• Title/Summary/Keyword: Size of Particles

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Effect of Solution Properties on Luminance Characteristics of YAG:Ce Phosphors Prepared by Spray Pyrolysis (분무열분해법으로 YAG:Ce 제조시 용액 조건이 발광특성에 미치는 영향)

  • Lee, You-Mi;Kang, Tae-Won;Jung, Kyeong-Youl
    • Journal of Powder Materials
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    • v.19 no.3
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    • pp.220-225
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    • 2012
  • YAG:Ce yellow phosphor particles were synthesized by spray pyrolysis with changing the solution properties and their luminous properties, crystal structure, and morphological changes were studied by using PL measurement, XRD, and SEM analysis. It was clear that the solution properties significantly affected the crystal phase, crystallite size, the PL intensity, and the morphology of YAG:Ce particles. At low calcination temperature, the addition of urea only to the spray solution was helpful to form a pure YAG phase without any impurity phases, as the result, the highest luminescence intensity was achieved at the calcination temperature of $900^{\circ}C$. When the calcination temperatures were larger than $1300^{\circ}C$, however, the YAG particles prepared without any additive showed the highest luminescent intensity. Regardless of the solution conditions, the emission intensity of YAG:Ce particles prepared by spray pyrolysis showed a linear relation with the crystallite size. In terms of the morphology of YAG:Ce particles, the addition of both DCCA and $NH_4OH$ to the spray solution was effective to prepare a spherical and dense structured YAG particles.

Experimental Study on Electrical Agglomeration of Liquid Particles in an Alternating Electric Field (AC 전기장내 하전 액체 입자의 응집에 관한 실험적 연구)

  • Ji, Jun-Ho;Hwang, Jung-Ho;Bae, Gwi-Nam;Kim, Yong-Gin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.3
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    • pp.442-450
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    • 2001
  • Experiments were carried out on agglomeration of bipolarly charged particles in an alternating current electric field. Laboratory-scale setup was built and experiments were conducted at atmospheric condition. DOS(Di-octyl Sebacate) particles with 100% purity were generated by an atomizer. The particles were branched into two, each of which passed through a wire-to-plate type charging section where a positive or a negative DC high voltage was applied and was charged positively or negatively. These bipolarly charged particles together passed through an agglomeration section where an $\pm$20kV AC power was applied between two plates. The resident time in the agglomeration section was adjusted as l sec. Particle sampling was made by a cascade impactor (MOUDI). The effect of agglomeration system on the reduction ratio of particles below l ㎛ was 42∼45%. Effect of AC frequency on the particle size distribution was found insignificant.

Effect of Inflow Rate of Raw Material Solution on the Fabrication of Nano-Sized Cobalt Oxide Powder by Spray Pyrolysis Process

  • Kim, Dong Hee;Yu, Jae Keun
    • Korean Journal of Materials Research
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    • v.26 no.11
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    • pp.662-669
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    • 2016
  • In order to identify changes in the nature of the particles due to changes in the inflow rate of the raw material solution, the present study was intended to prepare nano-sized cobalt oxide ($Co_3O_4$) powder with an average particle size of 50 nm or less by spray pyrolysis reaction using raw cobalt chloride solution. As the inflow rate of the raw material solution increased, droplets formed by the pyrolysis reaction showed more divided form and the particle size distribution was more uneven. As the inflow rate of the solution increased from 2 to 10 ml/min, the average particle size of the formed particles increased from about 25 nm to 40 nm, while the average particle size did not show significant changes when the inflow rate increased from 10 to 50 ml/min. XRD analysis showed that the intensity of the XRD peaks increased remarkably when the inflow rate of the solution increased from 2 to 10 ml/min. On the other hand, the peak intensity stayed almost constant when the inflow rate increased from 10 to 50 ml/min. With the increase in the inflow rate from 2 to 10 ml/min, the specific surface area of the particles decreased by approximately 20 %. On the contrary, the specific surface area stayed constant when the inflow rate increased from 10 to 50 ml/min.

The Effect of Abrasive particles on Brake Performance (자동차 제동특성에 미치는 연마제의 영향에 관한 연구)

  • Hong, Young-Suk;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.11a
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    • pp.332-340
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    • 2000
  • Friction properties of automotive brake pads containing different types of abrasivess were investigated. Five different abrasives, including o-quartz, magnesia, magnetite, alumina, zircon, were employed in this investigation and size effects of the abrasives on friction characteristics were also studied using 1, 50, 140$\mu\textrm{m}$ size zircon. Experimental results showed that the hardness and size of these abrasive particles were strongly related to friction behaviors and wear mechanisms. Harder and smaller abrasives showed higher friction coefficient and more wear. The surfaces of friction materials with different sizes of abrasives showed that two different modes of abrasion (two-body and three-body abrasion) appeared during sliding. Considering the above results, abrasive materials were thought to destroy transfer film and the extent of the destruction depends on the types and sizes of abrasive particles. A mechanism of the wear mode transition (two-body to three body abrasive motion) was suggested considering the binding energy and friction energy in terms of abrasive particle size.

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Monitoring of the Distribution of Ambient Air Particles in Seoul Using a Cascade Impactor and the Particle Toxicity

  • Park, Eun-Jung;Kim, Dae-Seon;Park, Kwang-Sik
    • Environmental Analysis Health and Toxicology
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    • v.25 no.2
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    • pp.99-109
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    • 2010
  • The distribution of ambient air particles varies according to climate, industries, and other sources. In this study, ambient air particles (less than 12.1 ${\mu}m$) were monitored from February to August, 2007 as 12 different fractions sorted by a cascade impactor. Particles in the size range from 0.33 ${\mu}m$ to 0.76 ${\mu}m$ comprised the main fraction of ambient air particles in Seoul, Korea. On the day of an Asian dust event, the particle fraction size increased to 1.25~2.5 ${\mu}m$. The different sized particle fractions were also monitored for metals and were found to contain toxic heavy metals including Pb, Cd, Hg, Cr and As. Particle preparations were significantly cytotoxic when exposed to cultured BEAS-2B cells. Microarray analysis of the treated cells indicated a significant up-regulation of a number of genes associated with oxidative stress, including metallothionein, heme oxygenase-1, heat shock protein 70, and NAD(P)H dehydrogenase-1.

Development, validation and implementation of multiple radioactive particle tracking technique

  • Mehul S. Vesvikar;Thaar M. Aljuwaya;Mahmoud M. Taha;Muthanna H. Al-Dahhan
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4213-4227
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    • 2023
  • Computer Automated Radioactive Particle Tracking (CARPT) technique has been successfully utilized to measure the velocity profiles and mixing parameters in different multiphase flow systems where a single radioactive tracer is used to track the tagged phase. However, many industrial processes use a wide range of particles with different physical properties where solid particles could vary in size, shape and density. For application in such systems, the capability of current single tracer CARPT can be advanced to track more than one particle simultaneously. Tracking multiple particles will thus enable to track the motion of particles of different size shape and density, determine segregation of particles and probing particle interactions. In this work, a newly developed Multiple Radioactive Particle Tracking technique (M-RPT) used to track two different radioactive tracers is demonstrated. The M-RPT electronics was developed that can differentiate between gamma counts obtained from the different radioactive tracers on the basis of their gamma energy peak. The M-RPT technique was validated by tracking two stationary and moving particles (Sc-46 and Co-60) simultaneously. Finally, M-RPT was successfully implemented to track two phases, solid and liquid, simultaneously in three phase slurry bubble column reactors.

Characteristics of particles at Kosan, Cheju Island: Intensive study results duting March 11 .sim. 17 1994 (제주도 고산지역 입자특성 : 1994년 3월 11일 - 17일 측정결과)

  • 김용표;심상규;문길주;백남준;김성주;허철구;강창희
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.3
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    • pp.263-272
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    • 1995
  • Characteristics of anbient at Korean, Cheju Island have been studied during the intensive field study period on March 11 .sim. 17, 1994 in collaboration with other research organizations from Korea and abroad. The particle size distribution was measured using an Electrical Aerosol Analyzer(EAA) and an Optical particle Counter(OPC). Fine particles(PM1 and PM3) have been collected by filter pack samplers and their ionic compositions have been analyzed. sampling errors inherent to the filter pack sampling method are discussed and the method to analyze those errors are presented. The rine mass concentrations of this study show very similar mass concentrations when Seoul is clear. This is somewhat surprising result, because the most of researchers believe that Kosan is one of the cleanest area in Korea. Bimodal volume size distributions with peak values around 0.1 .sim. 0.2.mu.m and 3.mu.m in particle dimeter were observed for most of the measurement period, particle mass loadings and ionic composition data show a large fraction of particles are from non-sea salt origins. Estimation of water content and acidity of particles based on measurement by a gas/particle equilibrium model, SCAPE, reveals that the pH values of particles are comparable to or lower than those estimated based on measurements in Los Angeles, U.S.A. during the SCAQS study. These findings with the meteorological conditions during the study period suggest that the particles collected during the period have originated from outside Cheju Island.

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Characterization of mechanical and photocatalytic performance on cement-based materials with TiO2 particles for binder jet 3D printing (바인더젯 3D 프린팅을 위한 TiO2 입자를 함유한 시멘트 기반 재료의 기계적 성능 및 광촉매 특성 분석)

  • Liu, Jun-Xing;Li, Pei-Qi;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.69-70
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    • 2023
  • The development of advanced 3D printing technologies has opened up new opportunities for customized digital designs in the construction industry. Using nano- and micro-scale additives is expected to improve the performance of cement-based materials in 3D printing. TiO2 particles have been widely used as reinforcing additives in cement-based materials. Therefore, this study aims to investigate the application of cement-based materials containing multi-size TiO2 particles in binder jet 3D printing and the effect of different-size TiO2 particles on the performance of printed samples. TiO2 particles exhibit an excellent filling effect, which increases the density of the printed samples and promotes hydration, thereby improving the compressive strength of the samples. In addition, larger TiO2 particles exert more pronounced filling and photocatalytic effects on the resulting samples.

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Submicrometer Particle Size Distribution of Emissions from Diesel Engines (디젤엔진에서 배출되는 미세 입자의 크기 분포)

  • 김민철;권순박;이규원;김종춘;류정훈;엄명도
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.657-665
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    • 1999
  • Particulate matter produced by diesel engines is of concern to cngine manufactures because of its environmental impact. The majority of diesel particles are in the range of smaller than 1 ${\mu}{\textrm}{m}$. Because of their tiny volume, ultrafine diesel particles contribute very little to the total mass concentration which is currently regulated for automobile emissions. Ultrafinc particles are known to have deleterious effects upon human health cspecially because they penetrate deeply human respiratory tract and have negative effects on the health. In this study, the engine exhaust gas was diluted in a dilution tunnel and the particle size distribution was measured using the scanning mobility particel sizer system. Measurements of the number and the mass concentrations of the diesel exhaust were made under different engine ooperating conditions. The dilution sampling system provided a common basis for collection of the exhaust by cooling and diluting the source emission prior to the measurement. The measurement results showed that the particle size distributions of the exhaust from the diesel vehicles equipment with either heavy-duty or lignt-duty diesel engines, were similar in the particle size range of 0.08~0.2${\mu}{\textrm}{m}$.

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Electrodeposition Behavior of Ni-WC Composite Coatings with Variation of WC Particle Size (WC 분말 크기에 따른 Ni-WC 복합 도금층의 특성 거동에 관한 연구)

  • Kim, Dae-Geun;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.39 no.3
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    • pp.115-120
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    • 2006
  • The codeposition behavior of WC particles from an additive-free nickel sulfate and sulfamate solution has been investigated. Electroplating of Ni/WC composites was carried out at different current density with variation of WC particle size. The Guglielmi adsorption mechanism is applied to the electroplating of the fine WC in Ni matrix. The contents of WC in Ni composite coating were increased both by increasing current density and WC concentration in the bath. The hardness of Ni/WC composite coating at low current density is higher than that at high current density since finer WC particles dispersed through the coating. The codeposition behaviors of Co coated WC particles were also investigated. Conducting layer of particles promoted the codeposition behavior of Ni/WC-Co composite coatings.