• Title/Summary/Keyword: Size of Particles

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Preparation of Polystyrene particles based on interfacial stability of suspension polymerization (현탁중합의 계면안정에 따른 폴리스티렌 입자 제조)

  • 이진호;이상남;박문수;김은경;문명준
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.65-78
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    • 2002
  • The suspension polymerization of styrene was carried out to obtain the narrow-size distribution of particle by using poly(vinyl alcohol) (PVA) as suspension stabilizer according to the degree of hydrolysis and the molecular weight. The stabilizing properties of suspension are also dependent on the interfacial tension of aqueous solution when PVA is added. When the polymerization process was carried out with low hydrolyzed PVA, it gave single, well-defined particles, while high hydrolyzed PVA gave clusters. The size of particle produced in this study ranged between 5${\mu}{\textrm}{m}$ and 10${\mu}{\textrm}{m}$. The suspending agent, PVA, influences on the drop size and drop stability, When the molecular weight of PVA is increased, the drop size decreases and the drops become more stable toward coalescence. An increase in the PVA concentration decreases the mean drop size and narrows the drop size distribution.

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Effect of the Raw Material and Coating Process Conditions on the Densification of 8 wt% Y2O3-ZrO2 Thermal Barrier Coating by Atmospheric Plasma Spray

  • Oh, Yoon-Suk;Kim, Seong-Won;Lee, Sung-Min;Kim, Hyung-Tae;Kim, Min-Sik;Moon, Heung-Soo
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.628-634
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    • 2016
  • The 8 wt% yttria($Y_2O_3$) stabilized zirconia ($ZrO_2$), 8YSZ, a typical thermal barrier coating (TBC) for turbine systems, was fabricated under different starting powder conditions and coating parameters by atmospheric plasma spray (APS) coating process. Four different starting powders were prepared by conventional spray dry method with different additive and process parameter conditions. As a result, large- and small-size spherical-type particles and Donut-type particles were obtained. Dense structure of 8YSZ coating was produced when small size spherical-type or Donut-type particles were used. On the other hand, 8YSZ coating with a porous structure was formed from large-size spherical-type particles. Furthermore, a segmented coating structure with vertical cracks was observed after post heat treatment on the surface of dense structured coating by argon plasma flame at an appropriate gun distance and power condition.

Synthesis and characterization of $BaTiO_3$ fine particles by hydrothermal process (수열합성법에 의한 미립의 $BaTiO_3$ 분말합성 및 특성)

  • 배동식;주기태;한경섭;최상흘
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.563-566
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    • 1998
  • $BaTiO_3$ fine particles were prepared by hydrothermal process from titanium tetra-isoproproxide ($Ti(OiPr)_4$) and barium hexa-hydroxide ($Ba(OH)_2{cdot}8H_2O$) as raw materials. The fine particles were obtained at the temperature range of 160 to $185^{\circ}C$. The properties of $BaTiO_3$ particles were studied as a function of various parameters such as reaction temperature, reaction time and Ba/Ti ratio, etc. The average particle size of $BaTiO_3$ increased with increasing reaction temperature and time. After hydrothermal treatment at $170^{\circ}C$ for 8 h, the average particle size of $BaTiO_3$ was about 30 nm and the particle size distribution was narrow.

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A Study on Combustion Characteristics of Paraffin Blended Fuel on Aluminum Particle Size (알루미늄 입자 크기에 따른 파라핀 혼합연료의 연소 특성 연구)

  • Ko, Soohan;Han, Seongjoo;Ryu, Sunghoon;Kim, Jinkon;Moon, Heejang;Kim, Junhyung;Ko, Seungwon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.791-796
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    • 2017
  • In this study, the combustion characteristics of paraffin blended fuel on aluminum particle size were investigated. The combustion experiments were carried out using aluminum particles with an average particle size of 100 nm and $8{\mu}m$ and microcrystalline paraffin wax (Sasol 0907). A series of comparison was conducted on the regression rate, the pressure curve and the characteristic velocity of pure paraffin and paraffin blended fuels with aluminum particles. It was found that the micro-sized particles enhance the regression rate as the oxidizer mass flux increased. However, the nano-sized particles decrease the regression rate as the oxidizer mass flux is increased.

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Formation and Hygroscopic Growth Properties of Ultrafine Particles in College Station, Texas, in 2003 (2003년 미국 텍사스 칼리지스테이션에서 관측된 초미세입자의 형성과 흡습 성장 특성)

  • Lee, Yong-Seob;Collins, Don R.
    • Journal of Environmental Science International
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    • v.16 no.7
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    • pp.793-798
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    • 2007
  • During May of 2003, smoke from fires in the Yucatan Peninsula was transported across the Gulf of Mexico and into Texas where it caused significant enhancement in measured aerosol concentrations and reduced visibility. During this event, the formation and growth of aerosol particles has been observed by a differential mobility analyzer (DMA) / tandem differential mobility analyzer (TDMA) system to characterize the size distribution and size-resolved hygroscopicity of the aerosol. The most number concentration is by the particles smaller than 100 nm, but the integrated number concentrations for over 100 nm increased due to the aerosol growth. Hygroscopic growth factor increase from 1.2 to 1.4 for 25, 50, and 100 nm particles during the nucleating period. This distribution and the aerosol properties derived from the TDMA data were used to calculate the growth rate. Particle growth rates were in the range 1-12 nm/hr.

Effects of Particle Size of Dry Water on Fire Extinguishing Performance (드라이워터의 입자크기가 소화성능에 미치는 영향)

  • Lee, Eungwoo;Choi, Youngbo
    • Journal of the Korean Society of Safety
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    • v.34 no.3
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    • pp.28-35
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    • 2019
  • Dry water is a core-shell structured powder which comprises a very fine water core covered with hydrophobic silica particles. Recently, the dry water has attracted attention as a new type of fire extinguishing agents. However, characteristics of the dry water as a fire extinguishing agent have not been revealed until now. To our best knowledge, this is the first work to uncover effects of particle size of the dry water on the fire extinguishing performance. Pristine dry water, which has heterogeneous particle size distribution, was carefully separated by sieving method into three fractions which were a small size (ca. $110{\mu}m$) fraction, a medium size (ca. $220{\mu}m$) fraction and a large size (ca. $400{\mu}m$) fraction. Microscopic observations confirmed the effective separation of dry water's particle size. In extinguishing tests of wood cribs fire, the medium size dry water showed most excellent fire extinguishing performance, as compared to other dry waters having small (ca. $110{\mu}m$) and large (ca. $400{\mu}m$) particle size. The good performance of the medium size (ca. $220{\mu}m$) dry water may be attributed to the balance between cooling effect of the water core and smothering effect of the silica particles. It is also revealed that small size dry water has poor flowability than large size dry water.

Physicochemical Characteristics of Rice Flour Developed as Rice Powder and Quality Characteristics of Rice Cakes (쌀가루전용 품종들의 이화학적 특성 및 설기의 품질 특성)

  • Park, Ji Won;Choi, Sun Young;Chun, Areum;Jeong, Heon Sang;Lee, Youn Ri
    • The Korean Journal of Food And Nutrition
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    • v.32 no.4
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    • pp.395-400
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    • 2019
  • This study attempts to analyze the physicochemical characteristics of rice flour developed as rice powder for exclusive use, steamed rice cake recipes developed as basic recipefor rice cakes. The study also aims to compare the quality characteristics of steamed rice cakes in an effort to establish the possibilities of developing various rice cake recipes. The moisture content and amylose content increased as the rice powder particles for exclusive use became finer. With regards to water uptake, in the case of the Hungara type, the water uptake increased as rice powder particles increased in size. In the case of the Shingil and commercial types, the water uptake decreased as rice powder particles increased in size, and solubility and swelling force decreased as rice powder particles increased in size. In the case of chromaticity, Sulgidduk made with rice powder for exclusive use the brightness (L value) increased as powder particles became finer and the yellow indexes (b value) decreased, and this was especially pronounced in the Shingil type. The measurements of changes in the mechanical textures of Sulgidduk showed that rice types with larger particles led to lower hardness, cohesiveness, springiness, and chewiness.

Size Control of Nd-Fe-B Precursor Particles Prepared by Spray Drying and Its Effect on the Magnetic Properties of Nd-Fe-B Alloy Powders after Reduction-Diffusion (분무건조된 Nd-Fe-B 전구체 입자의 크기조절 및 환원-확산 후 자기 특성에 미치는 영향)

  • Baek, Youn-Kyoung;Seo, Young-Taek;Lee, Jung-Goo;Kim, Dong Su;Bae, Dong Sik;Choi, Chul-Jin
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.359-365
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    • 2013
  • In this study, we fabricated $Nd_2Fe_{14}B$ hard magnetic powders with various sizes via spray drying combined with reduction-diffusion process. Spray drying is widely used to produce nearly spherical particles that are relatively homogeneous. Thus, the precursor particles were prepared by spray drying using the aqueous solution containing Nd salts, Fe salts and boric acid with the target stoichiometric composition of $Nd_2Fe_{14}B$. The mean particle sizes of the spray-dried powders are in the range from one to seven micrometer, which are adjusted by controlling the concentrations of precursor solutions. After debinding the as-prepared precursor particles, ball milling was also conducted to control the particle sizes of Nd-Fe-B oxide powders. The resulting particles with different sizes were subjected to subsequent treatments including hydrogen reduction, Ca reduction and washing for CaO removal. The size effect of Nd-Fe-B oxide particles on the formation of $Nd_2Fe_{14}B$ phase and magnetic properties was investigated.

The Effect of Outdoor Air and Indoor Human Activity on Mass Concentrations of Size-Selective Particulate in Classrooms (대기오염과 실내 거주자의 활동도가 교실 내부의 입자 크기별 먼지 농도에 미치는 영향)

  • Choi, Sang-Jun
    • Journal of Environmental Health Sciences
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    • v.34 no.2
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    • pp.137-147
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    • 2008
  • This study evaluated the effects of the human activity and outdoor air on concentrations of size-selective particulate matters (PM) by conducting a realtime measurement in classrooms and on roofs at 4 elementary schools, 3 middle schools and 3 high schools in Incheon City. PM concentrations featured repetitive pattern of increasing during break time (including lunch hours) and cleaning time while decreasing during class hours. This trend was more prominent with inhalable PM and PM10 than fine PMs (PM2.5, PM1.0). The indoor/outdoor (I/O) ratio of inhalable PM and PM10 exceeded 1 while that of fine PMs was close to or below 1. The PM2.5 (out)/PM10 (out) ratio stood at 0.59 (${\pm}0.16$) and the PM2.5 (in)/PM10 (in) ratio was 0.29 (${\pm}0.09$), suggesting that occupant activity had a greater effect upon coarse particles (PM10-PM2.5) than upon fine particles (PM2.5, PM1.0). The correlations between the indoor and the outdoor PM concentrations showed a stronger positive correlation for fine particles than that of coarse particles. The linear regression analysis of PM concentrations indoor and outdoor indicated a higher determinant coefficient ($r^2>0.9$), and consistency for fine particles than in case of coarse particles. In conclusion, the results of this study suggest that the indoor coarse particle concentration is more attributed to occupant activity and the indoor fine particle concentration is more influenced by outdoor air pollution.

A Study on the Properties of Electric Arc-Furnace Steelmaking Dusts for Stabilization Processing (안정화 처리를 위한 전기로 제강분진의 물성)

  • 현종영;조동성
    • Resources Recycling
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    • v.7 no.5
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    • pp.13-18
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    • 1998
  • This study was carried out to understand the properties of the E.A.F. steel-making dusts for stabilization processing. The properties are related to mincral composition, shape, particle size, magnetism, density, porosity and leaching characteristic. the dust particles, the size of which ranges from sub-micron to tens-micron, were mainly spherical like balls that were agglomerated each other: the large particles were generally Fe-rich and the small particles were spherical like balls that were agglomerated each other: the large particles were franklinite (ZnFe$_{2}O_{4}$), magnetite (Fe$_{3}O_{4}$) and zincite (ZnO) by XRD analysis. When the dusts were sieved by a wet process, the particle fraction over 200 mesh had 1.5 wt.% with magnetite and quartz. The particles in the size range of 200-500 mesh consisted of magnetite, franklinite. The 82 wt.% of the steel-making dusts were occupied by the particles finer than 500 mesh and contained franklinite and zincite as main mineralogical compositions. When the dusts of around 78% porosity compressed under the load of approximately 1 KPa, the porosity decreased to 68% and to 535 under around 13 KPa. When the E.A.F. dusts were leached according to the Korea standard leaching procedure on the waster, the heavy metals exceeding the leaching criteria were cadmium, lead and mercury.

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