• 마이크로전자및패키징학회지
• /
• 제9권2호
• /
• pp.19-25
• /
• 2002

저온소결기판을 위하여 green sheet를 제조하기 위한 조성으로 $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$를 기초 조성으로 선정하였다. 조합 후 용융하여 만들어진 모유리는 열분석을 통하여 최적 핵형성 온도와 최고 결정성장 온도를 도출하였으며 핵형성 온도는 전이온도와 같은 $490^{\circ}C$로 선정하였다. 결정화 유리를 제조하기 위하여 두 단계의 열처리를 실시하였으며 , 생성된 결정상은 Lithium fluorhectorite와 Lithium boron fluorphlogopite결정상 이었다. 계속적으로 제조된 결정화 유리는 water swelling 현상을 이용하여 분말화를 실시하였으며 평균 입도크기는 2.574 $\mu\textrm{m}$이었다. glass ceramics 분말은 물에 넣으면 반응하여 팽창하는 것과 함께 끈적끈적한 sol이 생성되는 현상을 이용하여 green sheet 제조를 위한 slurry를 제조하였다. Tape casting을 위한 slurry의 결정화 유리 분말 대비 용매의 최적 비율은 100:18이었고, 슬러리의 점도는 11,000~14,000cps 이었다. KCl 1 M용액 10min담지 시편에 대해서는 $900^{\circ}C$에서, 20 min담지 시편에 대해서는 $800^{\circ}C$에서 각각 치밀한 소결성을 나타내었다.

• 콘크리트학회논문집
• /
• 제12권2호
• /
• pp.99-107
• /
• 2000

This research investigates experimentally an effect on the properties of the high flowing concrete to be poured in the under-ground slurry wall of Inchon LNG receiving terminal(#213,214-TK) according to variations of concrete materials. Variables for sensitivity test were selected items as followings. 1) Concrete temperature (3cases), 2) Unit water (5cases), 3) Fineness modulus of fine aggregate (5cases), 4) Particle size of lime stone powder (3cases), 5) Replacement ratio of blast-furnace slag (4cases) and 6) Addition ratio of high range water reducing agent (5cases). And fresh conditions of the super flowing concrete should be satisfied with required range including slump flow(65$\pm$5cm), 50cm reaching time of flow(4~10sec), V-lot flowing time(10~ 20sec), U-box height(min. 300mm) and air content(4$\pm$1%). As results for sensitivity test, considered flow-ability, self-compaction and segregation resistance of the high flowing concrete, material variations and conditions of fresh concrete should be satisfied with the range as follwings. 1) Concrete temperature are 10~2$0^{\circ}C$(below 3$0^{\circ}C$), 2) Surface moisture of fine aggregate is within $\pm$ 0.6%, 3) Fineness modulus of fine aggregate is 2.6$\pm$0.2, 4)Replacement ratio of blast-furnace slag is 45~50% and 5) Addition ratio of high range water reducing agent is within 1%. Based on the specification for quality control, we successfully finished concrete pouring on the under-ground slurry wall having 75,000㎥(#213,214-TK) and accumulated real date in site.

• KCI Concrete Journal
• /
• 제14권3호
• /
• pp.121-129
• /
• 2002

This study investigates experimentally into the design factors and quality variations having an effect on the properties of the combined high flowing concrete to be poured in the slurry wall of Inchon LNG in-ground receiving terminal. Especially, high belite cement and lime stone powder as cementitious materials and viscosity agent in order to improve self-compaction and hydration heat are used in this study. Water-cement ratio(W/C), fine aggregate volume ratio(Sr) and coarse aggregate volume ratio(Gv) as design factors of the combined high flowing concrete are applied to determine the optimum mix design proportion. Also quality variations for sensitivity test are selected items as followings. (1)Surface moisture(5cases) and (2)Fineness modulus of fine aggregate(5cases), (3)Concrete temperature(3cases), (4)Specific surface(3cases) and particle size of lime stone powder. As experimental results, water-cement ratio, fine and coarse aggregate volume ratio are shown as the optimum range 51%, 43% and 53% separately considering site condition of slurry wall. Also quality factors by sensitivity test should be controlled in the following ranges. (1) Surface moisture :to.67% and (2)Fineness modulus 2.6$\pm$0.2 of fine aggregate, (3)Concrete temperature l0-20t, (4) Specific surface 6,000$\textrm{cm}^2$/g and particle size 9.7$\pm$1.0${\mu}{\textrm}{m}$ of lime stone powder. Based on the results of this study, the optimum mix design proportion of the combined high flowing concrete are selected and poured successfully in the slurry wall of LNG in-ground tank.

• Transactions on Electrical and Electronic Materials
• /
• 제8권1호
• /
• pp.5-10
• /
• 2007

Using a reference slurry, ammonium dodecyl sulfate (ADS), an anionic and environmentally friendly surfactant, was investigated as an alternative to BTA for its inhibition and lubrication characteristics. Results demonstrated that the inhibition efficiency of ADS was superior to that of BTA. Coefficient of friction (COF) was the lowest when the slurry contained ADS. This suggested that adsorbed ADS on the surface provided lubricating action thereby reducing the wear between the contacting surfaces. Temperature results were consistent with the COF and removal rate data. ADS showed the lowest temperature rise again confirming the softening effect of the adsorbed surfactant layer and less energy dissipation due to friction. Spectral analysis of shear force showed that increasing the pad-wafer sliding velocity at constant wafer pressure shifted the high frequency spectral peaks to lower frequencies while increasing the variance of the frictional force. Addition of ADS reduced the fluctuating component of the shear force and the extent of the pre-existing stick-slip phenomena caused by the kinematics of the process and collision event between pad asperities with the wafer. By contrast, in the case of BTA, there were no such observed benefits but instead undesirable effects were seen at some polishing conditions. This work underscored the importance of real-time force spectroscopy in elucidating the adsorption, lubrication and inhibition of additives in slurries in CMP.

• Journal of the Korean Wood Science and Technology
• /
• 제43권5호
• /
• pp.578-590
• /
• 2015

The present study examines the influence of slurry composting and biofiltration liquid fertilizer (SCBLF) treatment on the biomass characteristics of yellow poplar, and the optimization of organosolv pretreatment for sugar production. After SCBLF treatment, total exchangeable cation contents of yellow poplar was increased from $3.1g\;kg^{-1}$ to $4.4g\;kg^{-1}$, and as a result, biomass production of yellow poplar was also enhanced by 82.3%. Organosolv pretreatment was conducted with three independent variables: 1) reaction temperature: $133.2^{\circ}C$ to $166.8^{\circ}C$; 2) acid concentration: 0.2% to 1.8%; and 3) reaction time: 1.6 min to 18.4 min. Reaction temperature was the most significant variable in water insoluble solid (WIS) recovery rate. High overall sugar yield was attained from pretreatment conditions approximately 50% of WIS recovery rate, and the highest overall glucose yield (44.0%) was achieved from pretreatment at $140^{\circ}C$ with 1.5% acid concentration for 5 min. Consequently, 21.1% of glucose and 5.8% of xylose were produced from the organosolv pretreatment of SCBLF-treated 8-year-old yellow poplar.

• 한국주조공학회지
• /
• 제21권4호
• /
• pp.253-259
• /
• 2001

There are many methods to produce metal foams, which can be classified into three groups according to the state of the starting metal i.e. liquid or powder or solid. Three types of defects such as cell closing, cell deformation or breakdown and cell misrun are thought to be occurred when we make the open cell aluminum foams by precision casting. Filling ability of the mold slurry between preform is related with cell closing, mold collapsibility is related with cell deformation or breakdown, mold temperature and pouring pressure are related with cell misrun. These factors can be evaluated by measuring slurry fluidity, burnout strength and permeability of the mold. Properties of the plaster mold were evaluated to find optimum mold conditions for high quality open cell aluminum foam in this study. Permeability was almost zero independent of burnout conditions, however, crack initiation was found on the surface of all specimens one or two minutes after taking out from the furnace. Crack has grown and disappeared with time. This crack may facilitate the mold filling when molten metal is poured, because of the improved mold permeability. It was considered that crack initiation and disappearance was closely related with temperature difference between the surface and inner part. Knocking-out the mold is a difficult problem due to the small cell size, because continuous mesh structure of the metal foam is not strong. It is not easy to remove molding material after pouring. We can expect that water quenching can facilitate the knocking-out the mold after solidification without damaging cell structures. Collapsed particles after water quenching became bigger with the increase in time.

• Nuclear Engineering and Technology
• /
• 제55권8호
• /
• pp.2966-2976
• /
• 2023

A tritium breeder is a lithium-based material capable of producing tritium. Many researchers designing nuclear-fusion energy are studying tritium production using pebbles, which are solid-type breeders. The sphericity and size of the pebbles are critical in obtaining pebbles with good tritium-breeding efficiency. Furthermore, tritium-release efficiency can be increased by using pebbles with appropriate porosities. Promising raw materials for tritium-breeding materials include Li₄SiO₄ and Li₂TiO₃. Li₄SiO₄ has a higher lithium density than Li₂TiO₃ and exhibits excellent tritium-breeding efficiency. However, it has the disadvantage of being easily decomposed during the Li₄SiO₄-green-pebble sintering process because of its low structural stability at high temperatures and high lithium density. In this study, we attempted to determine the optimal conditions for manufacturing Li₄SiO₄ pebbles using the droplet-freeze-drying method. The optimal Li₄SiO₄ slurry conditions and sintering temperatures were determined. The optimal Li₄SiO₄ slurry-fabrication conditions were 3 wt% polyvinyl alcohol and 75 wt% Li₄SiO₄ based on the deionized-water weight content. The sintering temperature at which Li₄SiO₄ did not decompose and exhibited the optimum porosity of 10.8% was 900 ℃.

• 한국축산시설환경학회지
• /
• 제10권1호
• /
• pp.1-10
• /
• 2004

현장규모 (8.6${\times}$2.5${\times}$2.4 m) 및 파이롯트규모 (1.39${\times}$0.89${\times}$0.89 m)의 고온호기산화장치를 이용하여 공기투입량 및 처리온도에 따른 양돈분뇨의 감량화 효율을 검토하였다. 현장규모에서 공기투입장치, 거품제거장치의 설치조건이 양돈슬러리 증발량과 처리온도에 모두 영향을 미치고 있음을 알 수 있었다. 현장규모 연구는 3가지의 처리방법 (처리A:공기공급량 120㎥/h, 수중펌프 2대, 소포장치2대: 처리 B: 공기공급량 180㎥/h, 수중펌프 3대, 소포장치 3대; 처리C: 공기공급량 180㎥/h, 수중펌프 3대, 소포장치 4대)으로 실행되었다. 1일 5㎥ 양돈슬러리를 동일하게 투입하면서 얻어진 연구결과, 수위변화, 온도변화 및 증발량은 각각 처리A: 50∼100cm, 31∼$64^{\circ}C$, 55L/$\m^2$ㆍday, 처리B: 40∼90cm, 29∼$52^{\circ}C$, 75L/$\m^2$ㆍday, 처리C: 40∼70cm, 45∼$54^{\circ}C$, 120L/$\m^2$ㆍday이었다. 한편 파이롯트 규모 연구는 반 연속식으로 양돈분뇨를 투입하면서 매일 투입량을 처리1: 50L/2h, 처리2: 50L/3h, 처리3: 40L/3h, 처리4: 60L/4h으로 하여 최대 슬러리 감량조건을 도출하기 위해 수행하였다.

• 한국축산시설환경학회지
• /
• 제14권2호
• /
• pp.129-138
• /
• 2008

본 연구는 고수분 돈분뇨슬러리를 재료로 하여 톱밥여과 호기성 퇴비화 현장시설의 환경요인과 효율을 구명하기 위하여 퇴비화 과정중 온도, 수분함량, 물질수지, 수분증발량, 침출수 발생량, 퇴비 품질을 조사하였다. 분뇨투입은 퇴비화 초기에는 매일 분뇨를 투입하고 $2{\sim}3$주 이후에는 1주일에 2회씩 투입하여 처리하게 설계하였다. 본 시험에서는 발효조에 톱밥을 채우고 6개월간 지속적으로 분뇨를 발효장에 살포하고 교반하여 연속 호기성 발효 처리하는 퇴비화 방식의 농가에서 시험이 수행되었다. 1. 퇴비발효상의 온도는 상층부 $57.7^{\circ}C$, 중간부 $50.9^{\circ}C$, 하층부 $44.4^{\circ}C$를 나타내어 상층부가 가장 높고 하층부가 가장 낮았다. 교반 후 $3{\sim}5$시간 후부터 온도가 $36{\sim}50^{\circ}C$로 저하되었으며 교반 8시간 후부터 온도가 $64.5^{\circ}C$로 상승하여 정상온도를 유지하였다. 퇴비발효상 내부 온도의 일중 변화는 크지 않는 $20{\sim}30^{\circ}C$ 범위에 있었으나 상대습도는 $50{\sim}99%$로서 변화가 매우 컸다. 2. 퇴비발효상의 수분수지를 산출한 결과 총 투입수분량의 10.3%가 침출수로 배출되었고, 78.4%는 증발량으로 배출되었다. 본 호기성 퇴비화 시설은 수분 증발량이 높아 침출수 배출량을 제외하고 톱밥 $1m^3$당 $3.16m^3$의 슬러리 처리가 가능하여 수분조절제인 톱밥의 절감효과가 있었다. 3. 퇴비발효상 여과 침출액의 수질은 투입 슬러리 대비 BOD는 89.5%, CODcr는 81.2%, SS는 97.5% 저감되었다. 4. 최종 퇴비의 품질은 유기물은 29.1%, OM/N의 비율은 46.9%이었으며 중금속 함량은 비료공정규격 기준에 적합하였다.

• 한국환경과학회지
• /
• 제10권1호
• /
• pp.59-64
• /
• 2001

The effect of major operating parameters in spray drying sorber(=SDS) for automatic control for the simultaneous removal of acidic and organic gaseous pollutants from solid waste incinerator was performed. The field experiment was carried out in pilot scale test for the quantification of major operating parameters of hydrophilic and the hydrophobic pollutants. The removal efficiencies of $SO_2$and HCI in the 5wt% slurry condition were being increased with the increase of the stoichiometric ration which is the molecular ratio of lime to the pollutant concentration, and with the decrease of inflow flue gas temperature in the pilot SDS reactor. The removal efficiency along the height of spray drying sorber was closely related to the temperature profile, and more than 90% of total removal efficiency was achieved in an absorption region. For the removal of acidic gas the optimum operating condition considering the economics and a stable operation is the 5wt% of slurry concentration, 1.2 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. For the organic gases of benzene and toluene the removal efficiencies were 20-60% which is much lower than that of acidic gas. The best removal efficiency was obtained at 1.5 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. The organic\`s removal efficiency along the height of spray drying sorber was quite different from that of acidic gas, that is, more than 60% of the total removal efficiency for benzene and 90% of the total removal for toluene were achieved in the dried adsorption region, which was formed at the lower or exit part of the reactor.