of disinfection process in water by ultrasonic irradiation. It has been recognized that the ultrasounds are irradiated in aqueous solution, cavitation bubbles are generated and shock waves of high temperature and pressure are emitted as the bubbles are developed and finally broken, which function as a energy source to promote reaction efficiencies of various kinds of chemical reactions such as disinfection reaction in water. Therefore, this study was performed to apply the ultrasound for the disinfection method of infected drinking raw water and to discuss the limiting factors such as pH, sample volume and reaction temperature influenced on the removal efficiency of E. coli from experimental analysis of the results obtained in bench-scale plant. For the experiments to measure the influence of reaction parameters in the ultrasonic disinfection process, escalated reactivity of aqueous solutions was excellent when pH in aqueous solution was low, and sample volume was small. On the contrary, the reactivity of disinfection became elevated when reaction temperature was high. It was found that the rate constant of disinfection reaction was applied by Chick's law, reaction kinetics of Chick's law was irreversible and pseudo-first order at all the tested conditions.As a conclusion it appeared that the technology using ultrasonic irradiation can be applied to the treatment of disinfection in infected water which are difficult to be treated by conventional methods.

• Journal of Microbiology and Biotechnology
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• v.12 no.1
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• pp.149-152
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• 2002

The effect of pressure on the catalytic properties of glutamate racemase from Aquifex pyrophilus, an extremophilic bacterium, was investigated. The activation volume for the overall reaction $({\Delta}V^{\neq})$ and catalysis $({{Delta}V_{cat}}^{\neq})$ was -96.97 ml/mol and 4.97 ml/mol, respectively, while the reaction volume for the substrate binding (${\Delta}V_{K_m^-1}$) was -101.94 ml/mol. The large negative ${\Delta}V^{\neq}$ for the overall reaction indicated that the pressurization of glutamate racemase resulted in enhanced catalytic efficiencies. In addition, this value was also due to the large negative ${Delta}V_{K_m^-1}$ for the substrate binding. The negative value of ${Delta}V_{K_m^-1}$ implied that the conformational changes in the enzyme molecule occurred during the substrate binding process, thereby increasing the degree of hydration. The small value of ${{Delta}V_{cat}}^{\neq}$suggested that the pressure did not affect the glutamate racemase catalysis after the substrate binding.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.5
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• pp.656-665
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• 2004

An Ozone reaction model combined with CFD(Computational Fluid Dynamics) technique was developed in this research, in the simulation of ozonation, hydrodynamic behavior as well as reaction model is important because ozone is supplied to treated water as gas ozone. In order to evaluate hydrodynamic behavior in an ozone contactor, CFD technique was applied. CFD technique elucidated hydrodynamic behavior in the selected ozone contactor, which consisted of three main chambers. Three back-mixing zones were found in the contactor. The higher velocities of water were observed in the second and third compartments than that in the first compartment. The flow of the opposite direction to the main flow was observed near the water surface. Based on the results of CFD simulation, the ozone contactor was divided into small compartments. Mass balance equations were established were established in each compartment with reaction terms. This reaction model was intended to predict dissolved ozone concentration, especially. We concluded that the model could predict favorably the mass balance of ozone, namely absorption efficiency of gaseous ozone, dissolved ozone concentration and ozone consumption. After establishing the model, we discussed the effect of concentration of gaseous ozone at inlet, temperature and organic compounds on dissolved ozone concentration.

• Journal of Korea Water Resources Association
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• v.33 no.1
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• pp.73-85
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• 2000

A water quality model was developed for small stream at a upland agricultural watershed. A control volume method was employed to digest the severe variability of stream shape, water quality and discharge at small streams. We estimated optimum reaction coefficients and model structure using a random number generation technique. The index of agreement and coefficient of efficiency were introduced for the model calibration criterion. As the result, the reliability of model parameter estimation could be improved. The applicability of model was tested by a set of sampling results at Yongduckchun in Kimhae. The variability of water quality reaction coefficient was explored through the observed data and using the developed model. model.

• Nuclear Engineering and Technology
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• v.4 no.3
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• pp.186-193
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• 1972

For efficient micro scale syntheses of Rose $Bengal-^{131}I$, $Hippuran-^{131}I$, and $H.S.A.-^{131}I$, the dependence of labelling yields on pH, on salt contents, and on the volume of buffer solution in the reaction mixtures as well as the reaction apparatus were studied. pH of 5.6 was optimum for preparation of both Rose $Bengal-_{131}I$ and Hippuran $-^{13}I$ but pH of 8.5 was optimum for preparation of $H.S.A.-^{131}I$. Salt in the reaction mixtures hindered drastically the formation of $Hippuran-^{131}I$ but it slightly increased the labelling yield of H.S.A.. The compactly closed reaction vessels were effective for preparations of both Rose $Bengal-^{131}I$and $Hippuran-^{131}I$ in small volume. Thereupon, the labelling procedures were modified to bring about higher labelling yields and better reproducibilities. By these newly established procedures, the labelling yields of Rose $Bengal-^{131}I$ and $Hippuran-^{131}I$ could be increased even with the home-produced sodium $iodide-^{131}I$ solution containing reducing agent.

• Computers and Concrete
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• v.16 no.1
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• pp.37-48
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• 2015

Alkali aggregate reaction affects numerous civil engineering structures and causes irreversible expansion and cracking. This work aims at developing model to predict the potential expansion of concrete containing alkali-reactive aggregates. First, the paper presents the experimental results concerning the influence of particle size of an alkali-reactive aggregate on mortar expansion studied at 0.15-0.80 mm, 1.25-2.50 mm and 2.5-5.0 mm size fractions and gives data necessary for model development. Results show that no expansion was measured on the mortars using small particles (0.15-0.80 mm) while the particles (1.25-2.50 mm) gave the largest expansions. Finally, model is proposed to simulate the experimental results by studying correlations between the measured expansions and the size of aggregates and to calculate the thickness of the porous zone necessary to take again all the volume of the gel created by this chemical reaction.