• Title/Summary/Keyword: Size separation

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Influence of pH on Sensitivity of $WO_3$ NO gas sensor fabricated by Sol-Coprecipitation method (Sol-Coprecipitation 법에 의한 NO 감지용 $WO_3$ 센서 제조시 pH의 영향)

  • Kim, Suk-Bong;Lee, Dae-Sik;Lee, Duk-Dong;Huh, Jeung-Soo
    • Journal of Sensor Science and Technology
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    • v.10 no.2
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    • pp.118-124
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    • 2001
  • When particles are dissolved in solution, they have different zeta-potentials depending on pH. Zeta-potential has an influence on particle separation, which can control particle size. And the size of $WO_3$ particle affects the sensitivity of $WO_3$ sensor for detecting NO gas. Therefore we study influence of pH on NO-sensing $WO_3$ gas sensor fabricated by Sol-Coprecipitation method. As pH increases from 2 to 7, dynamic mobility of $WO_3$ precursor was increased. When pH was 7, it showed the largest distribution separation. It means when pH is 7, we can make $WO_3$ powder which has smaller particle size. And it is confirmed by particle size analysis of $WO_3$ powder, X-ray diffration result of $WO_3$ sensing layer and surface morphology. It also affect NO sensing characteristics of $WO_3$ gas sensor. The sensing film synthesized at pH 7 showed the largest sensitivity.

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The Manufacturing Characteristics of Magnesium Chloride Emulsion by Different Rotational Speed of Homomixer as Soybean Curd Coagulant (두부응고제로서 Homomixer 회전속도를 달리한 염화마그네슘유화물의 제조특성)

  • Hong, Seung-Seok;Park, Won-Jong;Joung, Kyung-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.1252-1257
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    • 2013
  • This study was used homomixer as one of the manufacturing method to establish optimal manufacturing condition with magnesium chloride emulsion as coagulant. The more rotational speed of homomixer was fast, the more particle size of magnesium chloride emulsion was minute. The particle size was distributed between 1 and $5{\mu}m$. The more minute particle size of emulsion had an effect on increasing viscosity of emulsion and delay of oil phase separation during storage period, so the quality of magnesium chloride emulsion had correlation with dispersed phase particle size. After all the experiments, when manufacturing magnesium chloride emulsion, it used more than 10,000 rpm of rotational speed of homomixer, it showed the best result as coagulant according to the state of texture and the water separation ratio of soybean curd.

Molecular Dynamics Study to Investigate Ion Selectivity of Functionalized Carbon Nanotube Membranes (기능화된 탄소나노튜브 멤브레인의 이온 선택성에 관한 분자동역학 연구)

  • Suk, Myung Eun
    • Membrane Journal
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    • v.28 no.6
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    • pp.388-394
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    • 2018
  • Carbon nanotube (CNT) based membranes are promising candidates for separation membranes by showing high water transport rate and ion rejection rate according to their radii. The ion selectivity is an important factor to discover the full potential of CNT membranes, and it is affected by the functionalization of CNTs. With multivalent/size ion mixtures, the ion selectivity is affected by not only ion-functional groups interaction but also ion-ion interactions and ion size exclusion in a complex manner. In this study, molecular dynamics simulations are performed to study the ion selectivity of functionalized carbon nanotubes when multivalent/size ions are contained. The permeation energy barriers are calculated by plotting potential of mean force profiles, and various factors, such as CNT size and partial charges, affecting ion selectivity are investigated. The results presented here will be useful for designing CNT membranes for ion separation, biomimetic ion channels, etc.

Size Control of Iron Oxide (Fe3O4) Nanoclusters according to Reaction Factors and Consequent Change in Their Magnetic Attraction (반응 인자 제어에 의한 산화철(Fe3O4) 나노클러스터의 크기와 자기 특성 조절)

  • Sanghoon Lee;Arim Byun;Jin-sil Choi
    • Journal of Powder Materials
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    • v.30 no.4
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    • pp.297-304
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    • 2023
  • Iron oxide (Fe2O3) nanoclusters exhibit significant potential in the biomedical and pharmaceutical fields due to their strong magnetic properties, stability in solutions, and compatibility with living systems. They excel in magnetic separation processes, displaying high responsiveness to external magnetic fields. In contrast to conventional Fe2O3 nanoparticles that can aggregate in aqueous solutions due to their ferrimagnetic properties, these nanoclusters, composed of multiple nanoparticles, maintain their magnetic traits even when scaled to hundreds of nanometers. In this study, we develop a simple method using solvothermal synthesis to precisely control the size of nanoclusters. By adjusting precursor materials and reducing agents, we successfully control the particle sizes within the range of 90 to 420 nm. Our study not only enhances the understanding of nanocluster creation but also offers ways to improve their properties for applications such as magnetic separation. This is supported by our experimental results highlighting their size-dependent magnetic response in water. This study has the potential to advance both the knowledge and practical utilization of Fe2O3 nanoclusters in various applications.

Three-Dimensional Flow Analysis around Rolling Stock with Square Cross Section Using Low Re ${\kappa}-{\epsilon}$ (사각 단면을 갖는 철도차량 주위의 3차원 유동해석)

  • Jang, Yong-Jun
    • Journal of the Korean Society for Railway
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    • v.9 no.6 s.37
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    • pp.772-777
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    • 2006
  • Three-dimensional numerical study is performed for the flow analysis around the rolling stock with square cross section (Mugungwha train model). The height (H) of rolling stock is considered as the characteristic length and the total length of rolling stock is 40 which correspond to 1/2 unit of rolling stock. The gap between the surface and rolling stock is 0.17H which is average value. The relative velocity between the surface and rolling stock is assumed to be zero and Re=10,000 based on the characteristic length. Low Re ${\kappa}-{\epsilon}$[15] is employed for the calculation of turbulence which resolve all the way to the solid surface (laminar sub-layer). Large flow separation occurred at the front head of train and a pair of vortex is generated on both top and side of rolling stock. The behavior of vortices on the top of the rolling stock is believed to affect the performance of the pantograph which should be intensively investigated. The difference between the high pressure in the front stagnation region of train and the low pressure in the rear separated region causes a large pressure drag. A large pair or vortex are generated in the rear of train and the size of vortex is increased more than the size of cross section of train.

Preparation and Application of Functional Microsphere(I) - A Study on Microsphere Formation and Characteristics of Poly(ethylene-co-vinylacetate) Polymer with TiO2 (기능성마이크로스피어의 제조와 응용(I) - TiO2를 함유한 Poly(ethylene-co-vinylacetate) 공중합체의 마이크로스피어 제조 및 그 특성에 관한 연구)

  • Lee, Shin-Hee;Park, Soo-Min
    • Fashion & Textile Research Journal
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    • v.10 no.2
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    • pp.254-259
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    • 2008
  • Poly(ethylene-co-vinylacetate)(EVA) microspheres were prepared by a thermally induced phase separation. The microsphere formation occurred by the nucleation and growth mechanism in the metastable region. The diluents used were toluene. The microsphere formation and growth was followed by the cloud point of the optical microscope measurement. The microsphere size, which was obtained by SEM observation and particle size analyzer, became decreased when the titanium dioxide($TiO_2$) concentration was higher. The deodorizing function of the prepared fabrics was studied by the determination of the decomposing capability for $NH_3$. The deodorant activity of these deodorizing fabrics was measured by chromogenic gas detector tubes. The deodorant activity of $NH_3$ increased with increasing $TiO_2$ concentration of EVA microsphere.

A DNA Microextractor Using Crossed Field Electrophoresis (교차 전기영동법을 이용한 극소형 DNA 추출기)

  • Yi Soyeon;Seo Kyoung-Sun;Cho Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.8 s.227
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    • pp.1135-1139
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    • 2004
  • This paper presents a microextractor for the separation of DNA molecules by their sizes. The DNA microextractor immobilizes the DNA molecules of specific size in the micropillar array by adjusting the period of the crossed electric field, thus providing a starting-point independent target DNA extraction method without separation process monitoring. The DNA microextractor has been fabricated by a three-mask micromachining process. The velocity of three different DNA molecules has been measured at the electric field of E=5V/0.8cm in the fabricated DNA microextractor, resulting in the reorientation times of $4.80{\pm}0.44sec,\;7.12{\pm}0.75sec$, and $9.88{\pm}0.30sec$ for ${\lambda}$ DNA, micrococcus DNA, and T4 DNA, respectively. T4 DNA is trapped in the micropillar array when the crossed electric field of 5V/0.8cm is applied alternately at a 10 second time interval. The present DNA microextractor filters the DNA in a specific size range by adjusting the magnitude and/or the period of the crossed electric field applied in the micropillar array.

Assessment of Soil Washing Efficiency for Arsenic Contaminated Site Adjacent to Jang Hang Refinery (장항제련소 주변 비소오염토양의 특성분석에 따른 토양세척 처리효율 평가)

  • Moon, So-Young;Oh, Min-Ah;Jung, Jun-Kyo;Choi, Sang-Il;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.16 no.1
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    • pp.71-81
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    • 2011
  • Cause of contamination in the study area nearby Jang Hang Refinery is dust scattering in refinery stack, and soil washing treatment is one of the proper technologies for soil remediation in this area. Site conditions frequently limit the selection of a treatment process. A treatment technology may be eliminated based on the soil classification or physicochemical characteristics of soil. This study was assessed the soil washing efficiency by conducting of soil characteristic analysis in the vicinity of Jang Hang Refinery Stack within a 2 km radius. Also, it was decided about remedial range with comparative analysis of As in soil by Korean Standard Test Method before/after revision, whereupon As concentration in soil showed a increasing tendency after revision. As a result, the soil washing using the size separation of soil was determined through identifying of As species in the soil. In this site, only particle size distribution and water content of soil can provide the initial means of screening for the potential use of soil washing.

Application of nanoparticles in extending the life of oil and gas transmission pipeline

  • Yunye, Liu;Hai, Zhu;Jianfeng, Niu
    • Structural Engineering and Mechanics
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    • v.84 no.6
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    • pp.733-741
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    • 2022
  • The amount of natural gas that is used on a worldwide scale is continuously going up. Natural gas and acidic components, such as hydrogen sulfide and carbon dioxide, cause significant corrosion damage to transmission lines and equipment in various quantities. One of the fundamental processes in natural gas processing is the separation of acid gases, among which the safety and environmental needs due to the high toxicity of hydrogen sulfide and also to prevent wear and corrosion of pipelines and gas transmission and distribution equipment, the necessity of sulfide separation Hydrogen is more essential than carbon dioxide and other compounds. Given this problem's significance, this endeavor aims to extend the lifespan of the transmission lines' pipes for gas and oil. Zinc oxide nanoparticles made from the environmentally friendly source of Allium scabriscapum have been employed to accomplish this crucial purpose. This is a simple, safe and cheap synthesis method compared to other methods, especially chemical methods. The formation of zinc oxide nanoparticles was shown by forming an absorption peak at a wavelength of about 355 nm using a spectrophotometric device and an X-ray diffraction pattern. The size and morphology of synthesized nanoparticles were determined by scanning and transmission electron microscope, and the range of size changes of nanoparticles was determined by dynamic light scattering device.

Crystallite Size Measurement of Uranium Oxide Fuel Powders by Neutron Diffraction (중성자 회절에 의한 산화우라늄 핵연료 분말의 결정크기 측정)

  • 류호진;강권호;문제선;송기찬;최용남
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.318-324
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    • 2003
  • The nano-scale crystallite sizes of uranium oxide powders in simulated spent fuel were measured by the neutron diffraction line broadening method in order to analyze the sintering behavior of the dry process fuel. The mixed $UO_2$ and fission product powders were dry-milled in an attritor for 30, 60, and 120 min. The diffraction patterns of the powders were obtained by using the high resolution powder diffractometer in the HANARO research reactor. Diffraction line broadening due to crystallite size was measured using various techniques such as the Stokes' deconvolution, profile fitting methods using Cauchy function, Gaussian function, and Voigt function, and the Warren-Averbach method. The non-uniform strain, stacking fault and twin probability were measured using the information from the diffraction pattern. The realistic crystallite size could be obtained after separation of the contribution from the non-uniform strain, stacking fault and twin.