• The Journal of the Petrological Society of Korea
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• v.2 no.2
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• pp.130-138
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• 1993

Kyeonggi Gneiss complex forming Korean Precambrian basement is mainly composed of high-grade metasedimentary rocks, which are generally difficult to determine their absolute ages. We examined the feasibility of successive absolute age determination method for the marbles from this basement. We used hydrochloric acid for the selective dissolution of carbonate minerals from the marbles. Trace element analysis shows that most of Zr and Rb are concentrated in the residues. U in the residue is more abundant than that in HC1-dissolved parts. Pb, Sr, Sm, and Nd are somewhat evenly distributed between HC1-dissolved parts and the residues. }Th shows rather complex behavior. Sr isotopic compositions of the HC1-dissolved parts reveal mixing with Sr from non-carbonate minerals having much higher $^{87}Sr/^{86}Sr$ ratios. We suggest that the most reliable method in the age determination for the marbles of this area is measuring Pb isotopic ratios of the pieces of pure marbles.

• The Journal of the Petrological Society of Korea
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• v.9 no.3
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• pp.121-141
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• 2000

Granitic and pophyroblastic gneisses are widely distributed in the Seungju-Suncheon area, the southwestern part of the Sobacksan Massif. Two groups of metamorphic P-T conditions are recognized from granitic gneiss. $622-760^{\circ}C/6.2~7.4\;kbar$(Group I) are estimated from garnet cores and samples with weak retrograde metamorphism. $606~785^{\circ}C/3.7~5.4\;kbar$(Group II) are estimated from garnet rims which have lower pyrope and higher spessartine contents due to the effect of retrograde metamorphism. The metamorphic P-T conditions estimated from porphyroblastic gneiss are $489~669^{\circ}C$, 2.1~4.8 kbar which are similar to the P-T conditions of Group II in the granitic gneiss. The whole rock-garnet Sm/Nd isotopic ages determined from granitic and porphyroblastic gneisses are, respectively, $1417{\pm}52\;Ma\;and\;1421{\pm}14\;Ma$. These date indicate that intermediate-P/T type metamorphism represented by Group I may have occurred between the intrusion of granite gneiss and the intrusion of porphyroblastic gneiss(between 1890 Ma~2120 Ma) and two gneisses experienced low-P/T type metamorphism after the intrusion of porphyroblastic gneiss at 1417~1421 Ma.

• The Journal of the Petrological Society of Korea
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• v.24 no.4
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• pp.365-371
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• 2015

The rare earth element(REE)s play an important role in understanding of rock formation and evolution because of their similar geochemical behaviors. Sm and Nd are more useful than other REEs because Sm-Nd isotopic system has important applications for geochemical interpretation like age dating and crustal evolution. These studies require a chromatographic technique for Sm and Nd separation from the geological samples. Ln-resin method using 0.25 M HCl as the eluent is widely used for Nd separation. However, this technique has a disadvantage of the poor elemental selectivity that the Nd fraction contains Ce as a tailing of the previous fraction. This technical report is a comparison study on the effect of eluent concentration between 0.25 M HCl and 0.15 M HCl on the separation of Nd with Ln-resin method for improving the technique of Nd separation. The results showed that the separation of Ce and Nd using 0.15M HCl as the eluent was not effective compared to the separation using 0.25 M HCl. In this experiment, we could confirm that the dilution of eluent might not be effective on the high purity separation of Nd with Ln-resin method.

• The Journal of the Petrological Society of Korea
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• v.9 no.1
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• pp.29-39
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• 2000

For the determination of metamorphic age of the metamorphic rocks distributed in the Ji-san area of Youngnam massif, Sm and Nd isotopic compositions were analyzed for the whole rock and garnet separates. As the result, we obtained 1799 + 11 Ma from the porphyroblastic gneiss, 1776 +30 Ma from the metapelite, 1714+35 Ma from the mafic granulite xenolith within the porphyroblastic gneiss, and 1776+30 Ma from the metapelite occurred as a xenolith within the quartzofeldspathic gneiss. There have been reports of geologic ages similar to such metamorphic ages of Jirisan area from the other portion of the Youngnam massif, which reveals that very intense metamorphism took place over the vast area of Youngnam massif during the period of 1.7-1.8 Ga ago. The granulite facies metomorphism of the Gyeonggi massif also shows the age similar to this period. Such resemblance in their metamorphic ages suggests that these massifs experienced similar tectonothermal events occurred at about the same Precambrian periods, which implies the possibility that the extension of the collision belt between the north and south China blocks does not extend through some places between the Youngnam and Gyeonggi massifs. On the other hand a quarzofeldspathic xenolith of porphyroblastic gneiss show 1928 +42 Ma which is older than above age of the metamorphism and is identical with the zircon U-Pb age of porphyroblastic gneiss indicating the formation age of the protolith of the porphyroblastic gneiss.