• Title/Summary/Keyword: Size separation

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Separation and Purification of Chiral Compounds Using Crosslinked Sodium Alginate Membranes (가교화된 알진산나트륨막을 이용한 키랄 화합물 분리 정제)

  • 김지혜;김상균;이규호;제갈종건
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.352-359
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    • 2004
  • Membrane technology was used for the optical resolution of the various racemic compounds such as tryptophan, tyrosine and phenylalanine, using enantioselective membranes prepared from sodium alginate (SA) and glutaraldehyde as a membrane material and crosslinking agent, respectively, The chemical structure of the membranes was characterized with FT-IR spectrophotometry and 3D molecular structure modeling study was done to figure out the optical resolution mechanism through the membrane. Effects of degree of crosslinking, feed concentration, operating pressure and different kinds of feed solution on the membrane performances were studied. As results, it was found that with increasing degree of crosslinking and membrane thickness, and decrease in the concentration of the feed solution and smaller size of solutes, the enantinselectivity of the membrane was improved. When the sodium alginate membranes with 80% of swelling index and 79${\mu}{\textrm}{m}$ of thickness were used, 77% of enantiomeric excess was obtained.

J-integral of Penny-Shaped Crack on the End of Stiff Fiber Embedded in Rubbery Materials (고무와 섬유로 구성된 복합체 내의 섬유 끝 부분의 원형 균열에 대한 J-적분)

  • Yang, Gyeong-Jin;Gang, Gi-Ju
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.4
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    • pp.617-624
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    • 2002
  • An equation of J-integral for a penny-shaped crack at the end of the fiber embedded in rubber matrix is proposed. The values of J-integral for the specimens with various crack and specimen radius are obtained by FEA(Finite Element Analysis). The dimensional analysis is applied to derive an equation of J-integral as a nonlinear elastic energy release rate. The geometry and deformation calibration function in an equation of J can be expressed in a separated form. The geometry calibration function characterizing the effects of cord and specimen size is expressed in a polynomial form of fourth order. The deformation calibration function characterizes the effect of the overall level of strain. As approaching the infinitesimal strain, the value of the deformation calibration function approaches the results of LEFM(Linear Elastic Fracture Mechanics).

Performance Determination of Novel Design Eddy Current Separator for Recycling of Non-Ferrous Metal Particles

  • Fenercioglu, Ahmet;Barutcu, Hamit
    • Journal of Magnetics
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    • v.21 no.4
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    • pp.635-643
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    • 2016
  • Improvements were made in the study for the design of the conventional Eddy Current Separator (ECS) used for separating small sized non-ferrous particles in the waste. These improvements include decreasing the air gap between the material and magnetic drum, making the drum position adjustable and placing the splitter closer to the drum. Thus, small particles were separated with high efficiency. The magnetic drum was removed from inside the ECS conveyor belt system as design change and was placed as a separate unit. Hence, the force generated on the test material increased by about 5.5 times while the air gap between the non-ferrous materials and drum decreased from 3 mm to 1 mm. The non-metal material in the waste is separated before the drum in the novel design. Whereas non-ferrous metal particles are separated by falling into the splitter as a result of the force generated as soon as the particles fall on the drum. Every material that passes through the drum can be recycled as a result of moving the splitter closer to the contact point of the drum. In addition, the drum can also be used for the efficient separation of large particles since its position can be adjusted according to the size of the waste material. The performance of the novel design ECS was verified via analytical approaches, finite element analysis (FEA) and experimental studies.

Pretreatment of Soybean and Development of Fermentation Conditions of Chungkukjang for High Contents Isoflavone Production (고함량 이소플라본 생산을 위한 대두의 전처리 및 청국장 발효조건 확립)

  • Yoo, Jae-Soo
    • Food Engineering Progress
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    • v.15 no.4
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    • pp.355-361
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    • 2011
  • The separation conditions for the enhancement of isoflavone contents in soybean by soaking and germination were developed, and the fermentation conditions of Chungkukjang were optimized by using response surface methodology analysis. The high-yield of isoflavone production was obtained when the conditions of soaking and gemination were at 25.6$^{\circ}C$, 7 hr and 29.1$^{\circ}C$, 42.4 hr, respectively. Total isoflavone contents in soybean (Daepung) by treatment were increased from 1,012 ppm to 1,912 ppm. Also, the optimum fermentation conditions of Chungkukjang were determined 39.96$^{\circ}C$, 1.32% (inoulum size) and 42.4 hr, respectively. Isoflavone contents in Chungkugjang under the optimum fermentation conditions were 1.3 times higher than the control (1,960 ppm).

Study on Filling Capacity of Self-Consolidating Concrete for Modular LNG Storage Tank (모듈형 LNG 저장탱크용 자기 충전 콘크리트의 충전 성능평가 실용화 연구)

  • Lee, Dong Kyu;Lee, Keon Woo;Choi, Myoung Sung
    • Journal of the Korean Society of Safety
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    • v.33 no.6
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    • pp.50-57
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    • 2018
  • The purpose of this study is to evaluate the practical application of the self consolidating concrete for the steel concrete pannel (SCP) in module LNG storage tank proposed in the previous research. We evaluated the physical properties and filling performance of developed concrete for the SCP module. First, a slump flow test was conducted to evaluate the performance of the proposed guidelines for the filling test. As a result, all of the concrete used showed satisfactory performance. Based on the results of the previous study, it was found that the reliability of the required time measured by the $T_{500}$ test and the rheometer results measured before and after pumping was 0.94 which means the separation and blocking should not occur. The L-box test and the U-box test were conducted before and after pumping. All of the guidelines suggested showed satisfactory performance. SCP module for LNG storage tanks was fabricated on actual size scale to evaluate the practical application at the final site. As a result, it was confirmed that satisfactory filling performance was obtained in all the specimens.

A Study on the Fabrication of 3D Scaffolds Using the Solid Freeform Method (임의 형상 제작 기법을 이용한 3차원 세포지지체 제작에 관한 연구)

  • Choi, Do-Hyun;Kim, Hyun-Chul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.2
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    • pp.44-51
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    • 2019
  • With the goal of tissue regeneration for organs damaged through an accident or a disease, research on tissue engineering has been conducted to produce 3-D scaffolds that can support the cells in the attachment and growth for the cell proliferation and differentiation. A scaffold requires a suitable pore size and porosity to increase the nutrient circulation or oxygen supply for the attachment and growth of cells. The existing production methods such as solvent-casting particulate leaching, phase separation, and fiber bonding have certain disadvantages. With these methods, it is difficult to obtain a free desired shape. In addition, certain pore sizes and interconnectivities among the pores may not be guaranteed. To solve these problems, this study has fabricated a scaffold with a 3-D shaped nose using Alginate, which is a natural polymer obtained through Fused Deposition Modeling (FDM), one of the CAD/CAM-based Solid Freeform Fabrication (SFF) methods.

Simultaneous Determination of Cysteamine and Cystamine in Cosmetics by Ion-Pairing Reversed-Phase High-Performance Liquid Chromatography

  • Kim, Yejin;Na, Dong Hee
    • Toxicological Research
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    • v.35 no.2
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    • pp.161-165
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    • 2019
  • Cysteamine has been used in cosmetics as an antioxidant, a hair straightening agent, and a hair waving agent. However, recent studies indicate that cysteamine can act as an allergen to hairdressers. The objective of this study was to develop and validate a simple and effective reversed-phase high-performance liquid chromatography (RP-HPLC) method for the measurement of cysteamine and its dimer, cystamine. Sodium 1-heptanesulfonate (NaHpSO) was used as an ion-pairing agent to improve chromatographic performance. Separation was performed on a Gemini C18 column ($250mm{\times}4.6mm$, $5{\mu}m$ particle size) using a mobile phase composed of 85:15 (v/v) 4 mM NaHpSO in 0.1% phosphoric acid:acetonitrile. UV absorbance was monitored at 215 nm. The RP-HPLC method developed in this study was validated for specificity, linearity, limit of detection, limit of quantitation, precision, accuracy, and recovery. Cysteamine and cystamine were chromatographically resolved from other reducing agents such as thioglycolic acid and cysteine. Extraction using water and chloroform resulted in the recovery for cysteamine and cystamine ranging from 100.2-102.7% and 90.6-98.7%, respectively. This validated RP-HPLC method would be useful for quality control and monitoring of cysteamine and cystamine in cosmetics.

Development of the Post-Operative Bra for Breast Augmentation Patients (유방 확대수술 환자용 수술 직후 보정용 브래지어 개발)

  • Yi, Kyong-Hwa;Choi, Hyun Ok
    • Journal of the Korean Society of Clothing and Textiles
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    • v.43 no.2
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    • pp.215-227
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    • 2019
  • This study develops a post-operative brassiere suitable for changed breast shapes and the characteristics of breast augmentation patients. Six subjects who experienced breast augmentation surgery with a cup size of C or D cup participated in the wearing test. We conducted a wearing test to evaluate the superiority of the developed post-operative bra. As a result, the evaluation of the developed bra was excellent in the outer cup, outer circle of breast front gore, shoulder straps and the wing pressures. Second the satisfaction of the developed brassiere was high in the front center part, and in the evaluation of wearing satisfaction of the subjects; in addition, the degree of close contact with the cup, flexibility, touch, and overall evaluation. The satisfaction of the developed bra was also higher than a commercial bra. Third, the developed bra proved superior in the adaptability test, such as prevention of breast shaking, prevention of bra and breast separation during movements, and ease of body movement.

On the effect of void ratio and particle breakage on saturated hydraulic conductivity of tailing materials

  • Ma, Changkun;Zhang, Chao;Chen, Qinglin;Pan, Zhenkai;Ma, Lei
    • Geomechanics and Engineering
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    • v.25 no.2
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    • pp.159-170
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    • 2021
  • Particle size of tailings in different areas of dams varies due to sedimentation and separation. Saturated hydraulic conductivity of high-stacked talings materials are seriously affected by void ratio and particle breakage. Conjoined consolidation permeability tests were carried out using a self-developed high-stress permeability and consolidation apparatus. The hydraulic conductivity decreases nonlinearly with the increase of consolidation pressure. The seepage pattern of coarse-particle tailings is channel flow, and the seepage pattern of fine-particle tailings is scattered flow. The change rate of hydraulic conductivity of tailings with different particle sizes under high consolidation pressure tends to be identical. A hydraulic conductivity hysteresis is found in coarse-particle tailings. The hydraulic conductivity hysteresis is more obvious when the water head is lower. A new hydraulic conductivity-void ratio equation was derived by introducing the concept of effective void ratio and breakage index. The equation integrated the hydraulic conductivity equation with different particle sizes over a wide range of consolidation pressures.

Synthesis and Application of Magnetoplasmonic Nanoparticles (마그네토플라즈모닉 나노 자성 입자의 합성과 응용)

  • Park, Sejeong;Hwang, Siyeong;Jung, Seonghwan;Gwak, Juyong;Lee, Jaebeom
    • Journal of Powder Materials
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    • v.28 no.5
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    • pp.429-434
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    • 2021
  • Magnetic nanoparticles have a significant impact on the development of basic sciences and nanomedical, electronic, optical, and biotech industries. The development of magnetic structures with size homogeneity, magnetization, and particle dispersibility due to high-quality process development can broaden their utilization for separation analysis, structural color optics using surface modification, and energy/catalysts. In addition, magnetic nanoparticles simultaneously exhibit two properties: magnetic and plasmon resonance, which can be self-assembled and can improve signal sensitivity through plasmon resonance. This paper reports typical examples of the synthesis and properties of various magnetic nanoparticles, especially magnetoplasmonic nanoparticles developed in our laboratory over the past decade, and their optical, electrochemical, energy/catalytic, and bio-applications. In addition, the future value of magnetoplasmonic nanoparticles can be reevaluated by comparing them with that reported in the literature.