• Journal of Korean Society of Steel Construction
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• v.29 no.3
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• pp.229-236
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• 2017

The purpose of this study is to investigate the behavior and characteristics of rubber springs and calculate the compressive stiffness by performing dynamic compression tests of rubber springs. In order to carry out the dynamic compression test of rubber spring, total 9 rubber springs were tailored by calculating the shape factor of L80-D55, L90-D58, and L100-D60, and used for the experiments. Experiments were performed by controlling the compression according to the length of the rubber spring, and the compression was increased in the order of 5%, 10%, 15%, 20% and 25% of the strain. From the experimental results, the force-strain curves were obtained and it was confirmed that strength decrease and strength increase phenomenon occurred as the strain increased. In addition, it was confirmed that the decrease of stiffness and the increase of stiffness were clearly observed according to the size and diameter of the rubber spring, and the effective compression stiffness was estimated using the slope of the force-strain curve. By using the effective compressive stiffness, design values that can be used in actual design were presented.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.9 no.3
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• pp.51-58
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• 2006

The purpose of this research presents a method to position and makes the structure for eco-corridors reasonably with collectable analysing results of various effects shown in mammals' road-kill at 429 points. Target animals of this research are Leopard cat, Siberian weasel, Raccoon dog, Korean hare, Eurasian red squirrel, Siberian chipmunk and Water deer. The results derived from the empirical analysis on the contents above are followed. First, according to the results as for Leopard cat road kill analysis, which is designated as Endangered Species Class II, the eco-corridor might be located at near village having stead food in order to decrease the frequencies of road-kill, because its road kill points were mainly collected at 4 lane hilly road with mountain-road-farm area geological type of. Second, because Siberian weasel's road kill was detected at 2 lane hilly road with mountain-road-stream geological type, the eco-corridor might be located at near a mill to decrease road-kill frequencies. Third, the road-kill frequency of Eurasian red squirrel can be reduced when the eco-corridor is located at the area across coniferous tree near 4 lane west sea freeway with mountain-road-mountain. Fourth, the road-kill of Raccoon dog can be reduced when the eco-corridor is located at 4 lane mountain road or hilly road with the geological type having farm land-road-mountain(stream). Fifth, Korean hare's road-kill can be reduced when the eco-corridor is located at grass land across ridge line of mountain, because wild rabbit road kill was happened at 4 lane mountain road or 2 lane mountain road(mountain-road-mountain). Sixth, As for Siberian chipmunk, the eco-corridor might be located at the side slope of mountain road at 2 lane mountain road under the speed of 60km/h with mountain-road-mountain. Seventh, For Water deer, the eco-corridor might be located at 4 lane hilly road with mountain-road-farm land. As for Common otter, Amur hedgehog, Yellow-throated marten, Weasel, it is difficult to specify the proper site of eco-corridor due to the lack of data. Eco-corridors for carnivores might be well located at 4 lane hilly road or 2 lane hilly road with mountain-road-farm land, and the track for herbivores might be well located as a overhead bridge on mountain-road-mountain type across mountains. In order to position eco-corridors for wildlife properly, we have to research animal's behavior with ecological background, and to consider the local uniqueness and regularly collect the empirical road-kill data in long term 3 to 5 year, which can be the foundation for the more suitable place of wild life eco-corridors.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.3
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• pp.347-357
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• 2018

The applicability of room temperature ionic liquids (RTILs), 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([$C_nmim$] [$Tf_2N$]), was investigated for the extraction of Am(III) and Eu(III) from nitric acid using n-octyl(phenyl)-N,N-diisobutyl carbamoylmethyl phosphine oxide (CMPO) and tri-n-butylphosphate (TBP) as extractants. The distribution ratios of Am(III) and Eu(III) in CMPO-TBP/[$C_nmim$][$Tf_2N$] were measured as a function of various parameters such as the concentrations of nitric acid, CMPO, and TBP. The results were compared with those obtained in CMPO-TBP/n-dodecane (n-DD). With comparable concentrations of the extractants, the distribution ratios obtained with RTILs were much higher than those obtained with n-DD. It was observed that the extraction efficiency was less for Eu(III) than for Am(III). The extraction of Am(III) and Eu(III) decreased with increases in the feed acidity for all three RTILs. The results suggest that the extraction of Am(III) and Eu(III) by CMPO in RTILs from nitric acid proceeds through the cation-exchange mechanism. The distribution ratios of Am(III) and Eu(III) increased with increases in the concentration of CMPO for all three RTILs. A linear regression analysis of the extraction data resulted in a straight line with a slope of about 3, suggesting the involvement of 3 molecules of CMPO during the extraction process.

• Journal of Wetlands Research
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• v.19 no.4
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• pp.375-382
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• 2017

In this study, general characteristics of dynamic behavior of stormwater runoff from a small impervious catchment was investigated from a series of simulations for a radial type surface runoff. Based on the simulation results, a better placement strategy for stormwater inlets to improve performance of a structural best management practice (BMP) was suggested. The degree of pollutant first flush from an ideal radial type impervious catchment was simulated using a 1-D diffusion wave equation coupled with a pollutant transport equation. The results showed that the first flush of the chemical oxygen demand was the strongest when the catchment length ranged 30-50m at a bed slope of 0.02. This result suggested that a required degree of the first flush can be intentionally obtained by just changing the locations and numbers of stormwater inlets, and thereby adjusting the catchment length. Particularly, the overall performance of a structural BMP in reducing pollutant load can be improved by placing the stormwater inlets at locations for obtaining a required first flush strength.

• Journal of the Korean Geotechnical Society
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• v.30 no.6
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• pp.5-21
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• 2014

It has been pointed out that the collapses of unsaturated road embankments caused by earthquake are attributed to high water content caused by the seepage of the underground water and/or the rainfall infiltration. Hence, it is important to study influences of water content on the dynamic stability and deformation mode of unsaturated road embankments for development of a proper design scheme including an effective reinforcement to prevent severe damage. This study demonstrates dynamic centrifugal model tests with different water contents to investigate the effect of water content on deformation and failure behaviors of unsaturated road embankments. Based on the measurement of displacement, the pore water pressure and the acceleration during dynamic loading, dynamic behavior of the unsaturated road embankments with about optimum water content and the higher water content than the optimum one have been examined. In addition, an image analysis has revealed the displacement field and the distributions of strains in the road embankment, by which deformation mode of the road embankment with higher water content has been clarified. It has been confirmed that in the case of higher water content the settlement of the crown is large mainly owing to the volume compression underneath the crown, while the small confining pressure at the toe and near the slope surface induces large shear deformation with volume expansion.

• Journal of the Korean Geotechnical Society
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• v.34 no.4
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• pp.13-25
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• 2018

When deformation occurs on slope reinforced with anchor, shear stress and bending stress are applied on the shear surface along the slip surface and increase of the shear deformation causes the tension force variation of the anchor. In this study, shear test was performed by measuring the tension force of the anchor by inducing shear deformation in vertical direction of the anchor using a large-scale direct shear test equipment in order to confirm the tension force variation of the anchor induced by shear deformation. The shear test was performed for 8 conditions which were classified according to the anchor reinforcement, separation distance (1D, 2D, 4D) from the shear surface to bonded part and the lateral-pressure condition (0.1 MPa, 0.2 MPa) of adjacent ground. As a result of the shear test, it was found that the separation distance and the lateral-pressure condition affect the shear force of the ground reinforced by anchor and the tension force of the anchor, and experimentally verified that the shear force variation is related to axial force variation of the anchor head and tip. Therefore, it was confirmed that the behavior of the bonded part induced by the shear deformation can be indirectly predicted by analyzing the tendency of the tension force variation of the anchor head.

• Journal of the Korean Geotechnical Society
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• v.18 no.2
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• pp.75-86
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• 2002

This paper presents sedimentation and consolidation characteristics of dredged soils mixed with sand materials through the self-weight consolidation tests adopting stepwise filling method. After completely throwing away dredged soils daily by flour kinds of S-C, which is the quantity of sand contained, results fi:om laboratory tests are compared with those from a new method using hyperbolic, which considers stage settling and consolidating characteristics, and those from the existing analyzing method. Liquid limit up to 65% had a large effect on consistency properties. Assuming that the settlement occurred only by clay content of dredged soils, it is shown that the clay void ratio is less than 2 and 4 respectively in case S-C is 0% and 50%. In the applied hyperbolic method, reinitialized curve has a linear behavior of a coefficient of correlation of almost 1, and the coefficient of slope and intercept except fur the specimen with the height of 10cm and 20cm had a tendency to fellow exponent function and a shape of zone settling and dispersing settling. The results computed by the applied hyperbolic method rather than the existing analyzing method coincide with those of laboratory tests. It is shown that the former is more suitable than the latter for the area considering the influence, of sand materials.

• Composites Research
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• v.32 no.6
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• pp.355-359
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• 2019

The high efficient water splitting system should involve the reduction of high overpotential value, which was enhanced by the electrocatalytic reaction efficiency of catalysts, during the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) reaction, respectively. Among them, transition metal-based compounds (oxides, sulfides, phosphides, and nitrides) are attracting attention as catalyst materials to replace noble metals that are currently commercially available. Herein, we synthesized optimal monodisperse Co₃[Co(CN)₆]₂ PBAs by FESEM, and confirmed crystallinity by XRD and FT-IR, and thermal behavior of PBAs via TG-DTA. Also, we synthesized monodispersed Co₃O₄ nanocubes by calcination of Co₃[Co(CN)₆]₂ PBAs, confirmed the crystallinity by XRD, and proceeded OER measurement. Finally, the synthesized Co₃O₄ nanocubes showed a low overpotential of 312 mV at a current density of 10 mA·cm^-2 with a low Tafel plot (96.6 mV·dec^-1).

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.697-708
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• 1992

Liquid Chromatographic behavior of Ni(II) in Isonitrosoethylacetoacetate Imine(IEAA-NR), Ni(IEAA-NH)(IEAA-NR)(R = H, CH_3, C-2H_5, n-C_4H_9, C_6H_5-CH_2) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of Ni(IEAA-NH)(IEAA-NR) chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It was fo$und that metal chelates were properly eluted in an acceptable range of capacity factor value(0{\le}logk'{\le}1). The dependence of the logarithm of capacity factor (k') on the volume fraction of water in the binary mobile phase as well as on the liquid-liquid extraction distribution ratio (Dc) in methanol-water/n-alkane extraction system showed the good linearties, and the dependence of the logarithm of capacity factor (k') on the column temperature and on the enthalpy exhibited the good linearties, and the compensation temperature ({\beta}) from the slope was 773.47{\circ}K. It was suggested that the retention of metal chelates was largely affected by the hydrophobic effect.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.8
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• pp.531-538
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• 2015

This study examined the size and shape of the nano-silver particle through the analysis of electrical resistance when synthesizing nano-sized silver by using the chemical liquid reduction. Changes in particle behaviors formed according to the changes in electronic characteristics by electric resistance in each time period in the beginning of reduction reaction in a course of synthesizing the nano-silver particle formation were studied. In addition, analysis was conducted on particle behaviors according to the changes in concentration of $AgNO_3$ and in temperature at the time of reduction and nucleation and growth course when synthesizing the particles based on the particle behaviors were also examined. As the concentration of $AgNO_3$ increased, the same amount of resistance of approximately $5{\Omega}$ was increased in terms of initial electronic resistance. Furthermore, according to the result of formation of nuclear growth graph and estimation of slope based on estimated resistance, slops of $6.25{\times}10^{-3}$, $2.89{\times}10^{-3}$, and $1.85{\times}10^{-3}$ were derived from the concentrations of 0.01 M, 0.05 M, and 0.1 M, respectively. As the concentration of $AgNO_3$ increased, the more it was dominantly influenced by the nuclear growth areas in the initial phase of reduction leading to increase the size and cohesion of particles. At the time of reduction of nano-silver particle, the increases of initial resistance were $4{\Omega}$, $4.2{\Omega}$, $5{\Omega}$, and $5.3{\Omega}$, respectively as the temperature increased. As the temperature was increased into $23^{\circ}C$, $40^{\circ}C$, $60^{\circ}C$, and $80^{\circ}C$, slopes were formed as $4.54{\times}10^{-3}$, $4.65{\times}10^{-3}$, $5.13{\times}10^{-3}$, and $5.42{\times}10^{-3}$ respectively. As the temperature increased, the particles became minute due to the increase of nuclear growth area in the particle in initial period of reduction.